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Understanding and control of the epitaxial multilayer growth of aromatic molecules on single crystalline metal substrates

Research Project

Project/Area Number 22560006
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionJapan Advanced Institute of Science and Technology

Principal Investigator

FRIEDLEIN Rainer  北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 准教授 (80452118)

Co-Investigator(Kenkyū-buntansha) TAKAMURA Yukiko (YAMADA Yukiko)  北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 准教授 (90344720)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords有機エレクトロニクス / 光電子分光 / エピタキシャル成長
Research Abstract

The epitaxial growth of single-crystalline-like organic multilayer films on selected metal surfaces, chosen to provide either weak or strong interactions at the hybrid interface, has been studied. In particular, while molecules containing heteroatoms form site-specific covalent bonds, the growth of oligoacenes on the Cu(110) surface is characterized by extended interfacial states and a flat molecular orientation in the first layer. On the contrary, for surfaces providing weak interactions like Bi(001) and silicene, both standing and flat orientations occur and are governed by the specific lattice-matching conditions for various crystallographic planes of the thin film crystals. The results provide a detailed understanding of the influence of the substrate beyond the widely studied first layer in achieving epitaxial growth and uniaxial alignment of the grains.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (56 results)

All 2013 2012 2011 2010 Other

All Journal Article (22 results) (of which Peer Reviewed: 20 results) Presentation (29 results) (of which Invited: 1 results) Remarks (5 results)

  • [Journal Article] Silicene: atomthick silicon with tunable properties2013

    • Author(s)
      R. Friedlein, A. Fleurence, T. Ozaki, Y. Yamada- Takamura
    • Journal Title

      SPIE Newsroom

    • Related Report
      2012 Final Research Report
  • [Journal Article] シリセン:ケイ素で出来たグラフェン?2013

    • Author(s)
      Y. Yamada-Takamura, A. Fleurence, R. Friedlein, T. Ozaki
    • Journal Title

      日本物理学会誌

      Volume: 68 Pages: 305-308

    • Related Report
      2012 Final Research Report
  • [Journal Article] Molecular order charge injection efficiency and the role of intramolecular polar bonds at organic/organic heterointerfaces2012

    • Author(s)
      Y. Wang, T. Matsushima, H. Murata, A. Fleurence, Y. Yamada-Takamura, R. Friedlein
    • Journal Title

      Org. Electr. 13

      Pages: 1853-1858

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Experimental evidence for epitaxial silicene on diboride thin films2012

    • Author(s)
      A. Fleurence, R. Friedlein, T. Ozaki, H. Kawai, Y. Wang, Y. Yamada-Takamura
    • Journal Title

      Phys. Rev. Lett. 108

      Pages: 245501-245501

    • NAID

      120004945375

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Experimental evidence for epitaxial silicene on diboride thin films2012

    • Author(s)
      A. Fleurence, R. Friedlein, T. Ozaki, H. Kawai, Y. Wang, Y. Yamada-Takamura
    • Journal Title

      Phys. Rev. Lett.

      Volume: 108 Issue: 24 Pages: 245501-245501

    • DOI

      10.1103/physrevlett.108.245501

    • NAID

      120004945375

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular order, charge injection efficiency and the role of intramolecular polar bonds at organic/organic heterointerfaces2012

    • Author(s)
      Y. Wang, T. Matsushima, H. Murata, A. Fleurence, Y. Yamada-Takamura, R. Friedlein
    • Journal Title

      Org. Electr.

