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Impedance Analyses on Porous Electrodes Considering the Distribution of Time Constants

Research Project

Project/Area Number 22560729
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionTokyo University of Science

Principal Investigator

ITAGAKI Masayuki  東京理科大学, 理工学部, 教授 (90266908)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords電気化学インピーダンス / 電気化学測定 / 多孔質電極 / インピーダンススペクトル / 表面・界面物性 / 先端機能デバイス / 材料加工・処理
Research Abstract

This study has been carried out to contribute to analyses on electrode structures of energy devices by applying an electrochemical impedance spectroscopy (EIS) to them. This study consists of EIS analyses on porous electrodes and cell structure analyses by finite element method (FEM). In the application of EIS, impedance spectra of porous electrode was separated depending on the frequency ranges, and itwas found that characteristic locus appeared for the porous structure in the middle frequency range. Pore size and electrolyte nature in the pore were investigated on the basis of impedance spectra. The current distribution during impedance measurement was calculated by FEM. It was found that the current distribution was changed depending on the imposed frequency. The relation between the porous structure and the characteristic impedance locus was discussed comparing the impedance results with the calculated current distribution. The analytical method developed by this study can be contributed to the material developments and operation monitoring’s of various energy devices.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (3 results)

All 2013 2012

All Presentation (3 results)

  • [Presentation] Relation between Penetration Depth and Potential Distribution in Porous Electrode2013

    • Author(s)
      H. Hoshi, T. Imai, I. Shitanda, M. Itagaki
    • Organizer
      9th International Symposium on Electrochemical Impedance Spectroscopy
    • Place of Presentation
      Okinawa
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Current Distribution of Dye-Sensitized solar Cells during Impedance Measurement by FEM2013

    • Author(s)
      T. Ohtaki, H. Hoshi, I. Shitanda, M. Itagaki
    • Organizer
      9th International Symposium on Electrochemical Impedance Spectroscopy
    • Place of Presentation
      Okinawa
    • Related Report
      2012 Final Research Report
  • [Presentation] 多孔質電極の電気化学インピーダンスに及ぼす多次元的な電位分布の影響に関する検討2012

    • Author(s)
      今井貴弘, 四反田功, 板垣昌幸
    • Organizer
      電気化学会大79回大会
    • Place of Presentation
      浜松
    • Year and Date
      2012-03-30
    • Related Report
      2011 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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