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Rheology Control of Nano-particle Dispersionsby Associating Polymers

Research Project

Project/Area Number 22550195
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionKyoto University

Principal Investigator

KOGA Tsuyoshi  京都大学, 大学院・工学研究科, 教授 (80303866)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords会合高分子 / ナノ粒子 / レオロジー / 組み替え網目理論 / 分子動力学シミュレーション / ナノコンポジットゲル / シミュレーション / クレイ / 高分子 / 会合 / 分子機構 / 高伸長性 / 高強度 / 法線応力効果 / クレイナノコンポジットゲル / 弾性
Research Abstract

On rheology control of spherical nanoparticle dispersions by associating polymers, we found an optimum ratio of the number of nanoparticles and polymer chains for the gel formation by molecular dynamics simulations. We also found that, by increasing the chain stiffness, the zero-shear viscosity increases, and the shear thickening behavior is enhanced. On elastic properties of nanocomposite gels, we found by coarse-grained molecular simulations that the molecular origin of the high extensibility of the nanocomposite gels is the dissociation of polymers from clay particles by uniaxial elongation.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (34 results)

All 2013 2012 2011 2010

All Journal Article (11 results) (of which Peer Reviewed: 9 results) Presentation (23 results) (of which Invited: 2 results)

  • [Journal Article] New insights into the effects of molecular weight and end group on the temperature-induced phase transition of poly(N-isopropylacrylamide) in water2013

    • Author(s)
      QIU XingPing, KOGA Tsuyoshi, TANAKA Fumihiko & WINNIK Francoise M
    • Journal Title

      SCIENCE CHINA Chemistry

      Volume: Vol.56、No.1 Issue: 1 Pages: 56-64

    • DOI

      10.1007/s11426-012-4781-9

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rheological properties of physical gel formed by hydrophobically modified urethane ethoxylate (HEUR) associative polymers in methanol-water mixtures2012

    • Author(s)
      Isamu Kaneda, Tsuyoshi Koga, and Fumihiko Tanaka
    • Journal Title

      Rheologica Acta

      Volume: 51 Issue: 1 Pages: 89-96

    • DOI

      10.1007/s00397-011-0571-0

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exclusion of Impurity Particles during Grain Growth in Charged Colloidal Crystals2011

    • Author(s)
      Koki Yoshizawa, Tohro Okuzono, Tsuyoshi Koga, Tomohiro Taniji, and Junpei Yamanaka
    • Journal Title

      Langmuir

      Volume: Vol.27、No.22 Issue: 22 Pages: 13420-13427

    • DOI

      10.1021/la202899v

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydration, phase separation and nonlinear rheology of temperature-sensitive water-soluble polymers2011

    • Author(s)
      Fumihiko Tanaka, Tsuyoshi Koga, IsamuKaneda, and Fran.coise M. Winnik
    • Journal Title

      Journal of Physics : Condensed Matter

      Volume: Vol.23、No.28 Issue: 28 Pages: 2841051-7

    • DOI

      10.1088/0953-8984/23/28/284105

    • NAID

      120003290276

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 会合高分子ダイナミックスの理論・シミュレーション2011

    • Author(s)
      古賀毅、田中文彦
    • Journal Title

      高分子

      Volume: Vol.60、No.4 Pages: 186-189

    • NAID

      10027971851

    • Related Report
      2012 Final Research Report
  • [Journal Article] Preferential Adsorption and Co-nonsolvency of Thermoresponsive Polymers in Mixed Solvents of Water/Methanol2011

    • Author(s)
      Fumihiko Tanaka, Tsuyoshi Koga, Hiroyuki Kojima, Na Xue, and Fran.coise M. Winnik
    • Journal Title

      Macromolecules

      Volume: vol.44、No.8 Issue: 8 Pages: 2978-2989

    • DOI

      10.1021/ma102695n

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydration and phase separation of temperature-sensitive water-soluble polymers2011

