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Pathfinding research for marine geochemistry of palladium, platinum and gold

Research Project

Project/Area Number 22651006
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Environmental dynamic analysis
Research InstitutionKyoto University

Principal Investigator

SOHRIN Yoshiki  京都大学, 化学研究所, 教授 (50197000)

Co-Investigator(Renkei-kenkyūsha) NORISUYE Kazuhiro  京都大学, 化学研究所, 助教 (50335220)
FIRDAUS M. lutfi  京都大学, 化学研究所, 助教 (20467434)
Research Collaborator YAMAMOTO Jun  京都大学, 理学研究科化学専攻, 修士課程
Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,430,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥2,000,000 (Direct Cost: ¥2,000,000)
Keywords化学海洋 / 地球化学 / 分析化学 / 貴金属 / 物質循環 / キレート樹脂固相抽法 / 高分解能ICP質量分析装置 / 海水 / キレート吸着剤固相抽法
Research Abstract

Since the concentrations of palladium, platinum and gold is extremely low in natural waters and it is difficult to determine them, their cycling in the hydrosphere is not known well. In the present study, we have investigated preconcentration using an ethylenediamine-chelating resin and highly sensitive measurement using a high resolution ICP mass spectrometer in order to develop a novel analytical method with high precision. Although we have succeeded in suppressing contamination during the preconcentration, some problems are still unsolved in preconcentration from a large volume sample.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (48 results)

All 2012 2011 2010 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (36 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Determination of bismuth in open ocean waters by inductively coupled plasma sector-field mass spectrometry after chelating resin column preconcentration2012

    • Author(s)
      Norisuye, K., Sohrin, Y.
    • Journal Title

      Analytica Chimica Acta

      Volume: (印刷中)(未定)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The molybdenum isotopic composition of the modern ocean2012

    • Author(s)
      Nakagawa, Y., Takano, S., Firdaus, M.L., Norisuye, K., Hirata, T., Vance, D., Sohrin, Y.
    • Journal Title

      Geochemical Journal

      Volume: (印刷中)(未定)

    • NAID

      10030744677

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Global status of trace elements in the ocean2011

    • Author(s)
      Sohrin, Y, Bruland, K. W.
    • Journal Title

      TrAC Trends in Analytical Chemistry

      Volume: 30(8) Issue: 8 Pages: 1291-1307

    • DOI

      10.1016/j.trac.2011.03.006

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stoichiometry among bioactive trace metals in seawater on the Bering Sea shelf2011

    • Author(s)
      Cid, A., Urushihara, S., Minami, T., Norisuye, K., Sohrin, Y.
    • Journal Title

      Journal of Oceanography

      Volume: 67 Issue: 6 Pages: 747-764

    • DOI

      10.1007/s10872-011-0070-z

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lake Biwa and the ocean : Geochemical similarity and difference2011

    • Author(s)
      Li, Y.H., Sohrin, Y, Takamatsu, T.
    • Journal Title

      Limnology

      Volume: 12 Issue: 1 Pages: 89-101

    • DOI

      10.1007/s10201-010-0326-0

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Strong elemental fractionation of Zr-Hf and Nb-Ta across the Pacific Ocean2011

    • Author(s)
      Firdaus, M.L., Minami, T., Norisuye, K., Sohrin, Y.
    • Journal Title

      Nature Geoscience

      Volume: 4 Issue: 4 Pages: 227-230

    • DOI

      10.1038/ngeo1114

    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lake Biwa and the ocean : Geochemical similarity and difference2011

    • Author(s)
      Li, Y.H., Sohrin, Y., Takamatsu, T.
    • Journal Title

      Limnology

      Volume: 12 Pages: 89-101

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 外洋海水中の生物活性微量金属の一括定量法の開発と国際相互校正への適用2010

    • Author(s)
      南知晴, 肥後衣里, 中塚清次, Cid, Abigail Parcasio, Vu, Thi Dieu Huong, 則末和宏, 宗林由樹
    • Journal Title

      分析化学

      Volume: 59 Pages: 1087-1096

    • NAID

      10026969015

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solvent Extraction of Metal Ions with 4,5-Bis(diphenylphosphinoyl)-1,2,3-Triazole2010