      Volume: 13 Issue: 10 Pages: 1853-1858

    • DOI

      10.1016/j.orgel.2012.05.038

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intermolecular band dispersion in quasi-one-dimensional adenine assemblies2011

    • Author(s)
      Y. Wang, A. Fleurence, Y. Yamada-Takamura, R. Friedlein
    • Journal Title

      Chem. Commun.47

      Pages: 12349-12351

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultra-fast charge transfer in organic electronic materials and at hybrid interfaces studied using the core-hole clock technique2011

    • Author(s)
      R. Friedlein, S. Braun, M. P. de Jong, W. Osikowicz, M. Fahlman, W. R. Salaneck
    • Journal Title

      J. Electr. Spectr. Relat. Phenom. 183

      Pages: 101-106

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structure-dependent band dispersion in epitaxial anthracene films2011

    • Author(s)
      F. Bussolotti, Y. Yamada-Takamura, Y. Wang, R. Friedlein
    • Journal Title

      J. Chem. Phys. 135

      Pages: 124709-124709

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of oxygen on the electronic structure of highly crystalline picene films2011

    • Author(s)
      Y. Wang, S. Di Motta, F. Negri, R. Friedlein
    • Journal Title

      J. Am. Chem. Soc. 133

      Pages: 10054-10057

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intermolecular band dispersions in quasi-one-dimensional adenine assemblies2011

    • Author(s)
      Y.Wang, A.Fleurence, Y.Yamada-Takamura, R.Friedlein
    • Journal Title

      Chemical Communications

      Volume: 47 Issue: 45 Pages: 12349-51

    • DOI

      10.1039/c1cc14942c

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure-dependent band dispersion in epitaxial anthracene films2011

    • Author(s)
      F.Bussolotti, Y.Yamada-Takamura, Y.Wang, R.Friedlein
    • Journal Title

      Journal of Chemical Physics

      Volume: 135 Issue: 12

    • DOI

      10.1063/1.3643717

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of oxygen on the electronic structure of highly-crystalline picene films2011

    • Author(s)
      Y.Wang, S.Di Motta, F.Negri, R.Friedlein
    • Journal Title

      Journal of the American Chemical Society (Comm.)

      Volume: 133 Issue: 26 Pages: 10054-7

    • DOI

      10.1021/ja204011j

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stacks of nucleic acids as molecular wires: Direct measurement of the intermolecular band dispersion in multilayer guanine assemblies2010

    • Author(s)
      R. Friedlein, Y. Wang, A. Fleurence, F. Bussolotti, Y. Ogata, Y. Yamada-Takamura
    • Journal Title

      J. Am. Chem. Soc. 132

      Pages: 12808-12808

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hybrid interfaces of biological molecules and metals: The prototypical case of adenine on Cu(110)2010

    • Author(s)
      F. Bussolotti, R. Friedlein
    • Journal Title

      J. Chem. Phys. 132

      Pages: 184705-184705

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hybridization and charge transfer at the anthracene/Cu(110) interface: Comparison to pentacene2010

    • Author(s)
      F. Bussolotti, R. Friedlein
    • Journal Title

      Phys. Rev. B 81

      Pages: 115457-115457

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultra-fast charge transfer in organic electronic materials and at hybrid interfaces studied using the core-hole clock technique2010

    • Author(s)
      R.Friedlein, S.Braun, M.P.de Jong, W.Osikowicz, M.Fahlman, W.R.Salaneck
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena

      Volume: 183 Pages: 101-106

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intermolecular band dispersions in single-crystalline anthracene multilayer films2010

    • Author(s)
      F.Bussolotti, Y.Yamada-Takamura, R.Friedlein
    • Journal Title

      Physical Review B

      Volume: 80

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hybridization and charge transfer at the anthracene/Cu(110) interface : Comparison to pentacene2010

    • Author(s)
      F.Bussolotti, R.Friedlein
    • Journal Title

      Physical Review B

      Volume: 81

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hybrid interfaces of biological molecules and metals : The prototypical case of adenine on Cu(110)2010

    • Author(s)
      F.Bussolotti, R.Friedlein
    • Journal Title

      J.Chemical Physics

      Volume: 132

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stacks of nucleic acids as molecular wires : Direct measurement of the intermolecular band dispersion in multilayer guanine assemblies2010

    • Author(s)
      R.Friedlein, Y.Wang, A.Fleurence, F.Bussolotti, Y.Ogata, Y.Yamada-Takamura
    • Journal Title

      Journal of the American Chemical Society (Comm.)

