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An Approach from Organic Synthesis Toward Elucidating the Mechanism of Super Energy Transfer Efficiencies of Carotenoids in Photosynthesis

Research Project

Project/Area Number 22550160
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Chemistry related to living body
Research InstitutionKwansei Gakuin University

Principal Investigator

KATSUMURA Shigeo  関西学院大学, 理工学部, 教授 (70047364)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords海洋光合成初期過程 / カロテノイド / 超エネルギー伝達効率の解明 / ペリジニン / フコキサンチン / シリーズでの類縁体合成 / 超高速時間分解スペクトル / カロテノイド・ペリジニン / カロテノイド・フコキサンチン / 新規ペリジニン類縁体 / ワンポット共役イリデンブテノリド合成 / 新規フコキサンチン類縁体 / 新規エネルギー準位・SICT / 海洋光合成 / ピペリジン / 構造的特徴と機能 / 効率的全合成 / 立体化学制御
Research Abstract

Peridinin and fucoxanthin are known as representative auxiliary light harvesting pigments for photosynthesis in the sea. In the super complexes constructed with these carotenoids, chlorophyll and protein, respectively, exceptionally high (>85%) energy transfer efficiencies from the carotenoids to chlorophyll have been reported. This high efficiency is thought to be related to the unique structure of the carotenoids, which possesse allene and carbonyl functions. There are, however, no studies on the relation between the structural features of these carotenoids and their super ability of the energy transfer. We then focused on the subjects of how these functions play a role in the exceptionally highly energy transfer. We have achieved the efficient syntheses of these natural carotenoids and their modified derivatives on allene and conjugated polyene. Measurements of their ultrafast time resolved spectra and Stark spectra have strongly suggested that the structural feature of the both carotenoids has essentially contributed to their super ability of the energy transfer.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (84 results)

All 2012 2011 2010 Other

All Journal Article (25 results) (of which Peer Reviewed: 25 results) Presentation (56 results) (of which Invited: 2 results) Book (3 results)

  • [Journal Article] Effect of Molecular Symmetry on the Spectra and Dynamics of the Intramolecular Charge Transfer (ICT) State of Peridinin2012

    • Author(s)
      Enriquez, M. M.; Hananoki, S.; Hasegawa, S.; Kajikawa, T.; Katsumura, S.; Wagner, N. L.; Birge, R. R.; Frank, H. A
    • Journal Title

      J. Phys. Chem. B

      Volume: 116 Issue: 35 Pages: 10748-10756

    • DOI

      10.1021/jp305804q

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stereocontrolled Total Synthesis of Fucoxanthin and its Polyene Chain-modifed Derivative2012

    • Author(s)
      Kajikawa, T.
    • Journal Title

      Organic Letters

      Volume: 14 Issue: 3 Pages: 808-811

    • DOI

      10.1021/ol203344c

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stereocontrolled Synthesis of Substituted Chiral Piperidines via One-Pot Asymmetric 6π-Azaelectrocyclization: Asymmetric Syntheses of (-)-Dendroprimine, (+)-7-Epidendroprimine, (+)-5-Epidendroprimine, and (+)-5,7-Epidendroprimine.2012

    • Author(s)
      Katsumura, S., Kobayashi, T.
    • Journal Title

      J. Org. Chem.

      Volume: 77 Issue: 4 Pages: 1812-1832

    • DOI

      10.1021/jo202350z

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-catalyzed Asymmetric 6-Endo Cyclization of Dienamides with Substituents-driven Activation.2012

    • Author(s)
      Katsumura, S., Tsuchikawa, H.
    • Journal Title

      Org. Lett.

      Volume: 14 Issue: 9 Pages: 2326-2329

    • DOI

      10.1021/ol300737t

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cholesterol´s Interactions with Serine Phospholipids - a Comparison of N-palmitoyl Ceramide Phosphoserine with Dipalmitoyl Phosphatidylserine.2012

    • Author(s)
      Katsumura, S., Sergelius, C.
    • Journal Title

      Biochim. Biophys. Acta

      Volume: 1828 Issue: 2 Pages: 785-791

    • DOI

      10.1016/j.bbamem.2012.11.009

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Singlet and triplet state spectra and dynamics of structurally modified peridinin2011

    • Author(s)
      Kajikawa, T.
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 115 Issue: 15 Pages: 4436-4445

    • DOI

      10.1021/jp110092c

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structure-activity relationship of sphingomyelin analogs with aphingomyelinase from Bacillus cereus2011

    • Author(s)
      Katsumura, S., Niinivehmas, C.S.
    • Journal Title

      Biochim.Biophys.Acta.

