| Project/Area Number |
22655031
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Polymer chemistry
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| Research Institution | Shizuoka University |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥3,520,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥1,700,000 (Direct Cost: ¥1,700,000)
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| Keywords | ポリイン / カルビン / クロスカップリング重合 / アセチレン等価体 / N-ヘテロカルベン / Ｎ-ヘテロ環状カルベン / ＮＨＣ / クロスカップリング反応 / シクロプロペノン / 炭素同素体 / マスクしたアセチレン / シクロプロペノンケタール / 炭素材料 |
|---|
| Research Abstract |
Polyyne is an allotrope of carbon consists of alternating single and triple C-C bonds. Although the polymer is interesting because of its potential applicability for functional materials, chemical synthetic method of the polymer has not been established. In this study, halogenated metal acetylide and its equivalents, cyclopropenone ketals, cyclopropenone dithioketals, and adducts of halogenated metal acetylide with N-heterocyclic carbine, are synthesized as promising monomers of polyyne.
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