Development of new oxygen storage material by local structure control of cation in interlayer.
Project/Area Number |
22560763
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Catalyst/Resource chemical process
|
Research Institution | Akita University |
Principal Investigator |
NAKATA Shinichi 秋田大学, 大学院・工学資源学研究科, 教授 (70312692)
|
Co-Investigator(Kenkyū-buntansha) |
KATO Sumio 秋田大学, 大学院・工学資源学研究科, 准教授 (50233797)
|
Project Period (FY) |
2010 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
|
Keywords | 酸素吸蔵材料 / 酸素吸蔵能 / デラフォサイト / 銅酸化物 |
Research Abstract |
Oxygen storage property of delafossite-type copper oxides and their structural stability under oxidative/reductive atmosphere at high temperature have been investigated. It is found that oxygen storage behavior of Cr containing delafossite was caused by reductive decomposition of the delafossite-phase to spine-type phase and metallic copper, and regeneration of the delafossite-phase under oxidative atmosphere. Oxygen storage property was controlled by adjustment of Cu-Cu distance in the delafossite lattice by means of cation substitution on octahedral site.
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Report
(4 results)
Research Products
(8 results)