| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Research Abstract |
In order to reveal the relationship between reactivity and electronic structures of high-valent iron porphyrin complexes, we have tried to establish the synthetic method to obtain 6-coordinate iron(IV) porphyrin. By the addition of strong-field ligand such as azide, iron(III) porphyrin radical cation has been converted to bis(azide) complex, which turns out to exist as an equilibrium mixture of iron(IV) porphyrin and iron(III) radical.
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