      Volume: 1818 Issue: 3 Pages: 474-480

    • DOI

      10.1016/j.bbamem.2011.10.013

    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New type of azacyclization : thermal preparation of 4,6-disubstituted 2-piperidinone from N-sulfonyldienamide and its substituted effect2011

    • Author(s)
      Katsumura, S., Maekawa, Y.
    • Journal Title

      Tetrahedron Lett

      Volume: 53 Issue: 7 Pages: 837-841

    • DOI

      10.1016/j.tetlet.2011.12.014

    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] N-cholesteryl sphingomyelin-A synthetic sphingolipid with unique membrane properties2011

    • Author(s)
      Katsumura, S., Sergelius C.
    • Journal Title

      Biochim.Biophys.Acta

      Volume: 1808 Issue: 4 Pages: 1054-1062

    • DOI

      10.1016/j.bbamem.2010.12.021

    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of sphingosine 2N- and 3O-methylation on palmitoyl ceramide properties in bilayer membranes2011

    • Author(s)
      Katsumura, S., Maula, T.
    • Journal Title

      Biophys J.

      Volume: 101 Issue: 12 Pages: 2948-2956

    • DOI

      10.1016/j.bpj.2011.11.007

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exploring a unique reactivity of 6II-azaelectrocyclization to enzyme inhibition, natural products synthesis, and molecular imaging : an approach to chemical biology by synthetic chemists2011

    • Author(s)
      Tanaka, K., Fukase, K., Katsumura, S.
    • Journal Title

      Synlett

      Volume: 15 Issue: 15 Pages: 2115-2139

    • DOI

      10.1055/s-0030-1261192

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] N- and O-methylation of sphingomyelin markedly affects its membrane properties and interactions with cholesterol2011

    • Author(s)
      Katsumura, S., Bjorkbom, A.
    • Journal Title

      Biochim.Biophys.Acta

      Volume: 1808 Issue: 4 Pages: 1179-1186

    • DOI

      10.1016/j.bbamem.2011.01.009

    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of sphingomyelin head group size on molecular properties and interactions with cholesterol2011

    • Author(s)
      Katsumura, S., Bjorkbom, A.
    • Journal Title

      Biophys.

      Volume: 99 Issue: 10 Pages: 3300-3308

    • DOI

      10.1016/j.bpj.2010.09.049

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Total synthesis of (-)-20-epiuleine via stereocontrolled one-pot asymmetric azaelectrocycilation followed by novel 1,4-addition reaction2011

    • Author(s)
      Katsumura, S., Sakaguchi, T.
    • Journal Title

      Organic & Biomolecular Chemistry

      Volume: 9 Issue: 1 Pages: 257-264

    • DOI

      10.1039/c0ob00627k

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Singlet and Triplet State Spectra and Dynamics of Structurally-modified Peridinins2011

    • Author(s)
      Katsumura, S., Fuciman, M.
    • Journal Title

      The Journal of Physical Chemistry

      Volume: 115 Issue: 17 Pages: 4436-4445

    • DOI

      10.1021/jp110378d

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] [1,5]-H Shift of Aldehyde Hydrogen in Dienal Compounds to Produce Ketenes2011

    • Author(s)
      Katsumura, S., Sakaguchi, T.
    • Journal Title

      Org.Lett.

