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Ship-in-bottle synthesis in mesoporous silica and development of highly functionalized surface

Research Project

Project/Area Number 22550179
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionYokohama National University

Principal Investigator

YOSHITAKE Hideaki  横浜国立大学, 工学研究院, 准教授 (20230716)

Project Period (FY) 2010-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Keywordsメソポーラスシリカ / ナノリアクター / 表面修飾 / 酸化触媒 / 酵素活性 / シップインボトル合成 / 部分酸化触媒 / シクロヘキセン酸化 / 選択性 / メソ細孔性シリカ / グラフト法 / 吸着 / オキシアニオン
Research Abstract

The pores of ordered mesoporous solids could work as nanoreactor. This is evident in the functionalization of mesoporous silica surface with a large surface area, though their preparations and analyses have not been carried out in this standpoint. Since, in the use of catalysts in nanoreactors, functionalization of the mesopore surface is inevitable, we started investigating the most fundamental aspects of surface reactions on the mesopore surface: the order of reactions, controlling the relative rate of diffusion into the pores/surface reaction. Although this approach is simple, we can explore the wide variety of surface structures from the same reactants. We show that several different structures are obtained in transition metal complexes on the surface, which show considerably different catalyses in selective oxidation reactions.

Report

(5 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (35 results)

All 2014 2013 2012 2011 2010 Other

All Journal Article (11 results) (of which Peer Reviewed: 10 results) Presentation (21 results) (of which Invited: 1 results) Book (3 results)

  • [Journal Article] Selenate adsorption on pre-coorinated Fe^<3+>-silane complexes grafted on mesoporous silicas2014

    • Author(s)
      Ryo Otsuka, Hideaki Yoshitake
    • Journal Title

      Journal of Nanoscience and Nanotechnology

      Volume: 14(8) Pages: 6409-6417

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Different modes of adsorptions of arsenate on silica grafted with Fe^3+-coordinated silanes2014

    • Author(s)
      Ryo Otsuka, Hideaki Yoshitake
    • Journal Title

      Journal of Colloid and Interface Science

      Volume: 415 Pages: 143-150

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Grafting of pre-coordinated Cu^<2+>-N-(2-aminoethyl) aminopropylsilane complexes onto mesoporous silicas and the adsorption of aqueous selenate on them2013

    • Author(s)
      Hideaki Yoshitake, Ryo Otsuka
    • Journal Title

      Langmuir

      Volume: 29(33) Pages: 10513-10520

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Adsorptions of iso- and terephthalaldehydes on 3-aminopropyl functionalized SBA-15 with various loadings2013

    • Author(s)
      Teruaki Koizumi, Hideaki Yoshitake
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 86(5) Pages: 657-662

    • NAID

      10031167861

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Grafting of paired 3-aminopropyltrialkoxy silanes onto mesoporous silica and adsorptions of isomers of benzenedialdehydes2013

    • Author(s)
      Hideaki Yoshitake, Teruaki Koizumi, Izuru Kawamura, Akira Naito
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 15(11) Pages: 3946-3954

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 構造規則性メソポーラスチタニアの合成、構造、応用2012

    • Author(s)
      吉武英昭
    • Journal Title

      ゼオライト

      Volume: 29 Pages: 2-8

    • NAID

      40019232190

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Structural transformations of lamellar assembly of polysilsesquioxane nanosheets and arsenate adsorptions on transformed variants2010

    • Author(s)
      Yu Gonda, Yasunori Oumi, Tsuneji Sano, Hideaki Yoshitake
    • Journal Title

      Colloids and Surfaces A, Physicochemical and Engineering Aspects

      Volume: 360 Pages: 159-166

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-pot synthesis of organo-functionalized monodisperse silica particles in W/O microemulsion and the effect of functional groups on addition into polystyrene2010

    • Author(s)
      Yohei Naka, Yoshihiko Komori, Hideaki Yoshitake
    • Journal Title

      Colloids and Surfaces A, Physicochemical and Engineering Aspects

      Volume: 361 Pages: 162-168

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption of transition metal cations onto a lamellar poly(3-aminopropyl)silsesquioxane : cation-cation interaction and transition of adsorption phase2010

    • Author(s)
      Yu Gonda, Hideaki Yoshitake
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 114 Pages: 20076-20082

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design of functionalization and structural analysis of organically-modified siliceous oxides with periodic structures for the development of sorbents for hazardous substances2010

