Fabrication ofn-type phthalocyanine nano-rods by CVD technique and organic photovoltaic cells

• Project/Area Number: 22560052
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Applied physics, general
• Research Institution: Kobe University
• Principal Investigator: KOSHIBA Yasuko 神戸大学, 大学院・工学研究科, 助手 (70243326)
• Co-Investigator(Kenkyū-buntansha): UEDA Yasukiyo 神戸大学, 大学院・工学研究科, 教授 (40116190) ; ISHIDA Kenji 神戸大学, 大学院・工学研究科, 准教授 (20303860)
• Project Period (FY): 2010 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000); Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2010: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
• Keywords: エネルギー変換 / 有機薄膜太陽電池 / 化学気相成長法 / ナノロッド構造 / n 型有機半導体 / n型有機半導体 / 有機薄膜太陽霞池

Research Abstract

Octacyanophthalocyanine (OcPc) nanorods were fabricated on a single KCl crystal. The diameters and lengths of nanorods ware controlled. The OcPc film exhibited n-type conduction characteristics, and the energy of the highest occupied molecular orbital was determined to be 5.8 eV. OPV cells using fluorinated phthalocyanine as electron acceptor were evaluated. OcPc nanorods were also fabricated on vacuum-deposited LiF or Cu. Photovoltaic power was observed in cells containing OcPc as an n-type semiconductor.

Research Products

• [Journal Article] Fabrication and Semiconducting Properties of Monodisperse n-Type Phthalocyanine Nanograss (2013)
  • Author(s): H. Saeki, M. Nishimoto, Y. Koshiba, M. Misaki, K. Ishida, Y. Ueda
  • Journal Title: Thin Solid Films Volume: Vol.531 Pages: 513-518
  • DOI: 10.1016/j.tsf.2013.01.009
  • Peer Reviewed
• [Journal Article] p 型/n 型界面での電荷分離特性向上に向けた強誘電体分子超薄膜との界面形成 (2012)
  • Author(s): 大杉拓也、小柴康子、三崎雅裕、石田謙司、上田裕清
  • Journal Title: 信学技報 IEICE Technical Report Volume: Vol.112 Pages: 55-59
  • NAID: 110009642065
• [Journal Article] p型/n型界面での電荷分離特性向上に向けた強誘電体分子超薄膜との界面形成 (2012)
  • Author(s): 大杉拓也、小柴康子、三崎雅裕、石田謙司、上田裕清
  • Journal Title: 信学技報 IEICE Technical Report Volume: Vol.112, No.304 Pages: 55-59
  • NAID: 110009642065
• [Journal Article] In-plane Orientation of Fluorescent Molecules in Friction-transferred Films (2011)
  • Author(s): Y. Koshiba, M. Misaki, K. Kanda, H. Miyaji, K. Ishida, Y. Ueda
  • Journal Title: Chemistry Letters Volume: Vol.40, No.11 Issue: 11 Pages: 1288-1299
  • DOI: 10.1246/cl.2011.1288
  • NAID: 130004426095
  • Peer Reviewed
• [Journal Article] Crystalline Thin Films of β-Phase Poly(9,9-dioctylfluorene) (2011)
  • Author(s): Takuji Kawamura
  • Journal Title: Thin Solid Films Volume: 519 Pages: 2247-2250
  • Peer Reviewed
• [Journal Article] Organic Solvent Based TiO_2 Dispersion Paste for Dye Sensitized Solar Cells Prepared by Industrial Production Level Procedure (2011)
  • Author(s): Ryohei Mori
  • Journal Title: J.Materials Science Volume: 46 Pages: 8272-8278
  • Peer Reviewed
• [Journal Article] Current-Voltage Characteristics of Organic Photovoltaic Cells Following Deposition of Cathode Electrode (2010)
