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Development of Ni-based intermetallic foil catalysts

Research Project

Project/Area Number 22560769
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionNational Institute for Materials Science

Principal Investigator

YA Xu  独立行政法人物質・材料研究機構, 水素利用材料ユニット, 主幹研究員 (00370304)

Co-Investigator(Kenkyū-buntansha) DEMURA Masahiko  独立行政法人物質・材料研究機構, 水素利用材料ユニット, 主任研究員 (10354177)
HIRANO Toshiyuki  独立行政法人物質・材料研究機構, 水素利用材料ユニット, NIMS特別研究員 (90354183)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords金属間化合物 / プレート型触媒 / 水素製造触媒 / Ni基金属間化合物箔 / メタノール分解 / Ni基金属間化合物 / メタノール分解反応
Research Abstract

In order to develop low-cost, highly-efficient catalysts for hydrogen production, we examined the catalytic properties of Ni-based intermetallic compounds, Ni3Fe and Ni3Sn, where Fe and Sn have similar oxidation potential to Ni. It was found that both intermetallics show high catalytic activity and selectivity for methanol decomposition. The mechanism for the excellent catalytic properties was proposed based on the detail characterization of the compounds.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (52 results)

All 2013 2012 2011 2010 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (37 results) (of which Invited: 1 results) Book (1 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Improvement of catalytic activity of atomized Ni_3Al powder for methanol decomposition by surface chemical treatments2013

    • Author(s)
      Ya Xu, M. Demura, T. Hirano
    • Journal Title

      Materials Science Forum

      Volume: Vol. 750 Pages: 68-71

    • DOI

      10.4028/www.scientific.net/msf.750.68

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Properties of Ni_3Fe Foil for Hydrogen Production from Methanol2012

    • Author(s)
      Y.Xu
    • Journal Title

      Materials Science Forum

      Volume: 706-709 Pages: 1052-1057

    • DOI

      10.4028/www.scientific.net/msf.706-709.1052

    • Related Report
      2012 Annual Research Report 2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic properties of TiNi foils for methanol decomposition2012

    • Author(s)
      J. Sakurai, Ya Xu, M. Demura, T. Hirano, R. Tamura
    • Journal Title

      Advanced Materials Research

      Volume: Vol. 409 Pages: 307-312

    • DOI

      10.4028/www.scientific.net/amr.409.307

    • Related Report
      2012 Annual Research Report 2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic activity improvement of Ni_3Al foils for methanol decomposition by oxidation-reduction pretreatment2011

    • Author(s)
      Jun Hyuk Jang, Ya Xu, Masahiko Demura, Dang Moon Wee, Toshiyuki Hirano
    • Journal Title

      Applied catalysis A: General

      Volume: Vol. 398 Issue: 1-2 Pages: 161-167

    • DOI

      10.1016/j.apcata.2011.03.040

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Properties of Ni3Al Foils for Hydrogen Production2011

    • Author(s)
      T. Hirano, Ya Xu, M. Demura
    • Journal Title

      Advanced Materials Research

      Volume: Vols. 306-307 Pages: 130-133

    • DOI

      10.4028/www.scientific.net/amr.306-307.130

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Texture and Ductility of Ni_3Al foils2011

    • Author(s)
      M. Demura, Ya Xu, T. Hirano
    • Journal Title

      Advanced Materials Research

      Volume: Vols. 306-307 Pages: 116-119

    • DOI

      10.4028/www.scientific.net/amr.306-307.116

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic activity improvement of Ni3Al foils for methanol decomposition by oxidation-reduction pretreatment2011

    • Author(s)
      Jun Hyuk Jang, Ya Xu, Masahiko, Demura, Dang, Moon Wee, Toshiyuki Hirano
    • Journal Title

      Applied Catalysis A : General

      Volume: 398 Pages: 161-167

    • DOI

      10.1016/j.apcata.2011.10.036

    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective dissolution of γ phase in binary Ni(γ)/Ni_3Al(γ´) two-phase alloys2010

    • Author(s)
      H.Y. Lee, M. Demura, Ya Xu, D.M. Wee, T. Hirano
    • Journal Title

      Corrosion Science

      Volume: Vol. 52 Issue: 11 Pages: 3820-3825

    • DOI

      10.1016/j.corsci.2010.07.036

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Ni-Al Intermetallic Nanoparticle Catalysts by Vacuum Arc Plasma Evaporation2010

    • Author(s)
      Ya Xu, J.Y. Yang, M. Demura, T. Hara, T. Hirano
    • Journal Title

      Materials Science Forum

      Volume: Vols. 654-656 Pages: 2907-2910

    • DOI

      10.4028/www.scientific.net/msf.654-656.2907

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Selective dissolution of Y phase in binary Ni(Y)/Ni_3aAl(Y')/two-phase alloys2010