    • Author(s)
      Mukai, H., Ono, S., Maruyama, Y., Minami, A., Sasamori, T., Tokitoh, N., Sohrin, Y.
    • Journal Title

      Journal of Ion Exchange

      Volume: 21 Pages: 227-230

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 北太平洋におけるビスマス(209Bi)の分布---KH-11-7航海観測結果を中心に---2012

    • Author(s)
      則末和宏, 山本純, 高野祥太朗, 宗林由樹
    • Organizer
      白鳳丸クリーン観測による微量元素・同位体研究の現状と展望(GEOTRACES計画)
    • Place of Presentation
      東京大学大気海洋研究所,柏
    • Year and Date
      2012-03-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] キレート樹脂を用いた海水中Cu安定同位体比精密測定法の開発2012

    • Author(s)
      高野祥太朗, 宗林由樹, 平田岳史, 谷水雅治
    • Organizer
      白鳳丸クリーン観測による微量元素・同位体研究の現状と展望(GEOTRACES計画)
    • Place of Presentation
      東京大学大気海洋研究所,柏
    • Year and Date
      2012-03-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] 日本海における生体活性微量金属の分布と挙動-白鳳丸KH-10-2次航海とKH-84-3次航海の分析結果2012

    • Author(s)
      中口譲, 坂本敦史, 西内明, 竹内誠, Vu, H.T.D., 南知晴, 宗林由樹
    • Organizer
      白鳳丸クリーン観測による微量元素・同位体研究の現状と展望(GEOTRACES計画)
    • Place of Presentation
      東京大学大気海洋研究所,柏
    • Year and Date
      2012-03-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] Distribution and behavior of dissolved bioactive trace metals in the Indian Ocean2012

    • Author(s)
      Vu, H.T.D., Sohrin, Y.
    • Organizer
      白鳳丸クリーン観測による微量元素・同位体研究の現状と展望(GEOTRACES計画)
    • Place of Presentation
      東京大学大気海洋研究所,柏
    • Year and Date
      2012-03-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] インド洋における溶存生物活性微量金属の分布と挙動2012

    • Author(s)
      Vu, H.T.D.
    • Organizer
      第262回京都化学者クラブ例会
    • Place of Presentation
      京都大学楽友会館,京都(招待講演)
    • Year and Date
      2012-03-03
    • Related Report
      2011 Annual Research Report
  • [Presentation] 海水中重金属の生態・生体影響評価を可能とする自動濃縮分離装置の開発とその海洋観測への適用2012

    • Author(s)
      宗林由樹
    • Organizer
      公益財団法人鉄鋼環境基金助成研究研究討論会
    • Place of Presentation
      鉄鋼会館,東京(招待講演)
    • Year and Date
      2012-02-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] DEVELOPMENT OF A SIMPLE PRETREATMENT METHOD USING NOBIAS CHELATE-PA1 RESIN FOR MEASUREMENT OF COPPER ISOTOPIC COMPOSITION IN SEAWATER2012

    • Author(s)
      Takano, S., Sohrin, Y., Hirata, T., Tanimizu, M.
    • Organizer
      2012 Ocean Sciences Meeting
    • Place of Presentation
      Salt Lake City, Utah, USA
    • Year and Date
      2012-02-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] DISTRIBUTION OF DISSOLVED BISMUTH IN THE WESTERN NORTH PACIFIC2012

    • Author(s)
      Norisuye, K., Yamamoto, J., Takano, S., Sohrin, Y.
    • Organizer
      2012 Ocean Sciences Meeting
    • Place of Presentation
      Salt Lake City, Utah, USA
    • Year and Date
      2012-02-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] キレート吸着剤固相抽出と高分解能ICP質量分析法に基づく海水中超微量貴金属元素(Pd, Pt, Au)の定量2011

    • Author(s)
      山本純, 佐藤賢吾, 宗林由樹
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学東山キャンパス,名古屋
    • Year and Date
      2011-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] 自動固相抽出装置の開発と外洋海水中溶存態Al、Mn、Fe、Co、Ni、Cu、Zn、Cd、Pbの定量への適用2011

    • Author(s)
      南知晴, 小瀧修一, 宗林由樹
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学東山キャンパス,名古屋
    • Year and Date
      2011-09-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] キレート吸着剤固相抽出と高分解能ICP質量分析法に基づく海水中超微量貴金属元素(Pd,Pt,Au)の定量2011