      Volume: 132 Pages: 12808-12810

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface electronic structure of ZrB_2 buffer layers for GaN growth on Si wafers2010

    • Author(s)
      Y.Yamada-Takamura, F.Bussolotti, A.Fleurence, S.Bera, R.Friedlein
    • Journal Title

      Applied Physics Letters

      Volume: 97

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Epitaxial silicene-tunable hybriddization with the substrate and weak interactions with epitaxial organic overlayers2013

    • Author(s)
      R. Friedlein, A. Fleurence, F. Bussolotti, Y. Yamada-Takamura
    • Organizer
      Spring Meeting of the German Physical Society
    • Place of Presentation
      Regensburg, Germany
    • Year and Date
      2013-03-13
    • Related Report
      2012 Final Research Report
  • [Presentation] Epitaxial silicene - tunable hybridization with the substrate and weak interactions with epitaxial organic overlayers2013

    • Author(s)
      R. Friedlein, A. Fleurence, F. Bussolotti, Y. Yamada-Takamura
    • Organizer
      Spring Meeting of the German Physical Society
    • Place of Presentation
      Regensburg, Germany
    • Related Report
      2012 Annual Research Report
  • [Presentation] Genetic matter as high mobility materials-the intermolecular band dispersion in guanosine and mixed guanosine-cytosine assemblies2012

    • Author(s)
      R. Friedlein, A. Fleurence
    • Organizer
      6th Intl. Meeting on Molecular Electronics
    • Place of Presentation
      Grenoble, France
    • Year and Date
      2012-12-05
    • Related Report
      2012 Final Research Report
  • [Presentation] Epitaxial silicene on ZrB2 buffer layers: Structure and electronic properties2012

    • Author(s)
      A. Fleurence, R. Friedlein, T. Ozaki, Y. Wang, Y. Yamada-Takamura
    • Organizer
      Spring Meeting of the European Materials Research Society
    • Place of Presentation
      Strasbourg, France
    • Year and Date
      2012-05-12
    • Related Report
      2012 Final Research Report
  • [Presentation] Silicene - buckling induced gap opening and tuneable interactions with the substrate2012

    • Author(s)
      R. Friedlein
    • Organizer
      MESA+ Institute of Nanotechnology, University of Twente
    • Place of Presentation
      Enschede, The Netherlands
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Genetic matter as high-mobility materials - the intermolecular band dispersion in guanosine and mixed guanosine-cytosine assemblies2012

    • Author(s)
      R. Friedlein, A. Fleurence
    • Organizer
      6th Intl. Meeting on Molecular Electronics (ELECMOL’ 6)
    • Place of Presentation
      Grenoble, France
    • Related Report
      2012 Annual Research Report
  • [Presentation] Stacks of nucleic acids as molecular wires: Measurement of the intermolecular band dispersion in guanine and adenine assemblies2011

    • Author(s)
      R. Friedlein, Y. Wang, A. Fleurence, F. Bussolotti, Y. Ogata, Y. Yamada-Takamura
    • Organizer
      6th Intl. Symp. on Surface Science
    • Place of Presentation
      東京
    • Year and Date
      2011-12-13
    • Related Report
      2012 Final Research Report
  • [Presentation] Stacks of nucleic acids as molecular wires : Measurement of the intermolecular band dispersion in guanine and adenine assemblies2011

    • Author(s)
      R.Friedlein, Y.Wang, A.Fleurence, F.Bussolotti, Y.Ogata, Y.Yamada-Takamura
    • Organizer
      6^<th> Intl.Symposium on Surface Science (ISSS-VI)
    • Place of Presentation
      タワーホール船堀,東京
    • Year and Date
      2011-12-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] Extended electronic states in self-assembled genetic matter2011

    • Author(s)
      R.Friedlein
    • Organizer
      6^<th> Japan-Sweden Workshop on 'Advanced Spectroscopy of Organic Materials for Electronic Applications' (ASOMEA-VI)
    • Place of Presentation
      加賀温泉,石川県(invited)
    • Year and Date
      2011-11-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Extended electronic states in self-assembled genetic matter2011

