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Fabrication ofn-type phthalocyanine nano-rods by CVD technique and organic photovoltaic cells

Research Project

Project/Area Number 22560052
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied physics, general
Research InstitutionKobe University

Principal Investigator

KOSHIBA Yasuko  神戸大学, 大学院・工学研究科, 助手 (70243326)

Co-Investigator(Kenkyū-buntansha) UEDA Yasukiyo  神戸大学, 大学院・工学研究科, 教授 (40116190)
ISHIDA Kenji  神戸大学, 大学院・工学研究科, 准教授 (20303860)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsエネルギー変換 / 有機薄膜太陽電池 / 化学気相成長法 / ナノロッド構造 / n 型有機半導体 / n型有機半導体 / 有機薄膜太陽霞池
Research Abstract

Octacyanophthalocyanine (OcPc) nanorods were fabricated on a single KCl crystal. The diameters and lengths of nanorods ware controlled. The OcPc film exhibited n-type conduction characteristics, and the energy of the highest occupied molecular orbital was determined to be 5.8 eV. OPV cells using fluorinated phthalocyanine as electron acceptor were evaluated. OcPc nanorods were also fabricated on vacuum-deposited LiF or Cu. Photovoltaic power was observed in cells containing OcPc as an n-type semiconductor.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (42 results)

All 2013 2012 2011 2010 Other

All Journal Article (8 results) (of which Peer Reviewed: 6 results) Presentation (32 results) Remarks (2 results)

  • [Journal Article] Fabrication and Semiconducting Properties of Monodisperse n-Type Phthalocyanine Nanograss2013

    • Author(s)
      H. Saeki, M. Nishimoto, Y. Koshiba, M. Misaki, K. Ishida, Y. Ueda
    • Journal Title

      Thin Solid Films

      Volume: Vol.531 Pages: 513-518

    • DOI

      10.1016/j.tsf.2013.01.009

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] p 型/n 型界面での電荷分離特性向上に向けた強誘電体分子超薄膜との界面形成2012

    • Author(s)
      大杉拓也、小柴康子、三崎雅裕、石田謙司、上田裕清
    • Journal Title

      信学技報 IEICE Technical Report

      Volume: Vol.112 Pages: 55-59

    • NAID

      110009642065

    • Related Report
      2012 Final Research Report
  • [Journal Article] p型/n型界面での電荷分離特性向上に向けた強誘電体分子超薄膜との界面形成2012

    • Author(s)
      大杉拓也、小柴康子、三崎雅裕、石田謙司、上田裕清
    • Journal Title

      信学技報 IEICE Technical Report

      Volume: Vol.112, No.304 Pages: 55-59

    • NAID

      110009642065

    • Related Report
      2012 Annual Research Report
  • [Journal Article] In-plane Orientation of Fluorescent Molecules in Friction-transferred Films2011

    • Author(s)
      Y. Koshiba, M. Misaki, K. Kanda, H. Miyaji, K. Ishida, Y. Ueda
    • Journal Title

      Chemistry Letters

      Volume: Vol.40, No.11 Issue: 11 Pages: 1288-1299

    • DOI

      10.1246/cl.2011.1288

    • NAID

      130004426095

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystalline Thin Films of β-Phase Poly(9,9-dioctylfluorene)2011

    • Author(s)
      Takuji Kawamura
    • Journal Title

      Thin Solid Films

      Volume: 519 Pages: 2247-2250

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic Solvent Based TiO_2 Dispersion Paste for Dye Sensitized Solar Cells Prepared by Industrial Production Level Procedure2011

    • Author(s)
      Ryohei Mori
    • Journal Title

      J.Materials Science

      Volume: 46 Pages: 8272-8278

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Current-Voltage Characteristics of Organic Photovoltaic Cells Following Deposition of Cathode Electrode2010

    • Author(s)
      H. Saeki, K. Hirohara, Y. Koshiba, S. Horie, M. Misaki, K. Takeshita, K. Ishida, Y. Ueda
    • Journal Title

      Applied Physics Letters

      Volume: Vol.97 Issue: 19

    • DOI

      10.1063/1.3516469

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Current-Voltage Characteristics of Organic Photovoltaic Cells Following Deposition of Cathode Electrode2010

    • Author(s)
      Hiroyuki Saeki
    • Journal Title

      Applied Physics Letters

      Volume: 97

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 気固相反応によるオクタシアノフタロシアニン薄膜生成過程の考察2013

    • Author(s)
      西本 光穂子,佐伯 宏之,小柴 康子,三崎 雅裕,石田 謙司,上田 裕清
    • Organizer
      2013 年第60回応用物理学会春季学術講演会
    • Place of Presentation
      厚木市
    • Related Report
      2012 Final Research Report
  • [Presentation] Fabrication and Evaluation of Organic Photovoltaic Cells Using Fluorinated Phthalocyanines as electron acceptor2013

    • Author(s)
      Y. Koshiba, T. Ohnishi, H. Saeki, M. Misaki, K. Ishida, Y. Ueda
    • Organizer
      Seventh International Conference on Molecular Electronics and Bioelectronics (M&BE7)
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] Fabrication and Evaluation of Organic Photovoltaic Cells Using Fluorinated Phthalocyanines as electron acceptor2013