    • Author(s)
      Fumihiko Tanaka, Tsuyoshi Koga, Hiroyuki Kojima and Fran.coise M. Winnik
    • Journal Title

      Chinese Journal of Polymer Science

      Volume: vol.29、No.1 Issue: 1 Pages: 13-21

    • DOI

      10.1007/s10118-010-1018-2

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] 会合高分子ダイナミックスの理論・シミュレーション2011

    • Author(s)
      古賀毅, 田中文彦
    • Journal Title

      高分子

      Volume: 60 Pages: 186-189

    • NAID

      10027971851

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Theoretical Modelling of Hierarchically Associated Structures inHydrophobically Modified PNIPAM Aqueous Solutions on the Basis of a Neutron Scattering Study2010

    • Author(s)
      Tsuyoshi Koga, Fumihiko Tanaka, Ryuhei Motokawa, Satoshi Koizumi, and Fran.coise M.Winnik
    • Journal Title

      Macromolecular Symposia

      Volume: vol.291-292 Issue: 1 Pages: 177-185

    • DOI

      10.1002/masy.201050521

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Predictions on Normal Stresses under Shear Flow in Transient Networks of Telechelic Associating Polymers2010

    • Author(s)
      T.Koga, F.Tanaka
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 3052-3060

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Modelling of Hierarchically Associated Structures in Hydrophobically Modified PNIPAM Aqueous Solutions on the Basis of a Neutron Scattering Study2010

    • Author(s)
      T.Koga, F.Tanaka, R.Motokawa, S.Koizumi, F.M.Winnik
    • Journal Title

      MACROMOLECULAR SYMPOSIA

      Volume: 291-292 Pages: 177-185

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Structure Formation andRheology of Associating Polymers2012

    • Author(s)
      Tsuyoshi Koga
    • Organizer
      5th International Symposium on Polymer Materials Science (ISPMS'12) & 8th Osaka University Macromolecular Symposium (OUMS'12)
    • Place of Presentation
      Osaka University,Toyonaka, Osaka, Japan
    • Year and Date
      2012-11-10
    • Related Report
      2012 Final Research Report
  • [Presentation] 会合高分子の構造形成とレオロジー2012

    • Author(s)
      古賀毅
    • Organizer
      平成24年度繊維学会秋季研究発表会
    • Place of Presentation
      福井大学
    • Year and Date
      2012-09-25
    • Related Report
      2012 Final Research Report
  • [Presentation] 理論・シミュレーションによる網目構造と弾性有効鎖2012

    • Author(s)
      古賀毅
    • Organizer
      田中豊一記念シンポジウム2012
    • Place of Presentation
      酪農学園大学
    • Year and Date
      2012-06-30
    • Related Report
      2012 Final Research Report
  • [Presentation] 剪断流動下における会合高分子のコンフォメーション転移とシア・シックニング2012

    • Author(s)
      古賀毅
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2012-05-29
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] テレケリック会合高分子の構造形成とレオロジー2012

    • Author(s)
      古賀毅,田中文彦
    • Organizer
      第9回京都大学福井謙一記念研究センターシンポジウム
    • Place of Presentation
      京都大学福井謙一記念研究センター
    • Year and Date
      2012-01-06
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] テレケリック会合高分子の構造形成とレオロジー2012

    • Author(s)
      古賀 毅
    • Organizer
      平成24年度繊維学会秋季研究発表会
    • Place of Presentation
      福井大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Structure Formation and Rheology of Associating Polymers2012

    • Author(s)
      Tsuyoshi Koga
    • Organizer
      Joint Symposium 5th International Symposium on Polymer Materials Science (ISPMS'12) & 8th Osaka University Macromolecular Symposium (OUMS'12)
    • Place of Presentation
      大阪大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 架橋多重度が固定された物理ゲルのモンテカルロシミュレーションによる構造解析2012

    • Author(s)
      尾﨑弘人,古賀毅
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] 会合高分子系におけるネットワーク形成のシミュレーション-分子内会合,分子間会合の効果2012