    • Author(s)
      R. Friedlein
    • Organizer
      6th Japan-Sweden Workshop on'Advanced Spectroscopy of Organic Materials for Electronic Applications'
    • Place of Presentation
      加賀温泉
    • Year and Date
      2011-11-25
    • Related Report
      2012 Final Research Report
  • [Presentation] Effect of oxygen on the electronic structure of highlycrystalline picene films2011

    • Author(s)
      Y. Wang, S. Di Motta, F. Negri, R. Friedlein
    • Organizer
      6th Japan-Sweden Workshop on'Advanced Spectroscopy of Organic Materials for Electronic Applications'
    • Place of Presentation
      加賀温泉
    • Year and Date
      2011-11-25
    • Related Report
      2012 Final Research Report
  • [Presentation] Effect of oxygen on the electronic structure of highly-crystalline picene films2011

    • Author(s)
      Y.Wang, S.Di Motta, F.Negri, R.Friedlein
    • Organizer
      6^<th> Japan-Sweden Workshop on 'Advanced Spectroscopy of Organic Materials for Electronic Applications' (ASOMEA-VI)
    • Place of Presentation
      加賀温泉,石川県
    • Year and Date
      2011-11-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] Experimental study of epitaxial silicene on zirconium diboride2011

    • Author(s)
      A.Fleurence, T.Ozaki, Y.Wang, R.Friedlein, Y.Yamada-Takamura
    • Organizer
      6^<th> Japan-Sweden Workshop on 'Advanced Spectroscopy of Organic Materials for Electronic Applications' (ASOMEA-VI)
    • Place of Presentation
      加賀温泉,石川県
    • Year and Date
      2011-11-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] Bonding and electronic states at organic/metal interfaces with strong interactions2011

    • Author(s)
      R. Friedlein
    • Organizer
      6th Intl. Workshop on 'Electronic Structure and Processes at Molecular-based Interfaces'
    • Place of Presentation
      Karlsruhe, Germany
    • Year and Date
      2011-09-27
    • Related Report
      2012 Final Research Report
  • [Presentation] Bonding and electronic states at organic/metal interfaces with strong interactions2011

    • Author(s)
      R.Friedlein
    • Organizer
      6^<th> Intl.Workshop on 'Electronic Structure and Processes at Molecular-based Interfaces' (ESPMI-VI)
    • Place of Presentation
      カールスルーエ、ドイツ(invited)
    • Year and Date
      2011-09-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Epitaxial silicene layer formed on ZrB2 thin films-Silicene?2011

    • Author(s)
      A.Fleurence, R.Friedlein, Y.Wang, F.Bussolotti, Y.Yamada-Takamura
    • Organizer
      38^<th> Intl.Conf.on Metallurgical Coatings and Thin Films (ICMCFT 2011)
    • Place of Presentation
      サンディエゴ、アメリカ
    • Year and Date
      2011-05-05
    • Related Report
      2011 Annual Research Report
  • [Presentation] Epitaxial silicene formed on single-crystalline ZrB_2 thin films : structure and electronic properties2011

    • Author(s)
      A.Fleurence, R.Friedlein, Y.Wang, Y.Yamada-Takamura
    • Organizer
      American Physical Society March Meeting 2011
    • Place of Presentation
      ダラス、アメリカ
    • Year and Date
      2011-03-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] Epitaxial silicene on diboride thin films2011

    • Author(s)
      Y.Yamada-Takamura, A.Fleurence, H.Kawai, Y.Wang, T.Ozaki, R.Friedlein
    • Organizer
      The 2011 WPI-AIMR Annual Workshop
    • Place of Presentation
      Tohoku University、仙台
    • Year and Date
      2011-02-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] Experimental evidence for silicene on ZrB_2(0001)2011

    • Author(s)
      A.Fleurence, R.Friedlein, Y.Wang, Y.Yamada-Takamura
    • Organizer
      Symposium on Surface and Nano Science 2011 (SSNS'11)
    • Place of Presentation
      雫石
    • Year and Date
      2011-01-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] Electronic properties and charge transport in extraordinary organic materials : from DNA bases to superconducting picene2011

