Relationship between elementary process of reactions and formation of the mesoscopic phase separated structure induced by the chemical reaction.
| Project/Area Number |
22550193
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer/Textile materials
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| Research Institution | Nagoya Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 反応誘起相分離 / 小角X線散乱 / ラジカル共重合 / メソスコピック / 構造形成 / ハイドロゲル / ポリジメチルシロキサン / モノマー反応性比 / 小角散乱 / ラジカル重合 |
|---|
| Research Abstract |
Mechanism of the formation of phase-separated structure induced by radical copolymerization of telechelic poly(dimethyl siloxane)-diacrylate and various vinyl monomers were investigated by mainly time-resolved small angle X-ray scattering and FT-IR spectroscopy. The most important key to determine the phase-separated structure was found to be monomer reactivity ratios. The precise structure of phase-separated network hydrogel was revealed by X-ray contrast variation method.
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Report
(4 results)
Research Products
(25 results)