      Volume: 13 Pages: 4292-4295

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Total synthesis of (-)-20-epiuleine via stereocontrolled one-pot asymmetric azaelectrocyclization followed by novel 1,4-addition reaction2011

    • Author(s)
      Sakaguchi, T.
    • Journal Title

      Organie & Biomolecular Chemistry

      Volume: 9 Pages: 257-264

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stark Absorption Spectroscopy of Peridinin and Allene-modified Analogues2010

    • Author(s)
      Kusumoto, T.; Horibe, T.; Kajikawa, T.; Hasegawa, S.; Iwashita, T.; Cogdell, R. J.; Birge, R. R.; Frank, H. A.; Katsumura, S.; Hashimoto, H
    • Journal Title

      Chem. Phys.

      Volume: 373 Issue: 1-2 Pages: 71-79

    • DOI

      10.1016/j.chemphys.2010.01.018

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] An Approach Based on Organic Synthesis toward Elucidating the Mechanism of Super Energy Transfer Efficiencies of Peridinin in Photosynthesis2010

    • Author(s)
      Kajikawa, T.; Furuichi, N.; Katsumura, S
    • Journal Title

      J. Synth. Org. Chem. Japan

      Volume: 68 Pages: 625-637

    • NAID

      10026869479

    • URL

      https://www.jstage.jst.go.jp/browse/yukigoseikyokaishi/68/6/_contents/-char/ja/

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Triplet State Spectra and Dynamics of Peridinin Analogs Having Different Extents of π-Electron Conjugation2010

    • Author(s)
      Kaligotla, S.; Doyle, S.; Niedzwiedzki, D. M.; Hasegawa, S.; Kajikawa, T.; Katsumura, S.; Frank, H. A
    • Journal Title

      Photosynth. Res.

      Volume: 103 Issue: 3 Pages: 167-174

    • DOI

      10.1007/s11120-010-9535-y

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses of Ylidenbutenolide-modified Derivatives of Peridinin and their Stereochemical and Spectral Characteristics2010

    • Author(s)
      Kajikawa, T.; Aoki, K.; Iwashita, T.; Niedzwiedzki, D. M.; Frank, H. A.; Katsumura, S
    • Journal Title

      Org. Biomol. Chem.

      Volume: 8 Issue: 11 Pages: 2513-2516

    • DOI

      10.1039/c002006k

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] New Strategy in Synthetic Biology : from Enzyme Inhibition and Natural Products Synthesis to PET Imaging by 6π-Azaelectrocyclization2010

    • Author(s)
      Tanaka, K.
    • Journal Title

      The Chemical Record

      Volume: 10 Pages: 119-139

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses of ylidenbutenolide-modified derivatives of peridinin and their stereochemical and spectral characteristics2010

    • Author(s)
      Kajikawa, T.
    • Journal Title

      Org.Biomol.Chem.

      Volume: 8 Pages: 2513-2516

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Approach Based on Organic Synthesis Toward Elucidating the Mechanism of Super Energy Transfer Efficiencies of Peridinin in Photosynthesis2010

    • Author(s)
      Kajikawa, T.
    • Journal Title

      Yuki Gosei Kagaku Kyokaishi

      Volume: 68 Pages: 625-637

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stark absorption spectroscopy of peridinin and allene-modified analogues2010

    • Author(s)
      Kusumoto, T.
    • Journal Title

      Chemical Physics

      Volume: 373 Pages: 71-79

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Synthesis of Peridinin Derivativestoward Elucidating the Mechanism of Super Energy Transfer Efficiencies of Peridinin in Photosynthesis2012

    • Author(s)
      Koki Yano, Takayuki Kajikawa, Shohei Hananoki, Takashi Iwashita, Harry A. Frank, Hideki Hashimoto, Shigeo Katsumura
    • Organizer
      the 12nd International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12)
    • Place of Presentation
      Rihga Royal Hotel(Kyoto)
    • Year and Date
      2012-11-14
    • Related Report
      2012 Final Research Report
  • [Presentation] Energy Transfer Mechanism of Polyfunctional Carotenoids in Marine Photosynthesis based on Organic Synthesis2012

    • Author(s)
      Koki Yano, Takayuki Kajikawa, Takashi Iwashita, Toshiyuki Kusumoto, Dariusz M. Niedzwiedzki, Hideki Hashimoto, Harry A. Frank, and Shigeo Katsumura
    • Organizer
      19^<th> International Conference on Organic Synthesis
    • Place of Presentation
      Melbourne(Australia).
    • Year and Date
      2012-07-05
    • Related Report
      2012 Final Research Report
  • [Presentation] イリデンブテノリド環をシフトさせた新規ペリジニン類縁体の合成2012

