| Project/Area Number |
22550161
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials/Devices
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| Research Institution | University of Tsukuba |
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Principal Investigator |
GOTO Hiromasa 筑波大学, 数理物質系, 准教授 (40292528)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
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| Keywords | キラル / コレステリック液晶 / ポーラロン / 光学活性エレクトロクロミズム / 吸収スペクトル / 回折 / 干渉 / 電解重合 / 液晶 / 導電性高分子 / 電解不斉重合法 / 旋光性 / 円偏光二色性 / らせん誘起力 / 共役系高分子 / 光異性 / 二色性 / 結晶構造 / 固体結晶電解液 |
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| Research Abstract |
Chiral liquid crystal electrolyte solution was prepared, and electrochemical synthesis of conjugated polymers were carried out. Furthermore, polymers with diffraction properties were obtained by electrochemical polymerization in chiral liquid crystals, and smectic A. Opticalproperties of the polymers were examined. Through this study, "elective reflection light electrochromism" was established. Next, electrochemical polymerization in crystals, and phase transition sequential polymerization were developed. Metallic reflection electrochromism phenomenon was confirmed.
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