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Development of anthocyanin-based photochromic material having low environmental impact and high safety

Research Project

Project/Area Number 22550173
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic industrial materials
Research InstitutionTokyo University of Technology

Principal Investigator

SHIBATA Masashi  東京工科大学, 応用生物学部, 教授 (00513657)

Co-Investigator(Kenkyū-buntansha) TAKAGI Katsuhiko  (財)神奈川科学技術アカデミー, 研究顧問 (60023264)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2012: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2011: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2010: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywords光スイッチ / ナノ細孔体 / フォトクロミズム / アントシアニンヒドロキシメトキシカルコン / メソポーラスシリカ / アントシアニン / ヒドロキシメトキシカルコン
Research Abstract

A composite of a synthetic anthocyanin-based dye (2-Hydroxy-4'-methoxychalcone) and mesoporous silica, which shows photochromic properties even in dry conditions (not as a solution), was prepared. For obtaining a composite material that displays a color upon ultraviolet irradiation and becomes colorless when stored in the dark, mesoporous silica that contains a small amount of Al was most suitable. On the other hand, mesoporous silica with alkyl trimethyl ammonium ions in the mesopores was most effective for a composite that showed coloration-decoloration cycles induced by alternating irradiation with ultraviolet light of different wavelengths.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (25 results)

All 2012 2011 2010 Other

All Journal Article (8 results) (of which Peer Reviewed: 6 results) Presentation (12 results) Book (2 results) Remarks (3 results)

  • [Journal Article] Ultraviolet Absorption Capabilities of Iron-Containing Mesoporous Silicas Synthesized by Various Methods2012

    • Author(s)
      CHAIKRIANGKRAI Amata, TAKESHITA Yuka, SHIBATA Masashi
    • Journal Title

      Journal of the Japan Society of Colour Material

      Volume: 85 Issue: 11 Pages: 439-448

    • DOI

      10.4011/shikizai.85.439

    • NAID

      10031128402

    • ISSN
      0010-180X, 1883-2199
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photochromism of 2-Hydroxy-4'-Methoxychalcone Adsorbed on Mesoporous Silicate2011

    • Author(s)
      Takakazu Takenouchi, Yuta Kawano, Yasuhiro Takeuchi, Yoshiumi Kohno, Katsuhiko Takagi, Masashi Shibata
    • Journal Title

      Journal of the Japan Society of Colour Material

      Volume: 84 Issue: 9 Pages: 308-312

    • DOI

      10.4011/shikizai.84.308

    • NAID

      10029659759

    • ISSN
      0010-180X, 1883-2199
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Iron-containing Mesoporous Silica Aiming to Use as a New Sunscreen Ultraviolet Absorber2011

    • Author(s)
      Amata Chaikriangkrai, Yuka Takeshita, Masashi Shibata
    • Journal Title

      Chem. Lett

      Volume: 40 Issue: 7 Pages: 693-695

    • DOI

      10.1246/cl.2011.693

    • NAID

      130004426268

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Iron-containing Mesoporous Silica Aiming to Use as a New Sunscreen Ultraviolet Absorber2011

    • Author(s)
      Amata Chaikriangkrai, Yuka Takeshita, Masashi Shibata
    • Journal Title

      Chem.Lett.

      Volume: 40 Pages: 693-695

    • NAID

      10029280474

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic-Inorganic Composites for Color Materials2011

    • Author(s)
      柴田雅史
    • Journal Title

      Journal of the Japan Society of Colour Material

      Volume: 84 Issue: 12 Pages: 421-425

    • DOI

      10.4011/shikizai.84.421

    • NAID

      10030178336

    • ISSN
      0010-180X, 1883-2199
    • Related Report
      2011 Annual Research Report
  • [Journal Article] 美に貢献するナノ技術-メソポーラスシリカの化粧品への応用2011

    • Author(s)
      柴田雅史
    • Journal Title

      化学

      Volume: 66 Pages: 72-73

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Photochromism of a 2-Hydroxy-4'-Methoxychalcone/Silica Composite2010

    • Author(s)
      Yuta Kawano, Takakazu Takenouchi, Yoshiumi Kohono, Ryoka Matsushima, Masashi Shibata
    • Journal Title

      Journal of the Japan Society of Colour Material

      Volume: 83 Issue: 7 Pages: 289-294

    • DOI

      10.4011/shikizai.83.289

    • NAID

      10026797599

    • ISSN
      0010-180X, 1883-2199
    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photochromism of a 2-hydroxy-4'-methoxychalcone/silica composite2010

    • Author(s)
      Yuta Kawano, Masashi Shibata
    • Journal Title

      J.Jpn.Soc.Colour Mater.