    • Author(s)
      Y. Koshiba, T. Ohnishi, H. Saeki, M. Misaki, K. Ishida, Y. Ueda
    • Organizer
      Seventh International Conference on Molecular Electronics and Bioelectronics (M&BE7)
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] 気固相反応によるオクタシアノフタロシアニン薄膜生成過程の考察2013

    • Author(s)
      西本 光穂子,佐伯 宏之,小柴 康子,三崎 雅裕,石田 謙司,上田 裕清
    • Organizer
      2013年第60回応用物理学会春季学術講演会
    • Place of Presentation
      厚木市
    • Related Report
      2012 Annual Research Report
  • [Presentation] 大西俊輝,佐伯宏之,小柴 康子,三崎 雅裕,石田 謙司,上田 裕清2012

    • Author(s)
      大西俊輝,佐伯宏之,小柴 康子,三崎 雅裕,石田 謙司,上田 裕清
    • Organizer
      第58回高分子研究発表会(神戸)
    • Place of Presentation
      神戸市
    • Year and Date
      2012-07-13
    • Related Report
      2012 Final Research Report
  • [Presentation] フッ化リチウム蒸着膜上でのオクタシアノフタロシアニン薄膜の生成と評価2012

    • Author(s)
      佐伯宏之, 他6名
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学早稲田キャンパス
    • Year and Date
      2012-03-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Fabrication and photovoltaic characterization of K2Pc(CN)8- complex nano-rod2012

    • Author(s)
      H. Saeki, M. Nishimoto, Y. Koshiba, M. Misaki, K.Ishida, Y. Ueda
    • Organizer
      ICEL2012
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] In situ observation of Octacyanophthalocyanine formation2012

    • Author(s)
      M. Nishimoto, H. Saeki, Y. Koshiba, M. Misaki, K. Ishida, Y. Ueda
    • Organizer
      KJF (Korea-Japan Joint Forum) International Conference on Organic Materials for Electronics and Photonics
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] Phase-Separated Thin Film Structures for Polymer Blend Solar Cells2012

    • Author(s)
      Y. koshiba, M. Misaki, S. Ueyama, H. Saeki, K. Ishida, Y. Ueda
    • Organizer
      KJF (Korea-Japan Joint Forum) International Conference on Organic Materials for Electronics and Photonics
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] フッ化リチウム蒸着膜上でのオクタシアノフタロシアニン薄膜の生成と評価2012

    • Author(s)
      佐伯宏之,西本光穂子,小柴康子,三崎雅裕,堀江聡,石田謙司,上田裕清
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      東京都
    • Related Report
      2012 Final Research Report
  • [Presentation] 色素/ポリマー積層型太陽電池の作製と安定性評価2012

    • Author(s)
      大西俊輝,佐伯宏之,小柴 康子,三崎 雅裕,石田 謙司,上田 裕清
    • Organizer
      第58回高分子研究発表会(神戸)
    • Place of Presentation
      神戸市
    • Related Report
      2012 Annual Research Report
  • [Presentation] Phase-Separated Thin Film Structures for Polymer Blend Solar Cells2012

    • Author(s)
      Y. koshiba, M. Misaki, S. Ueyama, H. Saeki, K. Ishida, Y. Ueda
    • Organizer
      KJF (Korea-Japan Joint Forum) International Conference on Organic Materials for Electronics and Photonics 2012
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] In situ observation of Octacyanophthalocyanine formation2012

    • Author(s)
      M. Nishimoto, H. Saeki, Y. Koshiba, M. Misaki, K. Ishida, Y. Ueda
    • Organizer
      KJF (Korea-Japan Joint Forum) International Conference on Organic Materials for Electronics and Photonics 2012
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] 気-固相反応による n 型有機半導体ナノロッドの作製と評価2011

    • Author(s)
      小柴康子,西本光穂子,佐伯宏之,三崎雅裕,石田謙司,上田裕清
    • Organizer
      平成 23 年度金沢大学-富山大学共同企画有機系太陽電池シンポジウム
    • Place of Presentation
      金沢市
    • Year and Date
      2011-12-17
    • Related Report
      2012 Final Research Report
  • [Presentation] 気-固相反応によるn型有機半導体ナノロッドの作製と評価2011

    • Author(s)
      小柴康子, 他5名
    • Organizer
      平成23年度金沢大学-富山大学共同企画有機系太陽電池シンポジウム
    • Place of Presentation
      金沢大学
    • Year and Date
      2011-12-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Morphology Control of Ocracyanophthalocyanine for Nano-Rod Array of n-Type Organic Semiconductor2011

    • Author(s)
      Hiroyuki SAEKI, Mihoko NISHIMOTO, 他5名
    • Organizer
      2011MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, MA Hynes Convention Center
    • Year and Date
      2011-11-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] N-type Semiconducting Property of Octacyanophthalocyanine Prepared by Vapor-solid Phase Reaction2011

