| Project/Area Number |
22655028
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Synthetic chemistry
|
|---|
| Research Institution | Osaka University |
|---|
Principal Investigator |
HIRAO Toshikazu 大阪大学, 大学院・工学研究科, 教授 (90116088)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
MORIUCHI Toshiyuki 大阪大学, 大学院・工学研究科, 准教授 (60281119)
|
|---|
| Project Period (FY) |
2010 – 2011
|
| Project Status |
Completed (Fiscal Year 2011)
|
| Budget Amount *help |
¥3,370,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥2,200,000 (Direct Cost: ¥2,200,000)
|
|---|
| Keywords | 酸化的臭素化 / 酸化触媒 / バナジウム / 分子状酸素 / レドックス |
|---|
| Research Abstract |
The vanadium-catalyzed oxidative bromination reaction of arenes, alkenes, and alkynes was achieved under atmospheric oxygen in the presence of NH_4VO_3 catalyst combined with bromide ion and Lewis acid. This catalytic system could be applied to the oxidative halogenation reaction by using halide ion instead of bromide ion.
|
