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Development of Solid Oxide Fuel Cell Anode for Direct Utilization of Dimethylether Fuel operated at 600℃

Research Project

Project/Area Number 22560706
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionTokyo University of Science

Principal Investigator

TAKEUCHI Ken  東京理科大学, 基礎工学部, 准教授 (80339134)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2010: ¥260,000 (Direct Cost: ¥200,000、Indirect Cost: ¥60,000)
Keywords燃料電池材料 / 燃料電池 / 中温作動 / ジメチルエーテル / インピーダンス測定
Research Abstract

In this study, we developed R-MnO2 catalyst that has higher activity for anode of the direct-DME fuel cell operated at intermediate-temperature. In order to investigate the mechanism how this catalyst makes a high activity, we applied both the a. c. impedance measurements and the inelastic neutron scattering. We found that the specific crystal structure of R-MnO2 (especially typical O-O bond length of R-MnO2) make the proton conductivity in the catalyst higher, and then the fuel cell performance is increased with this anodic catalyst.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (23 results)

All 2013 2012 2011 2010 Other

All Journal Article (11 results) (of which Peer Reviewed: 6 results) Presentation (12 results)

  • [Journal Article] Effect of crystal structure of manganese dioxide on response for electrolyte of a hydrogen sensor operative at room temperature2013

    • Author(s)
      Hideki Koyanaka, Yoshikatsu Ueda, Ken Takeuchi and Alexander I. Kolesnikov
    • Journal Title

      Sensors & Actuators B: Chemical

      Volume: Vol. 183 Pages: 641-647

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Proton conducton in eletrolyte made of managenese dioxide for hydrogen gas sensor2012

    • Author(s)
      Hideki Koyanaka, Yoshikatsu Ueda, Ken Takeuchi and Alexander I. Kolesnikov
    • Journal Title

      Proceedings of IMCS 2012-The 14thInternational Meeting on Chemical Sensors

      Pages: 497-499

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Kolesnikov and Hideki Koyanaka, Electrochemical property of proton-conductive manganese dioxide for sensoring hydrogen gas concentration2012

    • Author(s)
      Yoshikatsu Ueda, Yomei Tokuda, Toshinobu Yoko, Ken Takeuchi, Alexander I
    • Journal Title

      Solid State Ionics

      Volume: Vol225 Pages: 282-285

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical property of proton-conductive manganese dioxide forsensoring hydrogen gas concentration2012

    • Author(s)
      Y. Ueda, Y. Tokuda, T. Yoko, K. Takeuchi, A. I. Kolesnikov, and H. Koyanaka
    • Journal Title

      Solid State Ionics

      Volume: 225 Pages: 282-285

    • DOI

      10.1016/j.ssi.2012.04.006

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hideki Koyanaka2012

    • Author(s)
      Proton conduction in electrolyte made of manganese dioxide for hydrogen gas sensor
    • Journal Title

      Proceedings of IMCS 2012-The 14th International Meeting on Chemical Sensors

      Volume: 14 Pages: 497-499

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] irect-DME SOFC for Intermediate Operation Temperature Using Proton Conductor as the Electrolyte2011

    • Author(s)
      Ken Takeuchi, Rouske Tai, Koichi Ui, Kenjiro Fujimoto, Sigeru Ito, Hideki Koyanaka and N. Koura
    • Journal Title

      ECS Transactions

      Volume: Vol.35 Pages: 2755-2759

    • Related Report
      2012 Final Research Report
  • [Journal Article] Electrochemical Property of Manganese Dioxide Electrolyte for Sensoring Hydrogen Gas Concentration Chemical Sensors2011

    • Author(s)
      Yoshikatsu Ueda, Hideki Koyanaka, Yomei Tokuda and Ken Takeuchi
    • Journal Title

      Supplement A

      Volume: Vol.27 Pages: 121-123

    • Related Report
      2012 Final Research Report
  • [Journal Article] Electrochemical Property of Manganese Dioxide Electrolyte for Sensoring Hydrogen Gas Concentration2011

    • Author(s)
      Yoshikatsu Ueda, Hideki Koyanaka, Yomei Tokuda, Ken Takeuchi
    • Journal Title

      Chemical Sensors

      Volume: 27 Pages: 121-123

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Direct-DME SOFC for Intermediate Operation Temperature Using Proton Conductor as the Electrolyte2011

    • Author(s)
      Ken Takeuchi, Rouske Tai, Koichi Ui, Kenjiro Fujimoto, Sigeru Ito, Hideki Koyanaka, N.Koura
    • Journal Title

      ECS Transactions

      Volume: 35 Pages: 2755-2759

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Local crystal structure of nano-manganese-oxide gold adsorbent2010

    • Author(s)
      Satoshi Iikubo, Hideki Koyanaka, Shin-ichi Shamoto, Ken Takeuchi, Shinji Kohara, Katsuaki Kodama and Chun-Keung Loong
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: Vol.71 Pages: 1603-1608

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Property of Hydrogen Gas Sensor Using a Manganese Dioxide Electrolyte2010

    • Author(s)
      Yoshikatsu Ueda, Masahiko Tsujimoto, Hideki Koyanaka, Ken Takeuchi and Yomei Tokuda
    • Journal Title