    • Author(s)
      Mihoko NISHIMOTO, Yasukio KOSHIBA, 他5名
    • Organizer
      The 5th East Asia Symposium on Functional Dyes & Advannced Materials
    • Place of Presentation
      中国杭州花港海航假酒店
    • Year and Date
      2011-09-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Nano-Structure Control of Octacyanophthalocyanine Thin-Film Prepared by Chemical Vapor Deposition2011

    • Author(s)
      Hiroyuki SAEKI, Yasuko KOSHIBA, 他5名
    • Organizer
      KJF International Conference on Organic Materials for Electronics and Photonics 2011
    • Place of Presentation
      South Korea Gyeongju Hyundai Hotel
    • Year and Date
      2011-09-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] オクタシアノフタロシアニンナノロッドの均一成長制御2011

    • Author(s)
      佐伯宏之・西本光穂子, 他5名
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス
    • Year and Date
      2011-08-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] オクタシアノフタロシアニンナノロッドの光電変換特性評価2011

    • Author(s)
      西本光穂子・佐伯宏之, 他5名
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス
    • Year and Date
      2011-08-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] 有機半導体ナノロッドの作製と特性評価2011

    • Author(s)
      佐伯宏之、西本光穂子、小柴康子、三崎雅裕、堀江聡、石田謙司、上田裕清
    • Organizer
      2011 春季第58回応用物理学関係連合講演会
    • Place of Presentation
      厚木市
    • Year and Date
      2011-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] 有機半導体ナノロッドの作製と特性評価2011

    • Author(s)
      佐伯宏之
    • Organizer
      2011春季第58回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学(厚木市)
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Morphology Control of Ocracyanophthalo- cyanine for Nano-Rod Array of n-Type Organic Semiconductor2011

    • Author(s)
      H. SAEKI, M. NISHIMOTO, Y. KOSHIBA, M. MISAKI, S. HORIE, K. ISHIDA, Y. UEDA
    • Organizer
      2011MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] N-type Semiconducting Property of Octacyano phthalocyanine Prepared by Vapor-solid Phase Reaction2011

    • Author(s)
      M. NISHIMOTO, H. SAEKI, Y. KOSHIBA, M. MISAKI, S. HORIE, K. ISHIDA, Y. UEDA
    • Organizer
      The 5th East Asia Symposium on Functional Dyes & Advannced Materials
    • Place of Presentation
      Hangzhou, China
    • Related Report
      2012 Final Research Report
  • [Presentation] Nano-Structure Control of Octacyano phthalocyanine Thin-Film Prepared by Chemical Vapor Deposition2011

    • Author(s)
      H. SAEKI, M. NISHIMOTO, Y. KOSHIBA, M. MISAKI, S. HORIE, K. ISHIDA, Y. UEDA
    • Organizer
      KJF International Conference on Organic Materials for Electronics and Photonics 2011 (KJF-ICOMEP 2011)
    • Place of Presentation
      Gyeongju, Korea
    • Related Report
      2012 Final Research Report
  • [Presentation] オクタシアノフタロシアニンナノロッドの均一成長制御2011

    • Author(s)
      佐伯宏之, 西本光穂子, 小柴康子, 三崎雅裕, 堀江聡, 石田謙司, 上田裕清
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形市
    • Related Report
      2012 Final Research Report
  • [Presentation] オクタシアノフタロシアニンナノロッドの光電変換特性評価2011

    • Author(s)
      西本光穂子, 佐伯宏之, 小柴康子, 三崎雅裕, 堀江聡, 石田謙司,上田裕清
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形市
    • Related Report
      2012 Final Research Report
  • [Presentation] デバイス作製直後における有機薄膜太陽電池の光電変換特性挙動と有機-無機界面の効果2010

    • Author(s)
      佐伯宏之
    • Organizer
      2010年秋季第71回応用物理学会学術講演会
    • Place of Presentation
      長崎大学(長崎市)
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 分子配列制御の歴史2010

    • Author(s)
      上田裕清
    • Organizer
      2010年秋季第71回応用物理学会学術講演会
    • Place of Presentation
      長崎大学(長崎市)(招待講演)
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Oriented Thin Films of Fluorene Derivatives by Friction-transfer Method2010

    • Author(s)
      Yasuko Koshiba
    • Organizer
      Korea-Japan Forum 2010 on Organic Materials for Electronics and Photonics (KJF2010)
    • Place of Presentation
      Kitakyushu, Japan
    • Year and Date
      2010-08-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] The analysis on current-voltage characteristics of polythiophene : fullerene solar cell just after deposition of metal by in-situ measurement2010

    • Author(s)
      Hiroyuki Saeki
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2010 (ICSM 2010)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2010-07-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] Oriented Thin Films of Fluorene Derivatives by Friction-transfer Method2010

    • Author(s)
      Y. Koshiba. K. Kanda, H. Miyaji. M. Misaki, K. Ishida, Y. Ueda
    • Organizer
      KJF International Conference on Organic Materials for Electronics and Photonics (2010)
    • Place of Presentation
      Kitakyushu, Japan
    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://www.research.kobe-u.ac.jp/eng-cx1/

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://www.research.kobe-u.ac.jp/eng-cx1/

    • Related Report
      2011 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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