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Hydrothermal treatment for improvements in the strength and functions of anodic oxidation films formed on the biomaterial titanium alloy.

Research Project

Project/Area Number 22560700
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionKagawa University

Principal Investigator

TANAKA Yasuhiro  香川大学, 工学部, 准教授 (10217086)

Co-Investigator(Kenkyū-buntansha) FENG Qi  香川大学, 工学部, 教授 (80274356)
ISHIKAWA Yoshie  香川大学, 工学部, 准教授 (20509129)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsバイオマテリアル / 生体用チタン合金 / ナノチューブ処理 / アパタイト被覆処理 / 構造・機能材料 / 生体材料 / 電子顕微鏡 / 表面・界面物性 / 陽極酸化 / 陽極酸化処理 / マイクロアーク酸化 / アパタイト生成 / ナノチューブ形成 / 集束イオンビーム断面観察
Research Abstract

The purpose of this study is formation of excellent surface oxide films to improve the biocompatibility on a Ti-6Al-7Nb (α+β) 2 phase-type alloy by means of anodic oxidation, involving Ca cation and hydrothermal process. Nano-tube surface film was generated even there was some difference in tube diameter between α and β phases. And Ca was incorporated into the nano-tube structure. Micro-arc oxidation process in the chemical solution containing Ca ion made the surface film containing Ca cation. We find that ingredients of the chemical solutions affected phases in the oxide film and the structure of the interface and defects.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (32 results)

All 2013 2012 2011 2010 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (23 results)

  • [Journal Article] Crystallographic Orientation Dependence of ε Martensite Transformation during Tensile Deformation of Polycrystalline 30%Mn Austenitic Steel2013

    • Author(s)
      R. Ueji, Y. Takagi, N. Tsuchida, K. Shinagawa, Y. Tanaka, T. Mizuguchi
    • Journal Title

      Materials Science & Engineering A

      Volume: 576 Pages: 14-20

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Transformation of potassium Lindquist hexaniobate tovarious potassium niobates: solvothermal synthesis and structural evolution mechanism2013

    • Author(s)
      X. Kong, D. Hu, P. Weng, T. Ishii, Y. Tanaka, Q. Feng
    • Journal Title

      Dalton Transactions

      Volume: 42 Pages: 7699-7709

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystallographic orientation dependence of ε martensite transformation during tensile deformation of polycrystalline 30% Mn austenitic steel2013

    • Author(s)
      R.Ueji, Y.Takagi, N.Tsuchida, K.Shinagawa, Y.Tanaka, T.Mizuguchi
    • Journal Title

      Materials Science and Engineering A

      Volume: 61 Pages: 14-20

    • DOI

      10.1016/j.msea.2013.03.071

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fracture Behavior Transition by change of Strain Rate in Dislocation-induced Si Steels2012

    • Author(s)
      T. Mizuguchi, R. Ueji, H. Miyagawa, Y. Tanaka, K. Shinagawa
    • Volume
      706-709
    • Pages
      2187-2192
    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Solvothermal Soft Chemical Synthesis and Characterization of Nanostructured Ba_(Bi_K_)_xTiO_3 Platelike Particles with Crystal-axisorientation2011

    • Author(s)
      X. Kong, D. Hu, Y. Ishikawa, Y. Tanaka, Q. Feng
    • Journal Title

      Chemistry of Materials

      Volume: 23 Pages: 397-3986

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Solvothermal Soft Chemical Synthesis and Characterization of Nanostructured Bal-x(Bi0.5K0.5)xTiO3 Plate-like Particles with Crystal-axis-orientation2011

    • Author(s)
      Xingang Kong; Dengwei Hu; Yoshie Ishikawa; Yasuhiro Tanaka; Qi Feng
    • Journal Title

      Chemistry of Materials

      Volume: 23 Pages: 3978-3986

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical properties of 15%Mn steel with fine lamellar structure consisting of ferrite and austenite2010

    • Author(s)
      R. Ueji, Y. Okitsu, T. Nakamura, Y. Takagi, Y. Tanaka
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 240 Pages: 12029-12029

