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High temperature and pressure experiments to synthesize rarely-formed organic molecules

Research Project

Project/Area Number 22654063
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionTohoku University

Principal Investigator

KAKEGAWA Takeshi  東北大学, 大学院・理学研究科, 教授 (60250669)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,090,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2010: ¥1,400,000 (Direct Cost: ¥1,400,000)
Keywords生体・環境鉱物 / リボース / 生命起源 / 有機分子 / ホウ酸 / アミノ酸 / 核酸 / 初期地球 / ホルモース反応
Research Abstract

Formose reactions are responsible for ribose formation. The unique technique was invented in the present study to identify intermediate products and final products through the formose reactions. Using this new technique, it is found that ribose-borate complex is more stabilized compared to other pentose-borate complex. This yields selectively survived ribose in the alkaline and slightly heated solutions. In addition, this study answers a question as to why RNA chosen ribose.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (60 results)

All 2012 2011 2010 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (43 results) Book (3 results) Remarks (2 results)

  • [Journal Article] Stability of amino acids and their oligomerization under high-pressure conditions : implications for prebiotic chemistry2011

    • Author(s)
      Otake T., Taniguchi T., Furukawa Y., Kawamura F., Nakazawa H. and Kakegawa T.
    • Journal Title

      Astrobiology

      Volume: vol.11 Issue: 8 Pages: 799-813

    • DOI

      10.1089/ast.2011.0637

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Gunflint Formation. In"Encyclopedia of Astrobiology" Springer-Verlag2011

    • Author(s)
      Kakegawa T. Ishida A.
    • Journal Title

      Berlin

      Pages: 697-700

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Impact-induced phyllosilicate formation from olivine and water2011

    • Author(s)
      Furukawa Y. Sekine T. Kakegawa T. Nakazawa H.
    • Journal Title

      Geochimica Cosmochimica Acta

      Volume: vol.75 Pages: 6461-6472

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Gunflint Formation2011

    • Author(s)
      Kakegawa T., Ishida A.
    • Journal Title

      Encyclopedia of Astrobiology

      Volume: v0.2 Pages: 697-700

    • DOI

      10.1007/978-3-642-11274-4_681

    • ISBN
      9783642112713, 9783642112744
    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Impact-induced phyllosilicate formation from olivine and water2011

    • Author(s)
      Furukawa Y., Sekine T., Kakegawa T., Nakazawa H.
    • Journal Title

      Geochimica Cosmochimica Acta

      Volume: 75 Issue: 21 Pages: 6461-6472

    • DOI

      10.1016/j.gca.2011.08.029

    • NAID

      120005300484

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] d13C-dD distribution of lipid biomarkers in a bacterial mat from a hot spring in Miyagi Prefecture2010

    • Author(s)
      Naraoka H., Uehara T., Hanada S. T. Kakegawa
    • Journal Title

      NE Japan. Organic Geochemistry

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Last glacial-Holocine geochronology of sedimentcores from a high-altitude Tibetan lake based on AMC C-14 dating of plant fossils : Implications for paleoenvironmental reconstructions2010

    • Author(s)
      Watanabe T., Matsunaka T., Nakamura T., Nishimura M., IzuyaY., Minami M., Nara Watanabe F., Kakegawa T., Wang J.B., Zhu L.P.
    • Journal Title

      Chemical Geology

      Volume: Vol.277 Pages: 21-29

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] δ^<13>C-δD distribution of lipid biomarkers in a bacterial mat from a hot spring in Miyagi Prefecture, NE Japan.2010

    • Author(s)
      Naraoka H., Uehara T., HanadaS., Kakeeawa T.
    • Journal Title

      Organic Geochemistry

      Volume: Vol.41 Pages: 398-403

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Biogeography and biodiversity in sulfide structures of active and inactive vents at deep-sea hydrothermal fields of the southern Mariana TrOUgh2010

    • Author(s)
      Kato S., Takano Y., KakegawaT., et al.
    • Journal Title

      Applied and environmental microbiology

      Volume: Vol.76 Pages: 2968-2979

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A smooth negative shift of organic carbon isotope ratios at an end-Permian mass extinction horizon in central pelagic Panthalassa.Paleogeogaphy, Paleoclimatpology and Paleoecology2010