      Volume: 83 Pages: 289-294

    • NAID

      10026797599

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 細孔内修飾メソポーラスシリカ/フラビリウム色素複合体の光着消色挙動2012

    • Author(s)
      手島綾乃、河野芳海、柴田雅史
    • Organizer
      色材研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2012-09-21
    • Related Report
      2012 Final Research Report
  • [Presentation] Relationships between the Synthesis Conditions of Fe-Containing MesoporousSilicaandItsEffectivenessas a New Cosmetic Sunscreen Material2012

    • Author(s)
      Amata Chaikriangkrai, Yuka Takeshita, Masashi Shibata
    • Organizer
      14th IACIS
    • Place of Presentation
      仙台国際センター(宮城県)
    • Year and Date
      2012-05-17
    • Related Report
      2012 Final Research Report
  • [Presentation] Relationships between the Synthesis Conditions of Fe-Containing Mesoporous Silica and Its Effectiveness as a New Cosmetic Sunscreen Material2012

    • Author(s)
      Amata Chaikriangkrai, Yuka Takeshita, Masashi Shibata
    • Organizer
      14th IACIS
    • Place of Presentation
      仙台国際センター(宮城県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 疎水性天然色素と有機修飾メソポーラスシリカの複合化2012

    • Author(s)
      加藤恭嗣、柴田雅史、河野芳海、前田康久
    • Organizer
      色材研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 細孔内修飾メソポーラスシリカ/フラビリウム色素複合体の光着消色挙動2012

    • Author(s)
      手島綾乃、河野芳海、柴田雅史
    • Organizer
      色材研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 合成アントシアニンと有機処理メソポーラスシリカの複合体とそのフォトクロミック特性2011

    • Author(s)
      川野裕太,武内貴和,竹内泰宏,河野芳海,高木克彦,柴田雅史
    • Organizer
      色材研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2011-11-15
    • Related Report
      2012 Final Research Report
  • [Presentation] 合成アントシアニンと有機処理メソポーラスシリカの複合体とそのフォトクロミック特性2011

    • Author(s)
      川野裕太, 武内貴和, 竹内泰宏, 河野芳海, 高木克彦, 柴田雅史
    • Organizer
      2011年度色材研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2011-11-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 紫外線吸収剤を目指した鉄含有メソポーラスシリカの合成2011

    • Author(s)
      チャイキェンカイアマタ,竹下侑花,柴田雅史
    • Organizer
      コロイドおよび界面化学討論会
    • Place of Presentation
      京都大学(京都府)
    • Year and Date
      2011-09-08
    • Related Report
      2012 Final Research Report
  • [Presentation] 紫外線吸収剤を目指した鉄含有メソポーラスシリカの合成2011

    • Author(s)
      チャイキェンカイアマタ・竹下侑花・柴田雅史
    • Organizer
      第63回コロイドおよび界面化学討論会
    • Place of Presentation
      京都大学(京都府)
    • Year and Date
      2011-09-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] アントシアニジン色素のAlおよびFe含有メソポーラスシリカへの吸着と安定化2011

    • Author(s)
      早乙女綾, 柴田雅史
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(神奈川県)
    • Year and Date
      2011-03-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] アントシアニジン色素のゼオライトおよびメソポーラスシリカへの吸着特性2010

    • Author(s)
      早乙女綾,柴田雅史
    • Organizer
      色材研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2010-11-05
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Presentation] 2-ヒドロキシ-4'-メトキシカルコン/メソポーラスシリカ複合体のフォトクロミズム2010

    • Author(s)
      武内貴和,高木克彦,柴田雅史
    • Organizer
      光化学討論会
    • Place of Presentation
      千葉大学(千葉県)
    • Year and Date
      2010-09-10
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Book] おもしろサイエンスリップ化粧品の科学2012

    • Author(s)
      柴田雅史
    • Total Pages
      128
    • Publisher
      日刊工業新聞社
    • Related Report
      2012 Final Research Report
  • [Book] おもしろサイエンス リップ化粧品の科学2012

    • Author(s)
      柴田雅史
    • Total Pages
      128
    • Publisher
      日刊工業新聞社
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.shibatalab.org/

    • Related Report
      2012 Final Research Report
  • [Remarks] 柴田研究室の紹介

    • URL

      http://www.shibatalab.org/

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.shibatalab.org/p/blog-page_6399.html

    • Related Report
      2011 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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