Synthesis of highly functionalized compounds through electron transfer processes free from heavy metals and rare metals
| Project/Area Number |
22605003
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
元素戦略
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| Research Institution | Nagaoka University of Technology |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
YAMAMOTO Yoshimasa 東京工業高等専門学校, 物質工学科, 講師 (90444190)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Keywords | マグネシウム / 選択的合成 / 機能物質 / 環境調和型合成 / 有機工業化学 / 合成化学 / トリフルオロ酢酸エチル / クロスカップリング / 電子移動 / 還元 / 極性変換 / 炭酸ガス |
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| Research Abstract |
Mg-promoted reductive coupling of aromatic carbonyl compounds and ethyl trifluoroacetate brought about selective formation of fluorine-containing organic compounds. In general, the synthesis of fluorinated compounds is not easy, but it could be achieved by use of cheaper fluorine-containing reagents in these reactions. The reductive coupling reaction of aromatic carbonyl compounds and carbon dioxide gave the carboxylated compounds through the carbon-carbon bond formation. Mg-promoted reductive trifluoroacetylation of azulene led to the synthesis of 6-trifluoroacetylazulene in good yield.
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Report
(4 results)
Research Products
(105 results)