    • Author(s)
      Takahashi S, Kaiho K., Oba M., Kakegawa T.
    • Journal Title

      Paleogeography, Paleoclimatpology and Palececology

      Volume: Vol.292 Pages: 532-539

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Climate control of sulfate influx to Lake Hovsgol, northwest Mongolia, during the last glacial-postglacial transition : Constraints from sulfur geochemistry2010

    • Author(s)
      Nara F.W., Watanabe T., Kakeeawa T., other 6
    • Journal Title

      Paleogeography, Paleoclimatpology and Paleoecology

      Volume: Vol.298 Pages: 278-285

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 東北地方北部の金属鉱床に随伴する高インジウム鉱石の形成条件2010

    • Author(s)
      山田亮一、吉田武義、掛川武、奈良郁子、小川泰正
    • Journal Title

      資源地質

      Volume: Vol.60 Pages: 153-164

    • NAID

      10031141186

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 水曜海山海底熱水活動域における有機物窒素同位体と特異的形状を有した硫化鉱物2012

    • Author(s)
      掛川武, 中畑良紹, 長谷川樹, 橋爪光, 花田智, 森浩二
    • Organizer
      YK11-06速報. ブルーアース2012
    • Place of Presentation
      東京
    • Year and Date
      2012-02-23
    • Related Report
      2011 Final Research Report
  • [Presentation] 高温高圧条件下における固体アミノ酸の安定性と重合反応2011

    • Author(s)
      大竹翼, 谷口尚, 古川善博, 中沢弘基, 掛川武
    • Organizer
      地球化学会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 段階燃焼法によって明らかにされた初期原生代有機物窒素同位体比の2相性2011

    • Author(s)
      石田章純、橋爪光、掛川武
    • Organizer
      2011年度日本地球化学会年会
    • Place of Presentation
      北海道大学、北海道
    • Year and Date
      2011-09-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 南アフリカ・バーバートン地域の32億年前砕屑性及び化学性堆積岩中にみられる磁鉄鉱とクロム鉄鉱の起源2011

    • Author(s)
      坂本祐樹, 掛川武, 大竹翼
    • Organizer
      地球化学会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 初期地球環境下リボース生成反応におけるホウ酸の影響2011

    • Author(s)
      堀内真愛, 古川善博, 掛川武
    • Organizer
      地球化学会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 初期地球環境下リボース生成反応におけるホウ酸の影響2011

    • Author(s)
      堀内真愛・古川善博・掛川武
    • Organizer
      地球化学会
    • Place of Presentation
      札幌、北海道
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高温高圧条件下における固体アミノ酸の安定性と重合反応2011

    • Author(s)
      大竹翼、谷口尚、古川善博、中沢弘基、掛川武
    • Organizer
      地球化学会
    • Place of Presentation
      札幌、北海道
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] バリン重合反応に対する圧力の影響2011

    • Author(s)
      古川善博, 大竹翼, 中沢弘基, 掛川武
    • Organizer
      地球化学会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-14
    • Related Report
      2011 Final Research Report
  • [Presentation] カナダ・Lumby Lake地域における30億年前堆積岩の地質学的地球化学的研究2011

    • Author(s)
      横田和也、掛川武
    • Organizer
      地球化学会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-14
    • Related Report
      2011 Final Research Report
  • [Presentation] バリン重合反応に対する圧力の影響2011

    • Author(s)
      古川善博、大竹翼、中沢弘基、掛川武
    • Organizer
      地球化学会
    • Place of Presentation
      札幌、北海道
    • Year and Date
      2011-09-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] New evidence of early life found in > 3. 74Ga meta-sedimentary rocks of Isua Supracrustal Belt, Greenland2011

    • Author(s)
      T. Kakegawa
    • Organizer
      ISSOL and Bioastronomy, Joint International Conference
    • Place of Presentation
      Montpellier, France
    • Year and Date
      2011-07-04
    • Related Report
      2011 Final Research Report
  • [Presentation] Stability of amino acids and their oligomerization under high pressure conditions2011

    • Author(s)
      Otake T., Taniguchi T., Furukawa Y., Nakazawa H. and T. Kakegawa
    • Organizer
      ISSOL and Bioastronomy, Joint International Conference
    • Place of Presentation
      Montpellier, France
    • Year and Date
      2011-07-04
    • Related Report
      2011 Final Research Report
  • [Presentation] Oligomerization of valine under high temperature and high pressure conditions2011