  • Author(s): H. Saeki, K. Hirohara, Y. Koshiba, S. Horie, M. Misaki, K. Takeshita, K. Ishida, Y. Ueda
  • Journal Title: Applied Physics Letters Volume: Vol.97 Issue: 19
  • DOI: 10.1063/1.3516469
  • Peer Reviewed
• [Journal Article] Current-Voltage Characteristics of Organic Photovoltaic Cells Following Deposition of Cathode Electrode (2010)
  • Author(s): Hiroyuki Saeki
  • Journal Title: Applied Physics Letters Volume: 97
  • Peer Reviewed
• [Presentation] 気固相反応によるオクタシアノフタロシアニン薄膜生成過程の考察 (2013)
  • Author(s): 西本 光穂子,佐伯 宏之,小柴 康子,三崎 雅裕,石田 謙司,上田 裕清
  • Organizer: 2013 年第60回応用物理学会春季学術講演会
  • Place of Presentation: 厚木市
• [Presentation] Fabrication and Evaluation of Organic Photovoltaic Cells Using Fluorinated Phthalocyanines as electron acceptor (2013)
  • Author(s): Y. Koshiba, T. Ohnishi, H. Saeki, M. Misaki, K. Ishida, Y. Ueda
  • Organizer: Seventh International Conference on Molecular Electronics and Bioelectronics (M&BE7)
  • Place of Presentation: Fukuoka, Japan
• [Presentation] Fabrication and Evaluation of Organic Photovoltaic Cells Using Fluorinated Phthalocyanines as electron acceptor (2013)
  • Author(s): Y. Koshiba, T. Ohnishi, H. Saeki, M. Misaki, K. Ishida, Y. Ueda
  • Organizer: Seventh International Conference on Molecular Electronics and Bioelectronics (M&BE7)
  • Place of Presentation: Fukuoka, Japan
• [Presentation] 気固相反応によるオクタシアノフタロシアニン薄膜生成過程の考察 (2013)
  • Author(s): 西本 光穂子，佐伯 宏之，小柴 康子，三崎 雅裕，石田 謙司，上田 裕清
  • Organizer: 2013年第60回応用物理学会春季学術講演会
  • Place of Presentation: 厚木市
• [Presentation] 大西俊輝,佐伯宏之,小柴 康子,三崎 雅裕,石田 謙司,上田 裕清 (2012)
  • Author(s): 大西俊輝,佐伯宏之,小柴 康子,三崎 雅裕,石田 謙司,上田 裕清
  • Organizer: 第58回高分子研究発表会(神戸)
  • Place of Presentation: 神戸市
  • Year and Date: 2012-07-13
• [Presentation] フッ化リチウム蒸着膜上でのオクタシアノフタロシアニン薄膜の生成と評価 (2012)
  • Author(s): 佐伯宏之, 他6名
  • Organizer: 第59回応用物理学関係連合講演会
  • Place of Presentation: 早稲田大学早稲田キャンパス
  • Year and Date: 2012-03-17
• [Presentation] Fabrication and photovoltaic characterization of K2Pc(CN)8- complex nano-rod (2012)
  • Author(s): H. Saeki, M. Nishimoto, Y. Koshiba, M. Misaki, K.Ishida, Y. Ueda
  • Organizer: ICEL2012
  • Place of Presentation: Fukuoka, Japan
• [Presentation] In situ observation of Octacyanophthalocyanine formation (2012)
  • Author(s): M. Nishimoto, H. Saeki, Y. Koshiba, M. Misaki, K. Ishida, Y. Ueda
  • Organizer: KJF (Korea-Japan Joint Forum) International Conference on Organic Materials for Electronics and Photonics
  • Place of Presentation: Sendai, Japan
• [Presentation] Phase-Separated Thin Film Structures for Polymer Blend Solar Cells (2012)
  • Author(s): Y. koshiba, M. Misaki, S. Ueyama, H. Saeki, K. Ishida, Y. Ueda
  • Organizer: KJF (Korea-Japan Joint Forum) International Conference on Organic Materials for Electronics and Photonics
  • Place of Presentation: Sendai, Japan
• [Presentation] フッ化リチウム蒸着膜上でのオクタシアノフタロシアニン薄膜の生成と評価 (2012)
  • Author(s): 佐伯宏之,西本光穂子,小柴康子,三崎雅裕,堀江聡,石田謙司,上田裕清