      Chemical Sensors

      Volume: Vol.26 Pages: 31-33

    • Related Report
      2012 Final Research Report
  • [Presentation] 高純度ラムズデライト型二酸化マンガンによる水分子の酸化分解反応に基づく電子とプロトンおよび酸素の発生と貴金属微粒子析出を伴う充放電サイクル2013

    • Author(s)
      古屋仲秀樹、竹内 謙、Alexander I.Kolesnikov
    • Organizer
      電気化学会第80回大会
    • Place of Presentation
      東北大学、仙台
    • Year and Date
      2013-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] Conversion of CH4 Into H2 At 300℃ Using Pd/MnO2Catalyst Made With An Effect of Water Oxidation2013

    • Author(s)
      Hideki Koyanaka, Ken Takeuchi and Alexander I.Kolesnikov
    • Organizer
      224th ECS Meeting
    • Place of Presentation
      San Francisco, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] Development of the Solid Oxide Fuel Cell Operated at Intermediate-temperature for Direct Utilization of Dimethylether Fuel2012

    • Author(s)
      Ken Takeuchi, Koichi Ui, Kenjiro Fujimoto, Shigeru Ito, Nobuyuki Koura, C.-K. Loong and Hideki Koyanaka
    • Organizer
      2012 (3rd) Taiwan-Japan Symposium on Polyscale Technologies for Biomedical Engineering and Environmental Sciences(PT-BMES 2012)
    • Place of Presentation
      National Tsing Hua University, Hsinchu, Taiwan
    • Year and Date
      2012-09-05
    • Related Report
      2012 Final Research Report
  • [Presentation] Proton conduction in electrolyte made of manganese dioxide for hydrogen gas sensor2012

    • Author(s)
      Hideki Koyanaka, Yoshikatsu Ueda, Ken Takeuchi, and Alexander I.Kolesnikov
    • Organizer
      IMCS 2012 - The 14thInternational Meeting on Chemical Sensors
    • Place of Presentation
      Nurnberg/Nuremberg, Germany
    • Related Report
      2012 Final Research Report
  • [Presentation] Proton conduction in electrolyte made of manganese dioxide for hydrogen gas sensor2012

    • Author(s)
      Hideki Koyanaka
    • Organizer
      IMCS 2012 – The 14th International Meeting on Chemical Sensors
    • Place of Presentation
      Nuremberg, Germany
    • Related Report
      2012 Annual Research Report
  • [Presentation] パラジウムのナノ粒子を化学析出させた酸化マンガン触媒を用いたメタンガスの水素ガスへの直接変換2011

    • Author(s)
      古屋仲秀樹、辻本将彦、草野圭弘、竹内謙
    • Organizer
      粉体粉末冶金協会平成23年度春季大会(第107回講演大会)
    • Place of Presentation
      早稲田大学、東京
    • Year and Date
      2011-06-01
    • Related Report
      2012 Final Research Report
  • [Presentation] パラジウムのナノ粒子を化学析出させた酸化マンガン触媒を用いたメタンガスの水素ガスへの直接変換2011

    • Author(s)
      古屋仲秀樹、辻本将彦、草野圭弘、竹内謙
    • Organizer
      粉体粉末冶金協会平成23年度春季大会(第107回講演大会)
    • Place of Presentation
      東京、早稲田大学国際会議場
    • Year and Date
      2011-06-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Direct-DME SOFC for Intermediate Operation Temperature Using Proton Conductor as the Electrolyte2011

    • Author(s)
      Ken Takeuchi, Ryosuke Tai, Koichi Ui, Kenjiro Fujimoto, Shigeru Ito, Hideki Koyanaka and Nobuyuki Koura
    • Organizer
      219th ECS Meeting
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      2011-05-06
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] 水素濃度計測用MnO2電解質の電気化学的特性2011

    • Author(s)
      上田義勝 、 古屋仲秀樹 、徳田陽明 、竹内 謙
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国立大学、横浜
    • Year and Date
      2011-03-31
    • Related Report
      2012 Final Research Report
  • [Presentation] Solid Oxide Fuel Cell for Direct Utilization of DME at Intermediate Temperature2010

    • Author(s)
      Ken Takeuchi, Ryosuke Tai, Koichi Ui, Kenjiro Fujimoto, Shigeru Ito, Hideki Koyanaka and Nobuyuki Koura
    • Organizer
      Asian SOFC Symposium
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Presentation] Development of the Solid Oxide Fuel Cell Operated at Intermediate-temperature for Direct Utilization of Dimethylether Fuel

    • Author(s)
      Ken Takeuchi
    • Organizer
      2012 (3rd) Taiwan-Japan Symposium on Polyscale Technologies for Biomedical Engineering and Environmental Sciences (PT-BMES 2012)
    • Place of Presentation
      National Tsing Hua University, Hsinchu, Taiwan
    • Related Report
      2012 Annual Research Report
  • [Presentation] 高純度ラムズデライト型二酸化マンガンによる水分子の酸化分解反応に基づく電子とプロトンおよび酸素の発生と貴金属微粒子析出を伴う充放電サイクル

    • Author(s)
      古屋仲秀樹
    • Organizer
      電気化学会第80回大会
    • Place of Presentation
      東北大学、仙台
    • Related Report
      2012 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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