Development of Oxidative Catalytic System for Eco-Innovation
| Project/Area Number |
22655028
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
HIRAO Toshikazu 大阪大学, 大学院・工学研究科, 教授 (90116088)
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| Co-Investigator(Kenkyū-buntansha) |
MORIUCHI Toshiyuki 大阪大学, 大学院・工学研究科, 准教授 (60281119)
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| Project Period (FY) |
2010 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥3,370,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥2,200,000 (Direct Cost: ¥2,200,000)
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| Keywords | 酸化的臭素化 / 酸化触媒 / バナジウム / 分子状酸素 / レドックス |
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| Research Abstract |
The vanadium-catalyzed oxidative bromination reaction of arenes, alkenes, and alkynes was achieved under atmospheric oxygen in the presence of NH_4VO_3 catalyst combined with bromide ion and Lewis acid. This catalytic system could be applied to the oxidative halogenation reaction by using halide ion instead of bromide ion.
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Report
(3 results)
Research Products
(44 results)