    • Author(s)
      山本純, 佐藤賢吾, 宗林由樹
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学東山キャンパス,名古屋
    • Year and Date
      2011-09-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] 日本海における生体活性微量金属の鉛直分布2011

    • Author(s)
      坂本敦史, 中口譲, 竹内誠, 宗林由樹, Vu, H.T.D., 高野祥太朗
    • Organizer
      2011年度日本地球化学会第58回年会
    • Place of Presentation
      北海道大学札幌キャンパス,札幌
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] インド洋における生体活性微量金属の分布と粒子状物質の関係2011

    • Author(s)
      中口譲, 浅谷拓也, 廣田晶子, 西田亜希子, 南秀樹, 山田悠香子, 宗林由樹, 小畑元
    • Organizer
      2011年度日本地球化学会第58回年会
    • Place of Presentation
      北海道大学札幌キャンパス,札幌
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] ベーリング海大陸棚における生物活性微量金属のストイキオメトリー2011

    • Author(s)
      宗林由樹, Cid, A.P., 漆原聖平, 南知晴, 則末和宏
    • Organizer
      2011年度日本地球化学会第58回年会
    • Place of Presentation
      北海道大学札幌キャンパス,札幌
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 海水中Cu安定同位体比精密測定法の開発2011

    • Author(s)
      高野祥太朗, 宗林由樹, 平田岳史, 谷水雅治
    • Organizer
      2011年度日本地球化学会第58回年会
    • Place of Presentation
      北海道大学札幌キャンパス,札幌
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 生命と海の微量元素2011

    • Author(s)
      宗林由樹
    • Organizer
      第6回日本地球化学会ショートコース
    • Place of Presentation
      北海道大学札幌キャンパス,札幌(招待講演)
    • Year and Date
      2011-09-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] Marine Chemistry of Zirconium, Hafnium, Niobium and Tantalum2011

    • Author(s)
      Firdaus, M.L., Norisuye, K., Sohrin, Y.
    • Organizer
      IUPAC International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center, Kyoto(invited)
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Marine Geochemistry of Molybdenum and Tungsten2011

    • Author(s)
      Sohrin, Y.
    • Organizer
      IUPAC International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center, Kyoto(invited)
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Determination of Ultra-Trace Noble Metals(Pd, Pt and Au) in Seawater Using Chelating Resin-Solid Phase Extraction and High-Resolution ICP-MS2011

    • Author(s)
      Yamamoto, J., Sato, K., Sohrin, Y
    • Organizer
      IUPAC International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center, Kyoto
    • Year and Date
      2011-05-25
    • Related Report
      2011 Final Research Report
  • [Presentation] Developement of a Simple Pretreatment Method Using Nobias Chelate-PA1 Resin for Measurement of Copper Isotopic Composition in Seawater2011

    • Author(s)
      Takano, S., Sohrin, Y., Hirata, T.
    • Organizer
      IUPAC International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center, Kyoto
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Distribution of Dissolved Bioactive Trace Metals in the Japan Sea2011

    • Author(s)
      Sakamoto, A., Nakaguchi, Y., Takeuchi, M., Sohrin, Y., Vu, H.T.D., Takano, S.
    • Organizer
      IUPAC International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center, Kyoto
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Determination of Ultra-Trace Noble Metals (Pd, Pt and Au) in Seawater Using Chelating Resin-Solid Phase Extraction and High-Resolution ICP-MS2011

    • Author(s)
      Yamamoto, J., Sato, K., Sohrin, Y.
    • Organizer
      IUPAC International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center, Kyoto
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Development of a Simple and High-Sensitive Analytical Method for Determination of Bismuth in Seawater2011

    • Author(s)
      Norisuye, K., Sohrin, Y.
    • Organizer
      IUPAC International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center, Kyoto
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Distributions of Bioactive Trace Metals in the Eastern Bering Sea2011

    • Author(s)
      Cid, A.P., Urushihara, S., Minami, T., Norisuye, K., Sohrin, Y.
    • Organizer
      IUPAC International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center, Kyoto
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Distribution and Behaviors of Bioactive Trace Metals in the Western North Pacific Ocean2011

