| Project/Area Number |
22550144
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Environmental chemistry
|
|---|
| Research Institution | Osaka Municipal Technical Research Institute |
|---|
Principal Investigator |
MIZUNO Takumi 地方独立行政法人大阪市立工業研究所, 研究員 (10416290)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
MIHARA Masatoshi 地方独立行政法人大阪市立工業研究所, 有機材料研究部, 研究主任 (70416296)
NAKAI Takeo 地方独立行政法人大阪市立工業研究所, 有機材料研究部, 研究員 (60443545)
|
|---|
| Project Period (FY) |
2010 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
|
|---|
| Keywords | リサイクル化学 / ポリカーボネート / グリセリン / 一酸化炭素 / 硫黄 / セレン / 触媒 / エチレングリコール / 環状カーボネート / カルボニル化反応 / 酸化反応 / バイオディーゼル燃料 / グリセロールカーボネート / グリセリンカーボネート |
|---|
| Research Abstract |
The corrmiercial production of glycerol has increased considerably for several years, because of its rising inevitable formation as a by-product ofbiodiesel production. For the effective utilisation of glycerol, a new synthesis of glycerol carbonate(4-hydroxymethyl-2-oxo-1,3-dioxolane)which is used as raw material of polycarbonate ffom glycerol was explored. By combined sulfUr-assisted carbonylation of glycerol under 1.0 MPa of carbon monoxide at 80℃ in DMF with oxidation by copper(II)bromide, a facile synthetic method for glycerol carbonate in good yield was developed. Also, by the selenium-catalyzed carbonylation of slightly excess of glycerol with carbon monoxide and potassium carbonate under 0.1 MPa at 20℃ in DMF, followed by the oxidation with molecular oxygen(0.1MPa,20℃), glycerol carbonate was obtained in good yields. The catalytic synthesis of glycerol carbonate was also brought about in the mixed gas atmosphere (carbon monoxide:oxygen=3:1,0.1 Mpa,20℃).
|