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Deformation behavior of pure titanium at a wide range of strain rates2010

    • Author(s)
      Y. Tanaka, M. Kondo, N. Miyazaki, R. Ueji
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 240 Pages: 12021-12021

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crosssectional TEM observations and elemental mapping on anotic oxidation surface films of titanium alloy

    • Author(s)
      Y. Tanaka, Y. Fukuchi, L. Fei
    • Journal Title

      Proc. of the 8th Pacific Rim International Congress on Advanced Materials and Processing (accepted)

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Presentation] 陽極酸化処理で表面改質したチタン合金の断面 TEM 観察と元素分布分析2013

    • Author(s)
      田中康弘,福地優介,羅菲
    • Organizer
      日本金属学会第152回春期講演大会
    • Place of Presentation
      東京理科大
    • Year and Date
      2013-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] Ba_(Bi_K_)_xTiO_3 メソクリスタルのソルボサーマル合成と反応メカニズム2013

    • Author(s)
      馮旗,孔新剛,胡登衛,田中康弘
    • Organizer
      第51回セラミックス基礎科学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2013-01-10
    • Related Report
      2012 Final Research Report
  • [Presentation] Topotactic synthesis of Na0.5Bi0.5TiO3 mesocrystal plate-like particles from layered titanate precursor2013

    • Author(s)
      Dengwei Hu,Yasuhiro Tanaka,Qi Feng
    • Organizer
      第51回セラミックス基礎科学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2013-01-10
    • Related Report
      2012 Final Research Report
  • [Presentation] Crosssectional TEM observations and elemental mapping on anotic oxidation surface films of titanium alloy2013

    • Author(s)
      Y. Tanaka, Y. Fukuchi, L. Fei
    • Organizer
      The 8th Pacific Rim International Congress on Advanced Materials and Processing
    • Place of Presentation
      Hawaii
    • Related Report
      2012 Final Research Report
  • [Presentation] 陽極酸化処理で表面改質したチタン合金の断面TEM観察と元素分布分析2013

    • Author(s)
      田中康弘
    • Organizer
      日本金属学会2013年春季(第152回)講演大会
    • Place of Presentation
      東京理科大
    • Related Report
      2012 Annual Research Report
  • [Presentation] Ba1-x (Bi0.5K0.5)xTiO3メソクリスタルのソルボサーマル合成と反応メカニズム2013

    • Author(s)
      馮旗
    • Organizer
      第51回セラミックス基礎科学討論会
    • Place of Presentation
      仙台国際センター
    • Related Report
      2012 Annual Research Report
  • [Presentation] ニオブ酸カリウムのソルボサーマル合成と粒子形状制御2012

    • Author(s)
      馮旗,孔新剛,胡登衛,田中康弘,石井知彦
    • Organizer
      日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋
    • Year and Date
      2012-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] Ca イオン含有溶液中でマイクロアーク酸化処理したチタンの酸化皮膜微細構造2012

    • Author(s)
      田中康弘,羅菲
    • Organizer
      日本金属学会第150回春期講演大会
    • Place of Presentation
      横浜国大
    • Year and Date
      2012-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] Caイオン含有溶液中でマイクロアーク酸化処理したチタンの酸化皮膜微細構造2012

    • Author(s)
      田中康弘;羅非
    • Organizer
      日本金属学会
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] Shot peeningによるCu含有鋼表面赤熱脆性抑制機構の検討 ─初期酸化過程における組織変化─2012

    • Author(s)
      田中康弘
    • Organizer
      日本鉄鋼協会第164回秋季講演大会
    • Place of Presentation
      愛媛大
    • Related Report
      2012 Annual Research Report
  • [Presentation] 組成及び溶体化温度による歯科用金銀パラジウム合金の機械的性質と微細組織への影響2012

    • Author(s)
      池下雄一
    • Organizer
      日本金属学会第151回秋期講演大会
    • Place of Presentation
      愛媛大
    • Related Report
      2012 Annual Research Report
  • [Presentation] 純 Ti の高速引張変形時の強度-延性バランス向上とそれに与える変形双晶の効果2011

