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Circularly Polarized Luminescent Quantum Dots Prepared in Chiral Nanospace of Proteins

Research Project

Project/Area Number 22651043
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Nanomaterials/Nanobioscience
Research InstitutionNara Institute of Science and Technology

Principal Investigator

NAITO Masanobu  奈良先端科学技術大学院大学, 物質創成科学研究科, 特任准教授 (30346316)

Co-Investigator(Renkei-kenkyūsha) YAMASHITA Ichiro  奈良先端科学技術大学院大学, 物質創成科学研究科, 客員教授 (30379565)
IWAHORI Kenji  奈良先端科学技術大学院大学, 物質創成科学研究科, 研究員 (90467689)
Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,490,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2010: ¥1,800,000 (Direct Cost: ¥1,800,000)
Keywords円偏光発光 / 量子ドット / タンパク質 / キラリティー / フェリチン / バイオミネラリゼーション / キラル / 球殻状タンパク質 / 光学 / 光学活性
Research Abstract

In this study, we prepared circularly polarized luminescent CdS quantum dot by using hollow protein, ferritin, as a template for bio-mineralization. In addition, we elucidated mechanism of the chiral transfer from protein to quantum dots. As a result, we successfully prepared circularly polarized luminescent CdS quantum dots by using ferritin as a template at room temperature, in which chirality of the inner core of ferritin was efficiently transferred to the lattice structures of the CdS quantum dots. In addition, we could succeed in modulation of emission wavelength of the circularly polarized luminescence with laser fabrication technique.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (31 results)

All 2012 2011 2010 Other

All Journal Article (8 results) (of which Peer Reviewed: 4 results) Presentation (16 results) Remarks (1 results) Patent(Industrial Property Rights) (6 results) (of which Overseas: 4 results)

  • [Journal Article] Sterically controlled docking of gold nanoparticles on ferritin surface by DNA hybridization2011

    • Author(s)
      B. Zheng, M. Uemura, K. Iwahori, N. Okamoto, M. Naito, Y. Ishikawa, Y. Uraoka, I. Yamashita
    • Journal Title

      Nanotechnology

      Volume: 22 Pages: 275312-275319

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Versatile self-assembled hybrid systems with exotic structures and unique functions2011

    • Author(s)
      T. Nakanishi, M. Naito, Y. Takeoka, K. Matsuura
    • Journal Title

      Current Opinion in Colloid & Interface Science

      Volume: 16 Pages: 482-490

    • Related Report
      2011 Final Research Report
  • [Journal Article] 球殻状タンパク質を鋳型にした円偏光発光性量子ドットの創成2011

    • Author(s)
      内藤昌信
    • Journal Title

      化学工業

      Volume: 62 Pages: 54-58

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Journal Article] タンパク質の中で作る円偏光発光性量子ドット2011

    • Author(s)
      内藤昌信
    • Journal Title

      光アライアンス

      Volume: 22 Pages: 45-49

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Journal Article] 円偏光発光性を示す超分子・高分子材料2011

    • Author(s)
      内藤昌信
    • Journal Title

      光化学

      Volume: 42 Pages: 114-120

    • NAID

      10030166844

    • Related Report
      2011 Final Research Report
  • [Journal Article] Versatile self-assembled hybrid systems with exotic structures andunique functions2011

    • Author(s)
      T.Nakanishi, M.Naito, Y.Takeoka, K.Matsuura
    • Journal Title

      Current Opinion in Colloid & Interface Science

      Volume: 16 Pages: 482-490

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Circularly polarized luminescent CdS quantum dots prepared in protein nanocage2010

    • Author(s)
      M. Naito, K. Iwahori, A. Miura, Y. Yamane, I. Yamashita
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 49 Pages: 7006-7009

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Circularly Polarized Luminescent CdS Quantum Dots Prepared in Protein Nanocage2010

    • Author(s)
      M.Naito, K.Iwahori, A.Miura, M.Yamane, I.Yamashita
    • Journal Title

      Angew Chem Int.Ed.

      Volume: Vol.49 Pages: 7006-7009

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 竹取の翁が見た光は生体高分子の中で作る次世代ディスプ図4レーザ光酸化による円偏光発光波長の制御図3レーザ光酸化による円偏光発光波長の制御アポフェリチン(青)およびCdS量子ドット内包フェリチン(赤)の円偏光発光スペクトルレイ光源.2011

    • Author(s)
      内藤昌信
    • Organizer
      東京大学化学生命工学専攻第4回ChemBioハイブリッドレクチャー
    • Place of Presentation
      東京
    • Year and Date
      2011-11-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 竹取の翁が見た光は…?~生体高分子の中で作る次世代ディスプレイ光源~2011

    • Author(s)
      内藤昌信
    • Organizer
      化学生命工学専攻第4回ChemBioハイブリッドレクチャー
    • Place of Presentation
      東京大学
    • Year and Date
      2011-11-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 円偏光発光性キラル超分子の創製と機能創発2011

    • Author(s)
      内藤昌信
    • Organizer
      第179化学コースコロキウム(首都大学東京)
    • Place of Presentation
      東京
    • Year and Date
      2011-06-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 円偏光発光性キラル超分子の創成と機能創発2011

    • Author(s)
      内藤昌信
    • Organizer
      第179回・化学コースコロキウム
    • Place of Presentation
      首都大学東京
    • Year and Date
      2011-06-15
    • Related Report
      2011 Annual Research Report
  • [Presentation]2011

