Synthesis of three-dimensional networks of metal nanoparticles using bridging ligands and their functions
| Project/Area Number |
22655041
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional materials chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥3,450,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥450,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2010: ¥1,500,000 (Direct Cost: ¥1,500,000)
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| Keywords | ナノ粒子 / 水素吸蔵 / パラジウム / 集積化 / MOF / 錯形成 / バナジウム / 透過型電子顕微鏡 |
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| Research Abstract |
New multidirectional bridging ligands with 2-4 terpyridine groups were synthesized and their utilization for the formation of nanopores by construction of three-dimensional networks with combining isocyanide-protected palladium nanoparticles. The final goal of this study is to increase the capacity of hydrogen storage by the contribution of both interparticle nanopores and intraparticle lattice vacancies. The validity of this concept has been supported by the structural analysis of newly synthesized three-dimensional networks of Pd nanoparticles and by the measurement of their N_2 and H_2 absorption abilities.
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Report
(3 results)
Research Products
(15 results)