    • Author(s)
      花ノ木祥平、長谷川慎二、梶川敬之、勝村成雄
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス
    • Year and Date
      2012-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation] イリデンブテノリド環をシフトさせた新規ペジジニン類縁体の合成2012

    • Author(s)
      花ノ木祥平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] ワンポット不斉6π-アザ電子環状反応を用いた2β,4β,5α-置換ピペリジンを有するアルカロイドの合成2012

    • Author(s)
      小林昌平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] マイクロドメインの物性解明に向けたスフィンゴミエリン類縁体の合成2012

    • Author(s)
      山口翔
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] フコキサンチンにおけるアレン結合の役割解明に向けた類縁体の合成2012

    • Author(s)
      矢野亘記、梶川敬之、小澄大輔、橋本秀樹、勝村成雄
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス
    • Year and Date
      2012-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] β-エポキシケトンを持つアルデヒドの選択的改良ジュリアカップリング反応によるフコキサンチン類縁体の合成2012

    • Author(s)
      奥村聡、梶川敬之、小澄大輔、橋本秀樹、勝村成雄
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス
    • Year and Date
      2012-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] 有機合成が先導する光合成を担う海洋カロテノイドの機能解明2012

    • Author(s)
      梶川敬之、岩下孝、HarryA.Frank、橋本秀樹、勝村成雄
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス
    • Year and Date
      2012-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] ジエナール化合物におけるアルデヒド水素の[1,5]シフトとその置換基促進効果2012

    • Author(s)
      坂口拓
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] イオニリデンアセトアルデヒド水素の[1,5]シフト反応に始まる分子内[2+2]環化反応の置換基効果およびaframodialの合成2012

    • Author(s)
      堤陽平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] 有機合成が先導する光合成を担う海洋カロテノイドの機能解明2012

    • Author(s)
      梶川敬之
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] β-エポキシケトンを持つアルデヒドの選択的改良ジュリアカップリング反応によるフコキサンチン類縁体の合成2012

    • Author(s)
      奥村聡
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] フコキサンチンにおけるアレン結合の役割解明に向けた類縁体の合成2012

    • Author(s)
      矢野亘記
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス・矢上キャンパス(神奈川県)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] アルデヒド水素の[1,5]-Hシフト反応の開発と置換基効果2011

    • Author(s)
      坂口拓
    • Organizer
      第41回複素環化学討論会
    • Place of Presentation
      市民会館崇城大学ホール(熊本県)
    • Year and Date
      2011-10-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] ワンポット不斉6π-アザ電子環状反応を用いたGuettardineおよびProtoemetineの合成研究2011

    • Author(s)
      小林昌平
    • Organizer
      第41回複素環化学討論会
    • Place of Presentation
      市民会館崇城大学ホール(熊本県)
    • Year and Date
      2011-10-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] ジエンアミドの6-endo熱環化反応および置換基効果2011

    • Author(s)
      坂口拓
    • Organizer
      第41回複素環化学討論会
    • Place of Presentation
      市民会館崇城大学ホール(熊本県)
    • Year and Date
      2011-10-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] スフィンゴリン脂質の鎖状および環状類縁体の合成2011

    • Author(s)
      山口翔
    • Organizer
      第41回複素環化学討論会
    • Place of Presentation
      市民会館崇城大学ホール(熊本県)
    • Year and Date
      2011-10-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] 有機合成が先導する海洋光合成を担う多官能性カロテノイドの機能解明2011

    • Author(s)
      梶川敬之、奥村聡、花ノ木祥平、矢野亘記、岩下孝、小澄大輔、堀部智子、橋本秀樹、勝村成雄
    • Organizer
      第53回天然有機化合物討論会
    • Place of Presentation
      大阪国際交流センター
    • Year and Date
      2011-09-27
    • Related Report
      2012 Final Research Report
  • [Presentation] 有機合成が先導する海洋光合成を担う多官能性カロテノイドの機能解明2011

