New synthetic reactions using zirconocene complexes as nucleophiles
| Project/Area Number |
22590016
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Showa Pharmaceutical University |
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Principal Investigator |
HANZAWA Yuji 昭和薬科大学, 薬学部, 教授 (10096688)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Keywords | 有機化学 / 有機合成 / ジルコノセン錯体 / 遷移金属触媒 / 複素環構築 / ライセルト型反応 / 求核反応 / エナンチオ選択性 / アシルジルコノセン / ジルコノセン / 触媒 / 複素環 / 超原子価ヨウ素 / エナンチオ選択的反応 / 不斉配位子 |
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| Research Abstract |
Search for the new reactivity of zirconocene chloride complexes as nucleophiles under transition metal-catalyzed conditions brought about the efficient carbon-carbon bond formation even in an enatioselective reaction. Particularly, the reaction with heter
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Report
(4 results)
Research Products
(49 results)
