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Approach to the Understanding of Hydrogen Embrittleness of Steels Using Energy Expression of the Chemical Bond and Its Application to Quantum Alloy Design

Research Project

Project/Area Number 22560658
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionNagoya University

Principal Investigator

MORINAGA Masahiko  名古屋大学, 大学院・工学研究科, 名誉教授 (50126950)

Co-Investigator(Kenkyū-buntansha) YUKAWA Hiroshi  名古屋大学, 大学院・工学研究科, 助教 (50293676)
YOSHINO Masahito  名古屋大学, 大学院・工学研究科, 助教 (10397466)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords水素脆化 / 量子材料設計 / 化学結合 / 鉄鋼材料 / 昇温脱離 / 昇温脱離法 / 金属炭化物 / 材料設計 / 原子価エネルギー
Research Abstract

Atomization energy analysis is proposed for treating the chemical bond in steels in an energy scale in order to understand the hydrogen embrittleness in view of the chemical bond. Following this analysis, the hydrogen trapping effect is understood by estimating the nature of the chemical bond between hydrogen (H) and non-metal elements (e.g., C) or alloying elements (e.g.,Cr) in steels. Also, the trend of the hydrogen trapping around metal carbides (e.g., VC) in steels is predictable approximately along this analysis. This is confirmed experimentally through the hydrogen trapping test in pure metal carbides by using the ball-milling in a hydrogen atmosphere. Such information is useful for the quantum design of steels against hydrogen embrittleness.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (19 results)

All 2013 2012 2011 2010 Other

All Journal Article (9 results) (of which Peer Reviewed: 5 results) Presentation (8 results) Remarks (2 results)

  • [Journal Article] DV-Xα法による合金設計2012

    • Author(s)
      森永正彦
    • Journal Title

      DV-Xα研究協会会報

      Volume: 25 Pages: 3-9

    • Related Report
      2012 Final Research Report
  • [Journal Article] DV-Xα法による合金設計2012

    • Author(s)
      森永正彦
    • Journal Title

      DV-Xα研究協会会報

      Volume: 25 Pages: 3-9

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Energy Expression of the Chemical Bond between Atoms in Metal Oxides2011

    • Author(s)
      Y. Shinzato, Y.Saito, M. Yoshino, H.Yukawa, M.Morinaga, T.Baba and H.Nakai
    • Journal Title

      J. Phys. Chem. Solids

      Volume: 72 Pages: 853-861

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Role of O-H Bonding in Catalytic Activity of Nb_2O_5 during the Course of Dehydrogenation of MgH_22011

    • Author(s)
      H.Hirate, H.Sawai, H.Yukawa and M.Morinaga
    • Journal Title

      International Journal of Quantum Chemistry

      Volume: 111 Pages: 2251-2257

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Atomization Energy Approach to the Understanding of the Chemical Bond between Atoms in 3d Transition-Metal Based Compounds2011

    • Author(s)
      M. Morinaga, Y. Saito, K. Ito, H. Yukawa, M.Yoshino and H. Nakai
    • Journal Title

      DV-Xα研究協会会報

      Volume: 24 Pages: 85-91

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Journal Article] Energy Expression of the Chemical Bond between Atoms in Metal Oxides2011

    • Author(s)
      Yoshifumi Shinzato, Yuki Saito, Masahito Yoshino, Hiroshi Yukawa, Masahiko Morinaga, Takeshi Baba, Hiromi Nakai
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 72 Issue: 7 Pages: 853-861

    • DOI

      10.1016/j.jpcs.2011.03.014

    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quantitative Evaluation of Catalytic Effect of Metal Chlorides on the Desorption Reaction of NaAlH_42010

    • Author(s)
      H.Hirate, Y.Saito, I.Nakaya, I. Nakaya, H.Sawai, H.Yukawa, M.Morinaga and H.Nakai
    • Journal Title

      International Journal of Quantum Chemistry

      Volume: 111 Pages: 950-960

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Unusual Energy Balance Between Atoms in Postperovskite MgSiO_32010

    • Author(s)
      H.Hirate, H.Sawai, Y.Saito, H.Yukawa, M.Morinaga and H.Nakai
    • Journal Title

      J. Am. Ceram. Soc.

      Volume: 93 Pages: 3449-3454

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electronic Approach to Alloy Design2010

    • Author(s)
      M. Morinaga
    • Journal Title

      DV-Xα研究協会会報

      Volume: 23 Pages: 39-45

    • Related Report
      2012 Final Research Report
  • [Presentation] NbC およびNb_2O_5にトラップされた水素の昇温脱離法による安定性の評価2013

    • Author(s)
      吉野正人、酒井智康、中嶋一重、谷本憲哉、湯川宏、森永正彦、渡邊真太、山田智明、長崎正雅、
    • Organizer
      日本金属学会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2013-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] Energy Expression of the Chemical Bond between Atoms in 3d Transition Metal-based Compounds2012

    • Author(s)
      M. Morinaga, Y. Saito, K. Ito, M.Yoshino, H. Yukawa and H. Nakai
    • Organizer
      The 5th International Symposium on Designing, Processing and Properties of Advanced Engineering Materials (ISAEM-2012)
    • Place of Presentation
      Loisir Hotel Toyohashi
    • Year and Date
      2012-11-06
    • Related Report
      2012 Final Research Report
  • [Presentation] DV-Xα法による合金設計2012

    • Author(s)
      森永正彦(DV-Xα研究協会・協会賞受賞)
    • Organizer
      DV-Xα研究会
    • Place of Presentation
      福岡大学
    • Year and Date
      2012-08-07
    • Related Report
      2012 Final Research Report
  • [Presentation] NbCおよびNb_2O_5にトラップされた水素の昇温脱離法による安定性の評価2012

    • Author(s)
      吉野正人、酒井智康、中嶋一重、谷本憲哉、湯川宏、森永正彦、渡邊真太、山田智明、長崎正雅
    • Organizer
      日本金属学会2012春期講演大会
    • Place of Presentation
      横浜国立大学(神奈川県)
    • Year and Date
      2012-03-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] Atomization Energy Approach to the Understanding of the Chemical Bond between Atoms in 3d Transition-Metal Based Compounds2011

    • Author(s)
      M. Morinaga, Y. Saito, K. Ito, H. Yukawa, M.Yoshino and H. Nakai
    • Organizer
      DV-Xα研究会
    • Place of Presentation
      静岡大学
    • Year and Date
      2011-08-09
    • Related Report
      2012 Final Research Report
  • [Presentation] 原子化エネルギーから見た3d遷移金属化合物の化学結合2011

    • Author(s)
      森永正彦、齋藤由樹、伊藤和樹、湯川宏、中井浩巳
    • Organizer
      第24回DV-Xα研究会
    • Place of Presentation
      静岡大学(静岡県)
    • Year and Date
      2011-08-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] Electronic Approach to Alloy Design2010

    • Author(s)
      M. Morinaga
    • Organizer
      DV-Xα法国際会議
    • Place of Presentation
      韓国基礎科学研究支援院(韓国)
    • Year and Date
      2010-08-06
    • Related Report
      2012 Final Research Report
  • [Presentation] DV-Xα法による合金設計

    • Author(s)
      森永正彦
    • Organizer
      第25回DV-Xα研究会
    • Place of Presentation
      福岡大学
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://sigma.numse.nagoya-u.ac.jp

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://www.toyotariken.jp

    • Related Report
      2012 Final Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

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