    • Author(s)
      梶川敬之
    • Organizer
      第53回天然有機化合物討論会
    • Place of Presentation
      大阪国際交流センター(大阪府)
    • Year and Date
      2011-09-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 光合成エネルギー伝達機構解明に向けた海洋性カロテノイドフコキサンチンおよびその類縁体の合成2011

    • Author(s)
      梶川敬之、奥村聡、矢野亘記、岩下孝、小澄大輔、橋本秀樹、勝村成雄
    • Organizer
      第25回カロテノイド研究談話会
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2011-09-13
    • Related Report
      2012 Final Research Report
  • [Presentation] 光合成エネルギー伝達機構解明に向けた海洋性カロテノイド、フコキサンチンおよびその類縁体の合成2011

    • Author(s)
      梶川敬之
    • Organizer
      第25回カロテノイド研究談話会
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Year and Date
      2011-09-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] 海洋光合成の機能解明に向けたフコキサンチンおよびその類縁体の合成2011

    • Author(s)
      梶川敬之、奥村聡、岩下孝、小澄大輔、橋本秀樹、勝村成雄
    • Organizer
      第46回天然物化学談話会
    • Place of Presentation
      熱川ハイツ、静岡
    • Year and Date
      2011-07-07
    • Related Report
      2012 Final Research Report
  • [Presentation] 海洋光合成の機能解明に向けたフコキサンチンおよびその類縁体の合成2011

    • Author(s)
      梶川敬之
    • Organizer
      第46回天然物化学談話会
    • Place of Presentation
      熱川ハイツ(静岡県)
    • Year and Date
      2011-07-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] イリデンブテノリド環をシフトさせた新規ペリジニン類縁体の合成2011

    • Author(s)
      花ノ木祥平、長谷川慎二、梶川敬之、勝村成雄
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学横浜キャンパス
    • Year and Date
      2011-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] 有機合成を基盤とした海洋光合成を担うカロテノイドの機能解明2011

    • Author(s)
      梶川敬之、長谷川慎二、奥村聡、岩下孝、HarryA.Frank、橋本秀樹、勝村成雄
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学横浜キャンパス
    • Year and Date
      2011-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] 多官能基カロテノイド、フコキサンチンおよびその類縁体合成2011

    • Author(s)
      奥村聡、梶川敬之、岩下孝、橋本秀樹、勝村成雄
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学横浜キャンパス
    • Year and Date
      2011-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] 多官能基カロテノイド、フコキサンチンおよびその類縁体合成2011

    • Author(s)
      奥村聡
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      (日本化学会第91春季年会予稿集 震災により開催中止のため)
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 有機合成を基盤とした海洋光合成を担うカロテノイドの機能解明2011

    • Author(s)
      梶川敬之
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      (日本化学会第91春季年会予稿集 震災により開催中止のため)
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] イリデンブテノリド環をシフトさせた新規ペリジニン類縁体の合成2011

    • Author(s)
      花ノ木祥平
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      (日本化学会第91春季年会予稿集 震災により開催中止のため)
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] マイクロドメインの性状解明に向けたスフィンゴミエリン類縁体の合成2011

    • Author(s)
      山口翔
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      (日本化学会第91春季年会予稿集 震災により開催中止のため)
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 鎖状ジエナール化合物の[1,5]Hシフトによるケテン生成反応の開発2011

    • Author(s)
      坂口拓
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      (日本化学会第91春季年会予稿集 震災により開催中止のため)
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 光合成初期過程におけるエネルギー伝達機構の解明に向けたフコキサンチン類縁体およびペリジニン類縁体の合成2010

    • Author(s)
      奥村聡、花ノ木祥平、梶川敬之、勝村成雄
    • Organizer
      第30回有機合成若手セミナー
    • Place of Presentation
      大阪府立大学学術交流会館
    • Year and Date
      2010-11-10
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Presentation] ワンポット不斉アザ電子環状反応を用いた(-)-Guettardineの全合成とその展開2010

    • Author(s)
      小林昌平
    • Organizer
      第30回有機合成若手セミナー
    • Place of Presentation
      大阪府立大学学術交流会館
    • Year and Date
      2010-11-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] マイクロドメインの性状解明に向けたスフィンゴミエリン類縁体の合成2010