    • Author(s)
      田中康弘, 堀江道広, 吉田達人, 水口隆,品川一成,上路林太郎
    • Organizer
      本金属学会第149回秋期講演大会
    • Place of Presentation
      沖縄
    • Year and Date
      2011-11-07
    • Related Report
      2012 Final Research Report
  • [Presentation] 純Ti高速引張変形時の強度向上に対する加工転位組織り役割2011

    • Author(s)
      田中康弘;堀江道広;吉田達人;水口隆;品川一成;上路林太郎
    • Organizer
      日本金属学会
    • Place of Presentation
      沖縄
    • Year and Date
      2011-11-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] 電気化学的に生成した Ti-6Al-7Nb 合金表面酸化皮膜の微細構造2011

    • Author(s)
      田中康弘,福地優介,羅菲,今井琢也
    • Organizer
      軽金属学会 60 周年記念事業中国四国支部記念講演大会
    • Place of Presentation
      松山
    • Year and Date
      2011-09-12
    • Related Report
      2012 Final Research Report
  • [Presentation] 電気化学的に生成したTi-6Al-7Nb合金表面酸化皮膜の微細構造2011

    • Author(s)
      田中康弘;福地優介;羅菲;今井琢也
    • Organizer
      軽金属学会中国四国支部
    • Place of Presentation
      松山
    • Year and Date
      2011-09-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] ソルボサンマルソフト化学法による配向性 Ba_(Bi_K_)_xTiO_3 板状粒子の合成と評価2011

    • Author(s)
      馮旗,孔新剛,胡登衛,石川善恵,田中康弘
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-07
    • Related Report
      2012 Final Research Report
  • [Presentation] マイクロアーク酸化処理によって Ti 及び Ti-6Al-7Nb 合金に生成する表面皮膜の断面構造評価2011

    • Author(s)
      羅菲,今井琢也,田中康弘
    • Organizer
      日本鉄鋼協会第54回・日本金属学会第51回中国四国支部講演大会
    • Place of Presentation
      岡山理科大学
    • Year and Date
      2011-08-08
    • Related Report
      2012 Final Research Report
  • [Presentation] マイクロアーク酸化処理によってTi及びTi-6Al-7Nb合金に生成する表面皮膜の断面構造評価2011

    • Author(s)
      羅菲;今井琢也;田中康弘
    • Organizer
      日本鉄鋼協会・日本金属学会中国四国支部
    • Place of Presentation
      岡山
    • Year and Date
      2011-08-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] Shot peeningによるCu鋼表面赤熱脆性抑制機構の検討-初期酸化状態への影響2010

    • Author(s)
      田中康弘
    • Organizer
      日本鉄鋼協会
    • Place of Presentation
      北海道大学(招待講演)
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Hunks 液中で分極試験した Ti 材に生成する表面皮膜の断面 TEM 観察2010

    • Author(s)
      田中康弘,今井琢也,中桐祥伸,水口隆,足立善一,樋口鎮央,和田主実
    • Organizer
      日本金属学会第147回秋期講演大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-26
    • Related Report
      2012 Final Research Report
  • [Presentation] Hunks液中で分極試験したTi材に生成する表面皮膜の断面TEM観察2010

    • Author(s)
      田中康弘
    • Organizer
      日本金属学会
    • Place of Presentation
      北海道大学(招待講演)
    • Year and Date
      2010-09-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] イオンプレーティング処理 Ti 材のハンクス液中分極試験と断面構造観察2010

    • Author(s)
      今井琢也,中桐祥伸,田中康弘,足立善一,樋口鎮央,和田主実
    • Organizer
      日本鉄鋼協会第53回・日本金属学会第50回中国四国支部講演大会
    • Place of Presentation
      山口大学
    • Year and Date
      2010-08-10
    • Related Report
      2012 Final Research Report
  • [Presentation] イオンプレーティング処理Ti材のハンクス液中分極試験と断面構造観察2010

    • Author(s)
      今井琢也
    • Organizer
      日本金属学会
    • Place of Presentation
      山口大学(招待講演)
    • Year and Date
      2010-08-10
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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