  • Organizer: 第59回応用物理学関係連合講演会
  • Place of Presentation: 東京都
• [Presentation] 色素/ポリマー積層型太陽電池の作製と安定性評価 (2012)
  • Author(s): 大西俊輝，佐伯宏之，小柴 康子，三崎 雅裕，石田 謙司，上田 裕清
  • Organizer: 第58回高分子研究発表会（神戸）
  • Place of Presentation: 神戸市
• [Presentation] Phase-Separated Thin Film Structures for Polymer Blend Solar Cells (2012)
  • Author(s): Y. koshiba, M. Misaki, S. Ueyama, H. Saeki, K. Ishida, Y. Ueda
  • Organizer: KJF (Korea-Japan Joint Forum) International Conference on Organic Materials for Electronics and Photonics 2012
  • Place of Presentation: Sendai, Japan
• [Presentation] In situ observation of Octacyanophthalocyanine formation (2012)
  • Author(s): M. Nishimoto, H. Saeki, Y. Koshiba, M. Misaki, K. Ishida, Y. Ueda
  • Organizer: KJF (Korea-Japan Joint Forum) International Conference on Organic Materials for Electronics and Photonics 2012
  • Place of Presentation: Sendai, Japan
• [Presentation] 気-固相反応による n 型有機半導体ナノロッドの作製と評価 (2011)
  • Author(s): 小柴康子,西本光穂子,佐伯宏之,三崎雅裕,石田謙司,上田裕清
  • Organizer: 平成 23 年度金沢大学-富山大学共同企画有機系太陽電池シンポジウム
  • Place of Presentation: 金沢市
  • Year and Date: 2011-12-17
• [Presentation] 気-固相反応によるn型有機半導体ナノロッドの作製と評価 (2011)
  • Author(s): 小柴康子, 他5名
  • Organizer: 平成23年度金沢大学-富山大学共同企画有機系太陽電池シンポジウム
  • Place of Presentation: 金沢大学
  • Year and Date: 2011-12-17
• [Presentation] Morphology Control of Ocracyanophthalocyanine for Nano-Rod Array of n-Type Organic Semiconductor (2011)
  • Author(s): Hiroyuki SAEKI, Mihoko NISHIMOTO, 他5名
  • Organizer: 2011MRS Fall Meeting & Exhibit
  • Place of Presentation: Boston, MA Hynes Convention Center
  • Year and Date: 2011-11-30
• [Presentation] N-type Semiconducting Property of Octacyanophthalocyanine Prepared by Vapor-solid Phase Reaction (2011)
  • Author(s): Mihoko NISHIMOTO, Yasukio KOSHIBA, 他5名
  • Organizer: The 5th East Asia Symposium on Functional Dyes & Advannced Materials
  • Place of Presentation: 中国杭州花港海航假酒店
  • Year and Date: 2011-09-27
• [Presentation] Nano-Structure Control of Octacyanophthalocyanine Thin-Film Prepared by Chemical Vapor Deposition (2011)
  • Author(s): Hiroyuki SAEKI, Yasuko KOSHIBA, 他5名
  • Organizer: KJF International Conference on Organic Materials for Electronics and Photonics 2011
  • Place of Presentation: South Korea Gyeongju Hyundai Hotel
  • Year and Date: 2011-09-16
• [Presentation] オクタシアノフタロシアニンナノロッドの均一成長制御 (2011)
  • Author(s): 佐伯宏之・西本光穂子, 他5名
  • Organizer: 第72回応用物理学会学術講演会
  • Place of Presentation: 山形大学小白川キャンパス
  • Year and Date: 2011-08-30
• [Presentation] オクタシアノフタロシアニンナノロッドの光電変換特性評価 (2011)
  • Author(s): 西本光穂子・佐伯宏之, 他5名
  • Organizer: 第72回応用物理学会学術講演会
  • Place of Presentation: 山形大学小白川キャンパス
  • Year and Date: 2011-08-30
• [Presentation] 有機半導体ナノロッドの作製と特性評価 (2011)
  • Author(s): 佐伯宏之、西本光穂子、小柴康子、三崎雅裕、堀江聡、石田謙司、上田裕清
  • Organizer: 2011 春季第58回応用物理学関係連合講演会
  • Place of Presentation: 厚木市
  • Year and Date: 2011-03-26
• [Presentation] 有機半導体ナノロッドの作製と特性評価 (2011)
  • Author(s): 佐伯宏之