    • Author(s)
      Hideaki Yoshitake
    • Journal Title

      Journal of Materials Chemistry

      Volume: 20 Pages: 4537-4550

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced selectivities in adsorptions of inorganic ions and organic molecules on functionalization of the surfaces of mesoporous silicas

    • Author(s)
      Taiyo Kodate, Keigo Sato, Hideaki Yoshitake
    • Journal Title

      Advanced Porous Materials

      Volume: (in press)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Presentation] メソポーラスシリカにおける表面有機基の細孔内合成と逐次合成2013

    • Author(s)
      佐藤圭悟、吉武英昭
    • Organizer
      横浜国立・市立大学第8回ナノテク交流シンポジウム
    • Place of Presentation
      横浜市立大学
    • Year and Date
      2013-03-06
    • Related Report
      2013 Final Research Report
  • [Presentation] Physicochemical Properties of Surface Organic Groups on Mesostructured Silica and Application to Removal of Aqueous Toxic Ions and Solid Catalyses2013

    • Author(s)
      Hideaki Yoshitake
    • Organizer
      IUMRS-ICA2013 Satellite Symposium (DST-JSPS Symposium,"Nanotechnology Based Innovation for Environmental, Energy & Biomedical Applications")
    • Place of Presentation
      Bangalore, India
    • Related Report
      2013 Final Research Report
  • [Presentation] メソポーラスシリカにおけるシップインボトル合成法の試み2013

    • Author(s)
      佐藤圭悟、吉武英昭
    • Organizer
      第29回ゼオライト研究発表会仙台
    • Place of Presentation
      東北大学
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis of highly ordered 3-aminopropyl-alkylpolysilsesquioxane with improved rate of aqueous ion adsorptions2013

    • Author(s)
      Taiyo Kodate, Hideaki Yoshitake
    • Organizer
      8th International Mesostructured Materials Symposium (IMMS 2013)
    • Place of Presentation
      Awaji
    • Related Report
      2013 Final Research Report
  • [Presentation] メソポーラスシリカにおけるシップインボトル合成法の試み2013

    • Author(s)
      佐藤圭悟、吉武英昭
    • Organizer
      ゼオライト研究発表会
    • Place of Presentation
      東北大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] メソポーラスシリカにおける表面有機基の細孔内合成および逐次合成:細孔構造の影響2012

    • Author(s)
      佐藤圭悟、吉武英昭
    • Organizer
      第28回ゼオライト研究発表会
    • Place of Presentation
      東京(タワーホール船堀)
    • Related Report
      2013 Final Research Report
  • [Presentation] Orientation and Density of Organic Functional Groups on Mesostructured Silicas and their Effects on Adsorption Properties of Organic Adsorbents2012

    • Author(s)
      Hideaki Yoshitake
    • Organizer
      1st International Conference on Emerging Advanced Nanomaterials (ICEAN 2012)
    • Place of Presentation
      Brisbane
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] イオンの吸着速度を向上させたポリシルセスキオキサン高規則性構造体2012

    • Author(s)
      小舘太陽、吉武英昭
    • Organizer
      日本ゾル-ゲル学会第10回討論会
    • Place of Presentation
      横浜市(慶應義塾大学)
    • Related Report
      2013 Final Research Report
  • [Presentation] メソポーラスシリカにおける表面有機基の細孔内合成および逐次 合成:細孔構造の影響2012

    • Author(s)
      吉武英昭
    • Organizer
      ゼオライト研究発表会
    • Place of Presentation
      東京都江戸川区タワーホール船堀
    • Related Report
      2012 Annual Research Report
  • [Presentation] Control of orientation of aminopropyl tethers in mesoporous silica toward selective adsorptions of m- and p-phthalaldehydes2011

    • Author(s)
      Teruaki Koizumi, Hideaki Yoshitake
    • Organizer
      Euromat 2011
    • Place of Presentation
      Montpellier
    • Related Report
      2013 Final Research Report
  • [Presentation] Fine Control of Organic Group on Mesoporous Silica for the Development of Adsorbents of Aqueous Pollutants2011

    • Author(s)
      Hideaki Yoshitake
    • Organizer
      International Workshop on Advanced Functional Nanomaterials
    • Place of Presentation
      Chennai(Keynote Lecture)
    • Related Report
      2013 Final Research Report
  • [Presentation] Control of orientation of aminopropyl tethers in mesoporous silica toward selective adsorptions of m- and p-phthalaldehydes2011