    • Author(s)
      Vu, H.T.D., Kono, T., Sohrin, Y.
    • Organizer
      IUPAC International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center, Kyoto
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Sectional Distribution of Dissolved Bioactive Trace Metals along 170°W in the Antarctic-Equatorial Pacific Oceans2011

    • Author(s)
      Minami, T., Higo, E., Matsunari, T., Sohrin, Y.
    • Organizer
      IUPAC International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center, Kyoto
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Multielemental determination of Al, Mn, Fe, Co, Ni, Cu, Zn, Cd and Pb in seawater using HR-ICP-MS and its application to the western North Pacific Ocean2011

    • Author(s)
      Vu, H.T.D., Kono, T., Nakatsuka, S., Sohrin, Y.
    • Organizer
      Analytica Vietnam Conference
    • Place of Presentation
      Ho Chi Minh City, Vietnam
    • Year and Date
      2011-04-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] キレート吸着剤固相抽出と高分解能ICP質量分析法に基づく海水中微量貴金族元素(Pd, Pt, Au)の定量2010

    • Author(s)
      山本純, 佐藤賢吾, 宗林由樹
    • Organizer
      第54回日本学術会議材料工学連合講演会
    • Place of Presentation
      ハートピア京都,京都
    • Year and Date
      2010-10-25
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 強配位子場元素ジルコニウム,ハフニウム,ニオブ,タンタルの太平洋・南極海鉛直断面分布2010

    • Author(s)
      宗林由樹, Firdaus, M.L., 則末和宏
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      東北大学,仙台
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 堆積物中モリブデン同位体比に基づく古日本海酸化還元状態の変動2010

    • Author(s)
      森島唯, 西田真輔, 中川裕介, 宗林由樹, 平田岳史, 村山雅史
    • Organizer
      日本地球化学会第57年会
    • Place of Presentation
      立正大学,熊谷
    • Year and Date
      2010-09-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] Distribution and behaviors of bioactive trace metals in the western North Pacific Ocean2010

    • Author(s)
      Vu, T.D.H., Kono, T., Sohrin, Y.
    • Organizer
      日本地球化学会第57年会
    • Place of Presentation
      立正大学,熊谷
    • Year and Date
      2010-09-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] 微量元素から探る海と生命2010

    • Author(s)
      宗林由樹
    • Organizer
      第21回日本微量元素学会
    • Place of Presentation
      京都大学,京都(特別講演)
    • Year and Date
      2010-07-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] GEOTRACES key trace metals at BATS in 2008(intercalibration)and in the western North Pacific in 20062010

    • Author(s)
      Sohrin, Y.
    • Organizer
      2010 Western Pacific Geophysics Meeting
    • Place of Presentation
      Taipei International Convention Center, Taipei(invited)
    • Year and Date
      2010-06-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] Distribution of Zr, Hf, Nb and Ta in the western and central Pacific Ocean2010

    • Author(s)
      Firdaus, M.L., Nakagawa, Y., Matsunari, T., Norisuye, K., Sohrin, Y.
    • Organizer
      2010 Western Pacific Geophysics Meeting
    • Place of Presentation
      Taipei International Convention Center, Taipei
    • Year and Date
      2010-06-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] 南太平洋西経170度における溶存態生物活性微量金属の断面分布2010

    • Author(s)
      南知晴, 肥後衣里, 松成恭博, 宗林由樹
    • Organizer
      第71回分析化学討論会
    • Place of Presentation
      島根大学,松江
    • Year and Date
      2010-05-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 堆積物中モリブデン安定同位体比の分析と古日本海酸化還元状態推定への応用2010

    • Author(s)
      宗林由樹, 森島唯, 西田真輔, 中川裕介, 平田岳史, 村山雅史
    • Organizer
      第71回分析化学討論会
    • Place of Presentation
      島根大学,松江
    • Year and Date
      2010-05-15
    • Related Report
      2010 Annual Research Report
  • [Book] 重金属(環境分析ガイドブック)(共著)2011

    • Author(s)
      宗林由樹
    • Publisher
      丸善
    • Related Report
      2010 Annual Research Report
  • [Book] 元素存在度,平均元素濃度(レアメタル便覧)(共著)2011

    • Author(s)
      宗林由樹
    • Publisher
      丸善
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://inter3.kuicr.kyoto-u.ac.jp/scope_J.html

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2016-04-21  

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