    • Author(s)
      H.Y.Lee, M.Demura, Ya Xu, D.M.Wee, T.Hirano
    • Journal Title

      Corrosion Science

      Volume: 52 Pages: 3820-3825

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Ni-Al Intermetallic Nanoparticle Catalysts by Vacuum Arc Plasma Evaporation2010

    • Author(s)
      Ya Xu, J.Y.Yang, M.Demura, T.Hara, T.Hirano
    • Journal Title

      Materials Science Forum

      Volume: 654-656 Pages: 2907-2910

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Ni3Al圧延箔のメタン水蒸気改質触媒特性2013

    • Author(s)
      許亜, 馬雁, 櫻井惇也, 出村雅彦, 平野敏幸, 寺岡有殿, 吉越章隆
    • Organizer
      日本金属学会2013春期講演大会
    • Place of Presentation
      東京理科大、東京
    • Related Report
      2012 Final Research Report
  • [Presentation] Ni基金属間化合物箔を用いた新しい水素製造触媒2013

    • Author(s)
      許亜
    • Organizer
      多元研ミニシンポジウム:「貴金属代替」? 合金からの挑戦?
    • Place of Presentation
      東北大、仙台
    • Related Report
      2012 Final Research Report
  • [Presentation] Ni基金属間化合物箔を用いた新しい水素製造触媒2013

    • Author(s)
      許亜
    • Organizer
      多元研ミニシンポジウム:「貴金属代替」~合金からの挑戦~
    • Place of Presentation
      仙台
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Ni3Al圧延箔のメタン水蒸気改質触媒特性2013

    • Author(s)
      許亜
    • Organizer
      日本金属学会2013春期講演大会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 熱プラズマ法によるNi3Al基ナノ粒子の作製とそのCO酸化触媒特性2012

    • Author(s)
      許亜, 楊君友, 出村雅彦, 平野敏幸, 松下能孝, 田中雅彦
    • Organizer
      日本金属学会2012年秋期講演大会
    • Place of Presentation
      愛媛大学, 松山
    • Related Report
      2012 Final Research Report
  • [Presentation] Improvement of Catalytic activity of atomized Ni3Al powder for methano l decomposition by surface chemical treatments2012

    • Author(s)
      Ya Xu, M. Demura, T. Hirano
    • Organizer
      The 8th International Forum on Advanced Materials Science and Technology
    • Place of Presentation
      Fukuoka Institute of Technology, Fukuoka
    • Related Report
      2012 Final Research Report
  • [Presentation] Ni-based intermetallic catalysts for hydrogen production2012

    • Author(s)
      Ya Xu, M. Demura, T. Hirano
    • Organizer
      2nd International Symposium on Methanol Steam Reforming, Ludwig-Maximilians-Universit Mnchen
    • Place of Presentation
      Commundo Tagungs Hotel,Ismaning, Germany
    • Related Report
      2012 Final Research Report
  • [Presentation] Catalytic properties of Ni-Al intermetallic nanoparticle catalysts for hydrogen production from methanol and methane2012

    • Author(s)
      Ya Xu, J.Y. Yang, M. Demura, T. Hirano
    • Organizer
      141st TMS Annual Meeting
    • Place of Presentation
      Swan & Dolphin Resort, Orlando, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] 熱プラズマ法によるNi3Al基ナノ粒子の作製とそのCO酸化触媒特性2012

    • Author(s)
      許亜
    • Organizer
      日本金属学会2012年秋期講演大会
    • Place of Presentation
      松山
    • Related Report
      2012 Annual Research Report
  • [Presentation] 水素製造用Ni基金属間化合物触媒2012

    • Author(s)
      許亜
    • Organizer
      2nd International Symposium on Methanol Steam Reforming
    • Place of Presentation
      Smaning, Germany
    • Related Report
      2012 Annual Research Report
  • [Presentation] Ni基金属間化合物プレート型触媒の研究2011

    • Author(s)
      許亜, 出村雅彦, 平野敏幸
    • Organizer
      第4回触媒材料研究会, 日本金属学会
    • Place of Presentation
      東北大学, 仙台
    • Year and Date
      2011-09-02
    • Related Report
      2012 Final Research Report
  • [Presentation] TiNi箔のメタノール分解触媒特性に及ぼす表面酸化物層の影響2011

    • Author(s)
      櫻井惇也、許亜, 出村雅彦, 平野敏幸
    • Organizer
      第4回触媒材料研究会, 日本金属学会
    • Place of Presentation
      東北大学, 仙台
    • Year and Date
      2011-09-02
    • Related Report
      2012 Final Research Report
  • [Presentation] Ni基金属間化合物プレート型触媒の研究2011