    • Author(s)
      内藤昌信、芝口廣司、滝山幸次郎、妻鳥紘之
    • Organizer
      日本化学会第91春季年会
    • Year and Date
      2011-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] 円偏光発光性キラル超分子の創成と機能2011

    • Author(s)
      内藤昌信, 芝口廣司, 瀧山幸次郎, 妻鳥紘之, 河合壮, 岩堀健治, 山下一郎
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学で開催予定が中止となり、予稿集により発表
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 生体材料を用いた光・電子ナノマテリアルの創出2011

    • Author(s)
      内藤昌信
    • Organizer
      第25回NAIST産学連携フォーラム
    • Place of Presentation
      大阪
    • Year and Date
      2011-03-17
    • Related Report
      2011 Final Research Report
  • [Presentation] 生体材料を用いた光・電子ナノマテリアルの創出2011

    • Author(s)
      内藤昌信
    • Organizer
      第25回NAIST産学連携フォーラム
    • Place of Presentation
      関西経済連合会(大阪市北区)
    • Year and Date
      2011-03-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 円偏光発光性キラル超分子の創製と機能創発2011

    • Author(s)
      内藤昌信
    • Organizer
      第25回超分子創製化学セミナー
    • Place of Presentation
      滋賀
    • Year and Date
      2011-01-11
    • Related Report
      2011 Final Research Report
  • [Presentation] 円偏光発生性キラル分子の創製と機能創発2011

    • Author(s)
      内藤昌信
    • Organizer
      第25回超分子創製化学セミナー
    • Place of Presentation
      立命館大学
    • Year and Date
      2011-01-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] Circularly polarized luminescent CdS quantum dots prepared in protein nanocage2010

    • Author(s)
      M. Naito, K. Iwahori, A. Miura, I. Yamashita
    • Organizer
      Pacifichem
    • Place of Presentation
      アメリカ
    • Year and Date
      2010-12-16
    • Related Report
      2011 Final Research Report
  • [Presentation] Circularly polarized luminescent CdS quantum dots prepared in protein nanocage2010

    • Author(s)
      M.Naito ; K.Iwahori ; A.Miura ; M.Yamane ; I.
    • Organizer
      2010環太平洋国際化学会議
    • Place of Presentation
      ハワイコンベンションセンター(アメリカホノルル)
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Circularly polarized luminescent supramolecular chemistry2010

    • Author(s)
      M. Naito
    • Organizer
      NAIST Colloquium for Future-Pioneering2010
    • Place of Presentation
      奈良
    • Year and Date
      2010-12-10
    • Related Report
      2011 Final Research Report
  • [Presentation] Circularly polarized luminescent supramolecular chemistry2010

    • Author(s)
      内藤昌信
    • Organizer
      NAIST Colloquium for Future-Pioneering 2010
    • Place of Presentation
      NAIST
    • Year and Date
      2010-12-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Circularly polarized luminescent CdS quantum dots prepared in protein nanocage2010

    • Author(s)
      M. Naito, K. Iwahori, A. Atsushi, M. Yamane, I. Yamashita
    • Organizer
      Asia NANO2010
    • Place of Presentation
      東京
    • Year and Date
      2010-11-02
    • Related Report
      2011 Final Research Report
  • [Presentation] Circularly Polarized Luminescent CdS Quantum Dots Prepared in Protein Nanocage2010

    • Author(s)
      Masanobu Naito, Kenji Iwahori, Atsushi Miura, Midori Yamane, Ichiro Yamashita
    • Organizer
      AsiaNANO2010
    • Place of Presentation
      日本科学未来館(東京都江東区)
    • Year and Date
      2010-11-02
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://samurai.nims.go.jp/NAITO_Masanobu-j.html

    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 棒状分子を表面に備える基板およびその製造方法2012

    • Inventor(s)
      内藤昌信、中村祐亮、緒方寿幸、高山寿一、細野隆之
    • Industrial Property Rights Holder
      奈良先端科学技術大学院大学、東京応化工業株式会社
    • Industrial Property Number
      2012-052177
    • Filing Date
      2012-03-08
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 棒状分子を表面に備える基盤及びその製造方法2012

    • Inventor(s)
      内藤昌信, 中村裕亮, 緒方寿幸, 高山寿一, 細野隆之
    • Industrial Property Rights Holder
      国立大学法人奈良先端科学技術大学院大学・東京応化工業株式会社
    • Industrial Property Number
      2012-052177
    • Filing Date
      2012-03-08
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] 円偏光性ナノ微粒子2010

    • Inventor(s)
      内藤昌信、岩堀健治
    • Industrial Property Rights Holder
      奈良先端科学技術大学院大学、科学技術振興機構
    • Filing Date
      2010-10-27
    • Related Report
      2011 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 円偏光性ナノ微粒子2010

    • Inventor(s)
      内藤昌信、岩堀健治
    • Industrial Property Rights Holder
      奈良先端科学技術大学院大学、科学技術振興機構
    • Filing Date
      2010-09-28
    • Related Report
      2011 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 円偏光発光性ナノ微粒子2010

    • Inventor(s)
      内藤昌信 岩堀健治
    • Industrial Property Rights Holder
      奈良先端科学技術大学院大学
    • Filing Date
      2010-09-28
    • Related Report
      2010 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 円偏光発光性ナノ微粒子2010

    • Inventor(s)
      内藤昌信 岩堀健治
    • Industrial Property Rights Holder
      奈良先端科学技術大学院大学
    • Filing Date
      2010-10-27
    • Related Report
      2010 Annual Research Report
    • Overseas

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Published: 2010-08-23   Modified: 2016-04-21  

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