    • Author(s)
      Y. Furukawa, Otake T., Ishiguro T., Nakazawa H., Kakegawa T.
    • Organizer
      ISSOL and Bioastronomy, Joint International Conference
    • Place of Presentation
      Montpellier, France
    • Year and Date
      2011-07-04
    • Related Report
      2011 Final Research Report
  • [Presentation] Stability of amino acids and their oligomerization under high pressure conditions2011

    • Author(s)
      Otake T., Taniguehi T., Furukawa Y., Nakazawa H., Kakegawa T.
    • Organizer
      ISSOL and Bioastronomy, Joint International Conference
    • Place of Presentation
      モンペリエ、フランス
    • Year and Date
      2011-07-04
    • Related Report
      2011 Annual Research Report
  • [Presentation] Oligomerization of valine under high temperature and high pressure conditions2011

    • Author(s)
      Furukawa Y., Otake T., Ishiguro T., Nakazawa H., Kakegawa T.
    • Organizer
      ISSOL and Bioastronomy, Joint International Conference
    • Place of Presentation
      モンペリエ、フランス
    • Year and Date
      2011-07-04
    • Related Report
      2011 Annual Research Report
  • [Presentation] Experimental and geological link for prebiotic peptide and ribose formation2011

    • Author(s)
      T. Kakegawa
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2011-05-23
    • Related Report
      2011 Final Research Report
  • [Presentation] 海洋衝突生成有機分子の衝突進化過程2011

    • Author(s)
      福永奈央, 関根利守, 泉俊輔, 古川善博, 掛川武, 小林敬道, 中沢弘基
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2011-05-23
    • Related Report
      2011 Final Research Report
  • [Presentation] 高温高圧環境におけるバリンペプチド生成2011

    • Author(s)
      古川善博, 石黒崇人, 大竹翼, 中沢弘基, 掛川武
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2011-05-23
    • Related Report
      2011 Final Research Report
  • [Presentation] カナダ・Lumby Lake地域に産する30億年前堆積岩の地質学的・地質学的研究2011

    • Author(s)
      横田和也, 掛川武
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2011-05-23
    • Related Report
      2011 Final Research Report
  • [Presentation] 32億年前に存在した酸化的な海洋表層環境の痕跡2011

    • Author(s)
      坂本祐樹, 大竹翼, 掛川武
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2011-05-23
    • Related Report
      2011 Final Research Report
  • [Presentation] 初期地球環境化ホルモース反応実験と中間生成物および糖の液体クロマトグラフ質量分析計による分析法の開発2011

    • Author(s)
      堀内真愛, 古川善博, 大竹翼, 掛川武
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2011-05-23
    • Related Report
      2011 Final Research Report
  • [Presentation] Experimental and geological link for prebiotic peptide and ribose formation2011

    • Author(s)
      Takeshi Kakegawa
    • Organizer
      日本地球惑星連合2011年大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2011-05-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] 初期地球環境化ホルモース反応実験と中間生成物および糖の液体クロマトグラフ質量分析計による分析法の開発2011

    • Author(s)
      堀内真愛、古川善博、大竹翼、掛川武
    • Organizer
      日本地球惑星連合2011年大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2011-05-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高温高圧環境におけるバリンペプチド生成2011

    • Author(s)
      古川善博、石黒崇人、大竹翼、中沢弘基、掛川武
    • Organizer
      日本地球惑星連合2011年大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2011-05-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] 初期地球における海洋堆積物中でのアミノ酸の安定性と重合反応2010

    • Author(s)
      大竹翼, 谷口尚, 古川善博, 中沢弘基, 掛川武
    • Organizer
      高圧討論会
    • Place of Presentation
      仙台
    • Year and Date
      2010-10-21
    • Related Report
      2011 Final Research Report
  • [Presentation] 初期地球における海洋堆積物中でのアミノ酸の安定性と重合反応2010

    • Author(s)
      大竹翼, 谷口尚, 古川善博, 中沢弘基, 掛川武
    • Organizer
      高圧討論会
    • Place of Presentation
      仙台、宮城
    • Year and Date
      2010-10-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] 阻石の後期中爆撃による有機物の生成2010

    • Author(s)
      古川義博、大庭雅寛、関根利守、掛川武、中沢弘基
    • Organizer
      高圧討論会
    • Place of Presentation
      仙台、宮城
    • Year and Date
      2010-10-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] 生命起源に関する化学進化の問題点2010

