Development of asymmetrically catalytic reactions produced only small amount of carbon dioxide using sea water as a reaction solvent
| Project/Area Number |
22590007
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Gifu Pharmaceutical University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
ITOH Akichika 岐阜薬科大学, 薬学部, 教授 (10203126)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 海水 / 有機触媒 / 温室効果ガス削減 / フルオラス / 環境技術 / 合成化学 / アルドール反応 / マイケル付加 |
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| Research Abstract |
To achieve lowering of carbon dioxide, we examined the development of efficient organocatalysts that can use in ecofriendly sea water as a reaction solvent instead of an organic solvent. We have found that novel sulfonamide oraganocatalysts promote efficiently asymmetric aldol reactions in water or brine. The organocatalysts have been improved their catalytic activity by introduction of fluorous group. In addition, the fluorous oraganocatalysts can be easily recovered and reused.
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Report
(4 results)
Research Products
(31 results)