    • Author(s)
      許亜、出村雅彦、平野敏幸
    • Organizer
      第4回触媒材料研究会
    • Place of Presentation
      仙台(招待講演)
    • Year and Date
      2011-09-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] TiNi箔のメタノール分解触媒特性に及ぼす表面酸化物層の影響2011

    • Author(s)
      櫻井惇也、許亜、出村雅彦、平野敏幸、田村隆治
    • Organizer
      第4回触媒材料研究会
    • Place of Presentation
      仙台
    • Year and Date
      2011-09-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis of Ni-Al intermetallic nanoparticle catalysts by vacuum arc plasma evaporation2011

    • Author(s)
      Ya Xu, Junyou Yang, Masahiko Demura, Toru Hara, Toshiyuki Hirano
    • Organizer
      3^<rd> International Symposium on Plasma Science (ISPlasma2011)
    • Place of Presentation
      名古屋工業大学(愛知県)
    • Year and Date
      2011-02-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] Ni基金属間化合物プレート型触媒の研究2011

    • Author(s)
      許亜, 出村雅彦, 平野敏幸
    • Organizer
      2011年度日本金属学会秋期大会
    • Place of Presentation
      沖縄コンベンションセンター,宜野湾市
    • Related Report
      2012 Final Research Report
  • [Presentation] TiNi箔のメタノール分解触媒特性に及ぼす表面酸化物層の影響2011

    • Author(s)
      櫻井惇也、許亜, 出村雅彦, 平野敏幸
    • Organizer
      2011年度日本金属学会秋期大会
    • Place of Presentation
      沖縄コンベンションセンター,宜野湾市
    • Related Report
      2012 Final Research Report
  • [Presentation] 加工性に富んだNi基メタン水蒸気改質触媒の開発2011

    • Author(s)
      長谷川誠,原恭,吉田正就、出村雅彦,許亜
    • Organizer
      2011年度日本金属学会秋期大会
    • Place of Presentation
      沖縄コンベンションセンター,宜野湾市
    • Related Report
      2012 Final Research Report
  • [Presentation] Ni/Ni3Al複相組織を利用したプレート触媒の高活性化2011

    • Author(s)
      出村雅彦, HyeYoun Lee, 許亜, Dang-Moon Wee, 平野敏幸
    • Organizer
      2011年度日本金属学会秋期大会
    • Place of Presentation
      沖縄コンベンションセンター,宜野湾市
    • Related Report
      2012 Final Research Report
  • [Presentation] Catalytic Properties of Ni3Fe Foil for Hydrogen Production from Methanol decomposition2011

    • Author(s)
      Ya Xu, M. Demura, T. Hirano, Y. Kaneno, T. Takasugi
    • Organizer
      7th International conference on advanced materials(THERMIC2011), TMS
    • Place of Presentation
      Quebec City Convention Centre, Quebec City, CANADA
    • Related Report
      2012 Final Research Report
  • [Presentation] Methanol decomposition on TiNi foils2011

    • Author(s)
      J. Sakurai, Ya Xu, M. Demura, T. Hirano
    • Organizer
      7th International conference on advanced materials(THERMIC2011), TMS
    • Place of Presentation
      Quebec City Convention Centre, Quebec City, CANADA
    • Related Report
      2012 Final Research Report
  • [Presentation] Mechanism of texture memory effect in the heavily cold-rolled Ni_3Al single crystals2011

    • Author(s)
      M. Demura, Ya Xu, T. Hirano
    • Organizer
      7th International conference on advanced materials(THERMIC2011), TMS
    • Place of Presentation
      Quebec City Convention Centre, Quebec City, CANADA
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis of Ni-Al intermetallic nanoparticle catalysts by thermal plasma2011

    • Author(s)
      許亜, 楊君友, 出村雅彦, 平野敏幸, 松下能孝, 田中雅彦, 原徹
    • Organizer
      3rd International Symposium on Plasma Science (ISPlasma2011)
    • Place of Presentation
      名古屋工業大学,名古屋
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis of Ni-Al intermetallic nanopowder catalysts by vacuum arc plasma evaporation2011

    • Author(s)
      許亜, 楊君友, 出村雅彦, 平野敏幸, 松下能孝, 田中雅彦, 原徹
    • Organizer
      NIMS International Symposium on Photocatalysis and Environmental, NIMS
    • Place of Presentation
      Tsukuba
    • Related Report
      2012 Final Research Report
  • [Presentation] Texture and Ductility of Ni3Al foils2011

    • Author(s)
      M.Demura, Ya Xu, T.Hirano
    • Organizer
      1st International Conference on Advanced Materials 2011
    • Place of Presentation
      Jinian, China(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Catalytic Properties of Ni3Al Foils for Hydrogen Production2011