    • Author(s)
      掛川武
    • Organizer
      第3回日本アストロバイオロジーネットワーク会議
    • Place of Presentation
      八王子
    • Year and Date
      2010-09-30
    • Related Report
      2011 Final Research Report
  • [Presentation] 生命起源に関する化学進化の問題点2010

    • Author(s)
      掛川武
    • Organizer
      第3回日本アストロバイオロジーネットワーク会議
    • Place of Presentation
      八王子、東京(招待講演)
    • Year and Date
      2010-09-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] 海洋堆積物の続成環境模擬実験における混合アミノ酸の重合と安定性2010

    • Author(s)
      高橋拓人, 大竹翼, 古川善博, 掛川武
    • Organizer
      地球化学会
    • Place of Presentation
      熊谷、埼玉
    • Year and Date
      2010-09-08
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Stability of amino acids and peptides during diagenesis on the early Earth2010

    • Author(s)
      Otake, T., Taniguchi, T., Furukawa, Y., Nakazawa, H., and Kakegawa, T.
    • Organizer
      Goldschmidt Conference
    • Place of Presentation
      Tennesee, USA
    • Year and Date
      2010-06-18
    • Related Report
      2011 Final Research Report
  • [Presentation] Stability of amino acids and peptides during diagenesis on the early Earth2010

    • Author(s)
      Otake, T., Taniguchi, T., Furukawa, Y., Nakazawa, H., Kakegawa.T.
    • Organizer
      Goldschmidt Conference
    • Place of Presentation
      Tennessee, USA
    • Year and Date
      2010-06-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Enhanced biological nitrogen and sulfur cycles in the stratified 1.9Ga Gunflint ocean2010

    • Author(s)
      Ishida A., Hashizume K., Oba M., Kakegawa T.
    • Organizer
      Goldschmidt Conference
    • Place of Presentation
      Tennessee, USA
    • Year and Date
      2010-06-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 生命の起源・進化とディープカーボンサイクルとの関係2010

    • Author(s)
      畳川武
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉(招待講演)
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] カナダ・Lumby Lake地域(30億年前)堆積岩の地質学的地球化学的研究2010

    • Author(s)
      横田和也、掛川武
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 南アフリカ・バーバートン地域に産する32億年前のFig Tree層とMoodies層中縞状鉄鉱層の地質学的地球化学的研究2010

    • Author(s)
      坂本裕紀、大竹翼、掛川武
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] ホウ素はバイオマーカーとなりうるか?:イスアからの報告2010

    • Author(s)
      掛川武
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2010-05-25
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] カナダ・ガンフリント層に記録された19億年前の層状海洋の中での極端な窒素と硫黄循環2010

    • Author(s)
      石田章純、橋爪光、捌川武
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2010-05-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] 隕石の後期中爆撃による有機物の生成2010

    • Author(s)
      古川善博、大庭雅寛、関根利守、掛川武、中沢弘基
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2010-05-24
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 初期地球における続成作用中のアミノ酸およびペプチドの安定性2010

    • Author(s)
      大竹翼、古川善博、掛川武
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2010-05-24
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 生命の起源・進化とディープカーボンサイクルとの関係2010

    • Author(s)
      掛川武
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張、千葉
    • Year and Date
      2010-05-24
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of organic molecules by oceanic impacts on the early Earth2010

    • Author(s)
      Furukawa Y., Sekine T., Oba M., Kakegawa T., Nakazawa H.
    • Organizer
      AbSciCon Conference
    • Place of Presentation
      Huston, USA
    • Year and Date
      2010-04-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Pressure effects on peptide formation : implication to chemical evolution for origin of life2010

    • Author(s)
      Kakeeawa T.
    • Organizer
      AbSciCon Conference
    • Place of Presentation
      Huston, USA
    • Year and Date
      2010-04-26
    • Related Report
      2010 Annual Research Report
  • [Book] 地球と生命. 地球環境と生物圏進化2011

    • Author(s)
      掛川武・海保邦夫
    • Publisher
      共立出版
    • Related Report
      2011 Final Research Report
  • [Book] 地球と生命-地球環境と生物圏進化-2011

    • Author(s)
      掛川武・海保邦夫
    • Publisher
      共立出版
    • Related Report
      2011 Annual Research Report
  • [Book] 古生物学辞典2010

    • Author(s)
      掛川武
    • Publisher
      朝倉書店
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.es.tohoku.ac.jp/JP/

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://web.me.com/take213/KakegawaLab/intro.html

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2023-03-16  

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