    • Author(s)
      R.Friedlein
    • Organizer
      CNSI-JAIST workshop
    • Place of Presentation
      University of California、ロサンジェルス、アメリカ(invited)
    • Year and Date
      2011-01-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] Peculiar electronic structure of K intercalated and O2 exposed picene-why are the transport properties of doped picene so special2010

    • Author(s)
      R. Friedlein, Y. Wang
    • Organizer
      5th Intl. Meeting on Molecular Electronics
    • Place of Presentation
      Grenoble, France
    • Year and Date
      2010-12-09
    • Related Report
      2012 Final Research Report
  • [Presentation] Surface study of ZrB_2 thin films grown on Si(111)2010

    • Author(s)
      A.Fleurence, W.Y.Zhang, Y.Wang, R.Friedlein, Y.Yamada-Takamura
    • Organizer
      European Conference on Surface Science 27 (ECOSS27)
    • Place of Presentation
      フローニンゲン、オランダ
    • Year and Date
      2010-08-31
    • Related Report
      2010 Annual Research Report
  • [Presentation] Hybrid electronic states at anthracene /Cu(110) and adenine/Cu(110) interfaces2010

    • Author(s)
      R. Friedlein, F. Bussolotti
    • Organizer
      Intl. Vacuum Congress
    • Place of Presentation
      Beijing, China
    • Year and Date
      2010-08-26
    • Related Report
      2012 Final Research Report
  • [Presentation] Hybrid electronic states at anthracene/Cu(110) and adenine/Cu(110) interfaces2010

    • Author(s)
      R.Friedlein, F.Bussolotti
    • Organizer
      International Vacuum Congress (IVC 18)
    • Place of Presentation
      北京、中国
    • Year and Date
      2010-08-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Structure-dependent, intermolecular band dispersion in anthracene multilayer films2010

    • Author(s)
      F.Bussolotti, Y.Yamada-Takamura, R.Friedlein
    • Organizer
      International Vacuum Congress (IVC 18)
    • Place of Presentation
      北京、中国
    • Year and Date
      2010-08-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Direct measurement of the intermolecular band dispersion in guanine assemblies2010

    • Author(s)
      Y.Wang, Y.Yamada-Takamura, A.Fleurence, F.Bussolotti, Y.Ogata, R.Friedlein
    • Organizer
      International Vacuum Congress (IVC 18)
    • Place of Presentation
      北京、中国
    • Year and Date
      2010-08-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Study of the structural and electronic properties of epitaxial Si layers on ZrB_2 thin films2010

    • Author(s)
      A.Fleurence, Y.W.Zhang, Y.Wang, R.Friedlein, Y.Yamada-Takamura
    • Organizer
      International Vacuum Congress (IVC 18)
    • Place of Presentation
      北京、中国
    • Year and Date
      2010-08-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Direct measurement of the intermolecular band dispersion in guanine assemblies2010

    • Author(s)
      Y.Wang, Y.Yamada-Takamura, A.Fleurence, F.Bussolotti, Y.Ogata, R.Friedlein
    • Organizer
      EM-NANO 2010
    • Place of Presentation
      富山
    • Year and Date
      2010-06-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] Structure-dependent, intermolecular band dispersion in anthracene multilayer films2010

    • Author(s)
      R.Friedlein, Y.Yamada-Takamura, F.Bussolotti
    • Organizer
      EM-NANO 2010
    • Place of Presentation
      富山
    • Year and Date
      2010-06-24
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.jaist.ac.jp/ms/labs/friedl/

    • Related Report
      2012 Final Research Report
  • [Remarks] 研究室ホームページ

    • URL

      http://www.jaist.ac.jp/ms/labs/friedl/

    • Related Report
      2012 Annual Research Report
  • [Remarks] [プレスリリース]世界で初めてシリセンの構造と性質の関係を実験から解明

    • URL

      http://www.jaist.ac.jp/news/press/2012/post-322.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.jaist.ac.jp/ms/labs/friedl/

    • Related Report
      2011 Annual Research Report
  • [Remarks] URL

    • URL

      http://www.jaist.ac.jp/ms/labs/friedl/

    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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