    • Author(s)
      山口翔
    • Organizer
      第30回有機合成若手セミナー
    • Place of Presentation
      大阪府立大学学術交流会館
    • Year and Date
      2010-11-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] N-スルホニルジエンアミド化合物の新しい環化反応による6員環ラクタムの形成2010

    • Author(s)
      前川裕也
    • Organizer
      第98回有機合成シンポジウム
    • Place of Presentation
      早稲田大学国際会議場
    • Year and Date
      2010-11-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] 立体選択的不斉エポキシ化反応を鍵としたフコキサンチンの合成2010

    • Author(s)
      梶川敬之、奥村聡、勝村成雄
    • Organizer
      第54回香料・テルペンおよび精油化学に関する討論会
    • Place of Presentation
      山梨大学甲府キャンパス
    • Year and Date
      2010-10-23
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Presentation] ワンポット不斉6π-アザ電子環状反応を用いたアルカロイド全合成2010

    • Author(s)
      坂口拓
    • Organizer
      第40回複素環化学討論会
    • Place of Presentation
      仙台市民会館
    • Year and Date
      2010-10-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] アルカロイド合成戦略としてのワンポット不斉6π-アザ電子環状反応:(-)-Hippodamine, (-)-Guettardineの全合成2010

    • Author(s)
      坂口拓
    • Organizer
      第52回天然有機化合物討論会
    • Place of Presentation
      グランシップ(静岡県)
    • Year and Date
      2010-10-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] N-スルホニルジエンアミド化合物の新しい環化反応による6員環ラクタムの形成2010

    • Author(s)
      前川裕也
    • Organizer
      第27回有機合成化学セミナー
    • Place of Presentation
      シーサイドホテル舞子ビラ神戸
    • Year and Date
      2010-09-04
    • Related Report
      2010 Annual Research Report
  • [Presentation] Syntheses of Peridinin Analogues Toward Elucidation of its Highly Efficient Energy Transfer Mechanism in Photosynthesis2010

    • Author(s)
      Takayuki Kajikawa, Shinji Hasegawa, Takashi Iwashita, Toshiyuki Kusumoto, Dariusz M. Niedzwiedzki, Hideki Hashimoto, Harry A. Frank, and Shigeo Katsumura
    • Organizer
      18^<th> International Conference on Organic Synthesis
    • Place of Presentation
      Grieghallen Culture&Convention Centre (Norway)
    • Year and Date
      2010-08-05
    • Related Report
      2012 Final Research Report
  • [Presentation] One-pot Asymmetric 6π-Azaelectrocyclization as a Strategy for Alkaloid Synthesis (1) ; Total Syntheses of (-)-Dendroprimine, (-)-Hippodamine2010

    • Author(s)
      Shigeo Katsumura
    • Organizer
      18^<th> International Conference on Organic Synthesis
    • Place of Presentation
      Grieghallen Culture & Convention Centre
    • Year and Date
      2010-08-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] One-pot Asymmetric 6π-Azaelectrocyclization as a Strategy for Alkaloid Synthesis (2); Syntheses of Indole Alkaloids2010

    • Author(s)
      Taku Sakaguchi
    • Organizer
      18^<th> International Conference on Organic Synthesis
    • Place of Presentation
      Grieghallen Culture & Convention Centre
    • Year and Date
      2010-08-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] Syntheses of Peridinin Analogues Toward Elucidation of its Highly Efficient Energy Transfer Mechanism in Photosynthesis2010

    • Author(s)
      Takayuki Kajikawa
    • Organizer
      18^<th> International Conference on Organic Synthesis
    • Place of Presentation
      Grieghallen Culture & Convention Centre
    • Year and Date
      2010-08-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] 海洋光合成を担うペリジニンの超エネルギー伝達機能と構造的特性2010