  • Organizer: 2011春季第58回応用物理学関係連合講演会
  • Place of Presentation: 神奈川工科大学(厚木市)
  • Year and Date: 2011-03-26
• [Presentation] Morphology Control of Ocracyanophthalo- cyanine for Nano-Rod Array of n-Type Organic Semiconductor (2011)
  • Author(s): H. SAEKI, M. NISHIMOTO, Y. KOSHIBA, M. MISAKI, S. HORIE, K. ISHIDA, Y. UEDA
  • Organizer: 2011MRS Fall Meeting & Exhibit
  • Place of Presentation: Boston, USA
• [Presentation] N-type Semiconducting Property of Octacyano phthalocyanine Prepared by Vapor-solid Phase Reaction (2011)
  • Author(s): M. NISHIMOTO, H. SAEKI, Y. KOSHIBA, M. MISAKI, S. HORIE, K. ISHIDA, Y. UEDA
  • Organizer: The 5th East Asia Symposium on Functional Dyes & Advannced Materials
  • Place of Presentation: Hangzhou, China
• [Presentation] Nano-Structure Control of Octacyano phthalocyanine Thin-Film Prepared by Chemical Vapor Deposition (2011)
  • Author(s): H. SAEKI, M. NISHIMOTO, Y. KOSHIBA, M. MISAKI, S. HORIE, K. ISHIDA, Y. UEDA
  • Organizer: KJF International Conference on Organic Materials for Electronics and Photonics 2011 (KJF-ICOMEP 2011)
  • Place of Presentation: Gyeongju, Korea
• [Presentation] オクタシアノフタロシアニンナノロッドの均一成長制御 (2011)
  • Author(s): 佐伯宏之, 西本光穂子, 小柴康子, 三崎雅裕, 堀江聡, 石田謙司, 上田裕清
  • Organizer: 第72回応用物理学会学術講演会
  • Place of Presentation: 山形市
• [Presentation] オクタシアノフタロシアニンナノロッドの光電変換特性評価 (2011)
  • Author(s): 西本光穂子, 佐伯宏之, 小柴康子, 三崎雅裕, 堀江聡, 石田謙司,上田裕清
  • Organizer: 第72回応用物理学会学術講演会
  • Place of Presentation: 山形市
• [Presentation] デバイス作製直後における有機薄膜太陽電池の光電変換特性挙動と有機-無機界面の効果 (2010)
  • Author(s): 佐伯宏之
  • Organizer: 2010年秋季第71回応用物理学会学術講演会
  • Place of Presentation: 長崎大学(長崎市)
  • Year and Date: 2010-09-15
• [Presentation] 分子配列制御の歴史 (2010)
  • Author(s): 上田裕清
  • Organizer: 2010年秋季第71回応用物理学会学術講演会
  • Place of Presentation: 長崎大学(長崎市)(招待講演)
  • Year and Date: 2010-09-15
• [Presentation] Oriented Thin Films of Fluorene Derivatives by Friction-transfer Method (2010)
  • Author(s): Yasuko Koshiba
  • Organizer: Korea-Japan Forum 2010 on Organic Materials for Electronics and Photonics (KJF2010)
  • Place of Presentation: Kitakyushu, Japan
  • Year and Date: 2010-08-24
• [Presentation] The analysis on current-voltage characteristics of polythiophene : fullerene solar cell just after deposition of metal by in-situ measurement (2010)
  • Author(s): Hiroyuki Saeki
  • Organizer: International Conference on Science and Technology of Synthetic Metals 2010 (ICSM 2010)
  • Place of Presentation: Kyoto, Japan
  • Year and Date: 2010-07-05
• [Presentation] Oriented Thin Films of Fluorene Derivatives by Friction-transfer Method (2010)
  • Author(s): Y. Koshiba. K. Kanda, H. Miyaji. M. Misaki, K. Ishida, Y. Ueda
  • Organizer: KJF International Conference on Organic Materials for Electronics and Photonics (2010)
  • Place of Presentation: Kitakyushu, Japan
• [Remarks]
  • URL: http://www.research.kobe-u.ac.jp/eng-cx1/
• [Remarks]
  • URL: http://www.research.kobe-u.ac.jp/eng-cx1/