    • Author(s)
      松本純,古賀毅
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] 架橋多重度が固定されたテレケリック会合高分子のネットワーク形成と力学物性2012

    • Author(s)
      尾﨑弘人,古賀毅
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 分子内・分子間会合転移により誘起されたシア・シックニング2012

    • Author(s)
      松本純,古賀毅
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 架橋多重度が固定されたテレケリック会合高分子のネットワーク形成と力学物性2012

    • Author(s)
      尾﨑弘人,古賀毅
    • Organizer
      第60回レオロジー討論会
    • Place of Presentation
      名古屋大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Network formation and mechanical property of telechelic associating polymers with fixed junction multiplicity2012

    • Author(s)
      Hiroto Ozaki, Tsuyoshi Koga
    • Organizer
      Joint Symposium 5th International Symposium on Polymer Materials Science (ISPMS'12) & 8th Osaka University Macromolecular Symposium (OUMS'12)
    • Place of Presentation
      大阪大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Network formation and mechanical property of telechelic associating polymers with fixed junction multiplicity2012

    • Author(s)
      Hiroto Ozaki, Tsuyoshi Koga
    • Organizer
      The 9th SPSJ International Polymer Conference(IPC 2012)
    • Place of Presentation
      Kobe International Conference Center
    • Related Report
      2012 Annual Research Report
  • [Presentation] テレケリックPNIPAMの感熱性とレオロジーII-応力成長と非線形レオロジ2011

    • Author(s)
      古賀毅,田中文彦,前田朋子,吉田奈央,四方俊幸,遊佐真一,WINNIK Francoise M
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      2011-09-28
    • Related Report
      2012 Final Research Report
  • [Presentation] テレケリックPNIPAMの感熱性とレオロジーII-応力成長と非線形レオロジー2011

    • Author(s)
      古賀毅
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] テレケリックPNIPAMの感熱性とレオロジー2011

    • Author(s)
      古賀毅,田中文彦,前田朋子,四方俊幸,Winnik Francoise M
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場
    • Year and Date
      2011-05-27
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] テレケリックPNIPAMの感熱性とレオロジー2010

    • Author(s)
      古賀毅,田中文彦,前田朋子,四方俊幸,F.M.Winnik
    • Organizer
      田中豊一記念シンポジウム2010
    • Place of Presentation
      京都大学
    • Year and Date
      2010-11-20
    • Related Report
      2012 Final Research Report
  • [Presentation] テレケリックPNIPAMの感熱性とレオロジー2010

    • Author(s)
      古賀毅,田中文彦,前田朋子,四方俊幸,F.M.Winnik
    • Organizer
      第58回レオロジ-討論会
    • Place of Presentation
      仙台国際センター
    • Year and Date
      2010-10-04
    • Related Report
      2012 Final Research Report
  • [Presentation] Rheology of Transient Networks of Telechelic Associating Polymers2010

    • Author(s)
      Tsuyoshi Koga
    • Organizer
      International Symposium on Non-Equilibrium Soft Matter 2010
    • Place of Presentation
      奈良県新公会堂
    • Year and Date
      2010-08-17
    • Related Report
      2012 Final Research Report
  • [Presentation] Rheology of Transient Networks in Telechelic Associating Polymers2010

    • Author(s)
      T. Koga and F. Tanaka
    • Organizer
      5th Pacific Rim Conference on Rheology (PRCR-5)
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-08-06
    • Related Report
      2012 Final Research Report
  • [Presentation] Rheology of Transient Networks in Telechelic Associating Polymers2010

    • Author(s)
      T.Koga, F.Tanaka
    • Organizer
      5th Pacific Rim Conference on Rheology
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-08-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] テレケリックPNIPAMフラワーミセル充填系の感熱性とレオロジー2010

    • Author(s)
      古賀毅,田中文彦,安中雅彦,Winnik Francoise
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2010-05-27
    • Related Report
      2012 Final Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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