    • Author(s)
      梶川敬之、長谷川慎二、岩下孝、楠本利行、Dariusz M.Niedzwiedzki、Harry A.Frank、橋本秀樹、勝村成雄
    • Organizer
      第45回天然物化学談話会
    • Place of Presentation
      三谷温泉ホテル明山荘
    • Year and Date
      2010-07-04
    • Related Report
      2012 Final Research Report
  • [Presentation] New type of Azacyclization :Preperation of 4,6-Disubstituted 2-Piperidinone from N-Sulfonyldienamide

    • Author(s)
      奥野雄大
    • Organizer
      19th International Conference on Organic Synthesis
    • Place of Presentation
      Melbourne, Australia
    • Related Report
      2012 Annual Research Report
  • [Presentation] Energy Transfer Mechanism of Polyfunctional Carotenoids in Marine Photosynthesis based on Organic Synthesis

    • Author(s)
      矢野亘記
    • Organizer
      19th International Conference on Organic Synthesis
    • Place of Presentation
      Melbourne, Australia
    • Related Report
      2012 Annual Research Report
  • [Presentation] [1,5]-H Shift of Aldehyde Hydrogen in Dienal Compounds to Produce Ketenes and It’s Substituent Effect

    • Author(s)
      坂口拓
    • Organizer
      19th International Conference on Organic Synthesis
    • Place of Presentation
      Melbourne, Australia
    • Related Report
      2012 Annual Research Report
  • [Presentation] ラフトドメイン機能解明を志向したスフィンゴミエリン類縁体の合成および評価

    • Author(s)
      坂口拓
    • Organizer
      第54回天然有機化合物討論会
    • Place of Presentation
      東京農業大学世田谷キャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] アルデヒド水素の[1,5]-Hシフト反応の開発と置換基効果

    • Author(s)
      奥野雄大
    • Organizer
      第41回複素環化学討論会
    • Place of Presentation
      熊本市民会館
    • Related Report
      2012 Annual Research Report
  • [Presentation] アルデヒド水素の[1,5]-Hシフト反応の開発およびアフラモジアールの合成

    • Author(s)
      坂口拓
    • Organizer
      第56回香料・テルペンおよび精油化学に関する討論会
    • Place of Presentation
      鹿児島大学郡元キャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] Smooth [1,5]-H Shift of Aldehyde Hydrogens due to Remarkable Substituent Effect

    • Author(s)
      坂口拓
    • Organizer
      12nd International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      リーガロイヤルホテル京都
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis of Peridinin Derivatives toward Elucidating the Mechanism of Super Energy Transfer Efficiencies of Peridinin in Photosynthesis

    • Author(s)
      矢野亘記
    • Organizer
      12nd International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      リーガロイヤルホテル京都
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis of Sphingomyelin Analogs toward Elucidation of Membrane Raft Properties

    • Author(s)
      勝村成雄
    • Organizer
      12nd International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      リーガロイヤルホテル京都
    • Related Report
      2012 Annual Research Report
  • [Presentation] 機能性天然物の新局面を拓く有機合成のパワー

    • Author(s)
      勝村成雄
    • Organizer
      第32回有機合成若手セミナー
    • Place of Presentation
      神戸薬科大学 ききょう記念ホール
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 仲間と追いかけた機能性天然物合成のおもしろさ

    • Author(s)
      勝村成雄
    • Organizer
      有機合成新春講演会
    • Place of Presentation
      大阪科学技術センター
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Book] In ARTIFICIAL PHOTOSYNTHESIS; Mohammad Mahdi Najafpour., Eds.; In Tech: Croatia2012

    • Author(s)
      Takayuki Kajikawa; Shigeo Katsumura
    • Publisher
      An Approach Based on Synthetic Organic Chemistry Toward Elucidation of Highly Efficient Energy Transfer Ability of Peridinin in Photosynthesis
    • Related Report
      2012 Final Research Report
  • [Book] ARTIFICIAL PHOTOSYNTHESIS2012

    • Author(s)
      梶川敬之
    • Total Pages
      18
    • Publisher
      In Tech
    • Related Report
      2012 Annual Research Report
  • [Book] 海洋性カロテノイドの効率的なエネルギー伝達のしくみを分子レベルで解き明かす2011

    • Author(s)
      梶川敬之、勝村成雄
    • Publisher
      化学と生物
    • Related Report
      2012 Final Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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