    • Author(s)
      T.Hirano, Ya Xu, M.Demura
    • Organizer
      1st International Conference on Advanced Materials 2011
    • Place of Presentation
      Jinian, China(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Catalytic Properties of Ni3Fe Foil for Hydrogen Production from Methanol2011

    • Author(s)
      Ya Xu, M.Demura, T.Hirano, Y.Kaneno, T.Takasugi
    • Organizer
      7th International conference on advanced materials (THERMIC2011)
    • Place of Presentation
      Quebec, Canada(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Mechanism of texture memory effect in the heavily cold-rolled Ni3Al single crystals2011

    • Author(s)
      M.Demura, Ya Xu, T.Hirano
    • Organizer
      7th International conference on advanced materials (THERMIC2011)
    • Place of Presentation
      Quebec, Canada(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Methanol decomposition on TiNi foils2011

    • Author(s)
      J.Sakurai, Ya Xu, M.Demura, T.Hirano, R.Tamura
    • Organizer
      7th International conference on advanced materials (THERMIC2011)
    • Place of Presentation
      Quebec, Canada
    • Related Report
      2011 Annual Research Report
  • [Presentation] Ni基金属間化合物プレート型触媒の研究2011

    • Author(s)
      許亜、出村雅彦、平野敏幸
    • Organizer
      日本金属学会2011年秋期大会
    • Place of Presentation
      沖縄(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] TiNi箔のメタノール分解触媒特性に及ぼす表面酸化物層の影響2011

    • Author(s)
      櫻井惇也、許亜、出村雅彦、平野敏幸、田村隆治
    • Organizer
      日本金属学会2011年秋期大会
    • Place of Presentation
      沖縄
    • Related Report
      2011 Annual Research Report
  • [Presentation] Ni/Ni3Al複相組織を利用したプレート触媒の高活性化2011

    • Author(s)
      出村雅彦, HyeYoun Lee, 許亜, Dang-Moon Wee, 平野敏幸
    • Organizer
      日本金属学会2011年秋期大会
    • Place of Presentation
      沖縄
    • Related Report
      2011 Annual Research Report
  • [Presentation] TiNi金属間化合物箔のメタノール分解反応に対する触媒特性2010

    • Author(s)
      櫻井惇也、田村隆治、許亜、出村雅彦、平野敏幸
    • Organizer
      2010年金属学会秋季講演大会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2010-09-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Catalytic performance of pretreated Ni_3Al foil by oxidation-reduction for hydrogen production from methanol and oxygen2010

    • Author(s)
      J.H.Jang, Ya Xu, M.Demura, D.M.Wee, T.Hirano
    • Organizer
      2010年金属学会秋季講演大会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2010-09-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Surface evolution of Ni_3Al foil catalyst during the initial period of methanol decomposition studied by hard X-ray photoelectron spectroscopy2010

    • Author(s)
      Ya Xu, H.Yoshikawa, J.H.Jang, M.Demura, K.Kobayashi, S.Ueda, Y.Yamashita, D.M.Wee, T.Hirano
    • Organizer
      The 18^<th> International Vacuum Congress (IVC-18)
    • Place of Presentation
      ternational Convention Center Beijing,(中国)
    • Year and Date
      2010-08-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] TiNi金属間化合物箔のメタノール分解反応に対する触媒特性2010

    • Author(s)
      櫻井惇也、許亜, 出村雅彦, 平野敏幸
    • Organizer
      日本金属学会2010年秋期大会
    • Place of Presentation
      北海道大学,札幌
    • Related Report
      2012 Final Research Report
  • [Presentation] Catalytic performance of pretreated Ni_3Al foil by oxidation-reduction for hydrogen production from methanol and oxygen2010

    • Author(s)
      Jun Hyuk Jang, Ya Xu, Masahiko Demura, Dang Moon Wee, Toshiyuki Hirano
    • Organizer
      日本金属学会2010年秋期大会
    • Place of Presentation
      北海道大学,札幌
    • Related Report
      2012 Final Research Report
  • [Book] メタン改質触媒材料、環境・エネルギー材料ハンドブック2011

    • Author(s)
      許亜
    • Publisher
      オーム社出版
    • Related Report
      2012 Final Research Report
  • [Remarks] NIMS Researcher Database SAMURAI

    • URL

      http://samurai.nims.go.jp/by_unit_jg15.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://samurai.nims.go.jp/XU_Ya-j.html

    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] ニッケルクロム合金触媒およびその製造方法2011

    • Inventor(s)
      長谷川誠、河口誠司、吉田正就、出村雅彦、許亜
    • Industrial Property Rights Holder
      物質・材料研究機構、(株)不二越
    • Industrial Property Number
      2011-038133
    • Filing Date
      2011-02-24
    • Related Report
      2012 Final Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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