    • Author(s)
      Teruaki Koizumi, Hideaki Yoshitake
    • Organizer
      Euromat 2011
    • Place of Presentation
      Le Corum (Montpellier) (France)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 表面遷移金属錯体によるオキシアニオン吸着におけるアミノ基配位数とメソ細孔構造の効果2011

    • Author(s)
      大塚亮、吉武英昭
    • Organizer
      第27回ゼオライト研究発表会
    • Place of Presentation
      関西学院大学(吹田市)
    • Related Report
      2011 Annual Research Report
  • [Presentation] シリカ表面のアミノプロピル基の配向制御に関するメソ細孔の効果2011

    • Author(s)
      小泉輝明、吉武英昭
    • Organizer
      第27回ゼオライト研究発表会
    • Place of Presentation
      関西学院大学(吹田市)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Electrochemical behavior of Li2MnSiO4 cathode prepared with mesoporous carbon template.2010

    • Author(s)
      T.Kawase, H.Yoshitake
    • Organizer
      Japan-India Forum of Advanced Materials Research for Sustainable Development
    • Place of Presentation
      Yokohama
    • Year and Date
      2010-10-12
    • Related Report
      2010 Annual Research Report
  • [Presentation] Control of Number of Ligands of Adsorption Sites in Mesopores for Optimization of Oxyanion adsorption2010

    • Author(s)
      R.Otsuka, H.Yoshitake
    • Organizer
      JSPS A3 Foresight Seminar, "Present Status and Future Prospects of Mesoporous Materials"
    • Place of Presentation
      Tokyo
    • Year and Date
      2010-09-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] 有機シランニ量体によるメソポーラスシリカの修飾及びアミノブ白ピル基の配向制御2010

    • Author(s)
      小泉輝明、吉武英昭
    • Organizer
      第26回ゼオライト研究発表会
    • Place of Presentation
      東京
    • Related Report
      2010 Annual Research Report
  • [Presentation] 修飾メソポーラスシリカ上の遷移金属カチオンの配位有機基数の制御とオキシアニオン吸着特性の検討2010

    • Author(s)
      大塚亮、吉武英昭
    • Organizer
      第26回ゼオライト研究発表会
    • Place of Presentation
      東京
    • Related Report
      2010 Annual Research Report
  • [Presentation] Adsorption anormalies and interactions between neighbouring transition metal cationson 2-dimensionally packed 3-aminopropyl sites in polysilsesquioxane2010

    • Author(s)
      H.Yoshitake, Y.Gonda
    • Organizer
      International Mesostructured Materials Symposium 7
    • Place of Presentation
      Sorrento (Italia)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Fine Control of Organic Group on Mesoporous Silica for the Development of Adsorbents of Aqueous Pollutants2010

    • Author(s)
      H.Yoshitake
    • Organizer
      International Workshop on Advanced Functional Nanomaterials
    • Place of Presentation
      Chennai (India)
    • Related Report
      2010 Annual Research Report
  • [Presentation] メソポーラスシリカにおける表面有機基の細孔内合成と逐次合

    • Author(s)
      吉武英昭
    • Organizer
      第8回ナノテク交流シンポジウム
    • Place of Presentation
      横浜市立大学
    • Related Report
      2012 Annual Research Report
  • [Book] "Functionalization of Periodic Mesoporous Silica and Its Application to the Adsorption of Toxic Anions"and"Layered Semi-crystalline Polysilsesquioxane : A Mesostructured and Stoichiometric Organic-Inorganic Hybrid Solid for the Removal of Environmentally Hazardous Ions" Environmental Applications of Nanomaterials, Synthesis, Sorbents and Sensors. 2 nd Edition, Chapters 11 and 122012

    • Author(s)
      Hideaki Yoshitake(G. E. Fryxell and B. Cao ed.)
    • Publisher
      Imperial College Press
    • Related Report
      2013 Final Research Report
  • [Book] Environmental Applications of Nanomaterials, Synthesis, Sorbents and Sensors, 2nd Ed.(共著)2012

    • Author(s)
      Hideaki Yoshitake
    • Total Pages
      726
    • Publisher
      Imperial College Press
    • Related Report
      2012 Annual Research Report
  • [Book] 触媒調製ハンドブックの第3編第2章22節2011

    • Author(s)
      吉武英昭、辰巳敬
    • Total Pages
      2
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2011 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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