Synthesis and application of carbonic N-confused porphyrinoid
Project/Area Number |
22655044
|
Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
Allocation Type | Single-year Grants |
Research Field |
Functional materials chemistry
|
Research Institution | Kyushu University |
Principal Investigator |
|
Project Period (FY) |
2010 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥3,420,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2010: ¥1,600,000 (Direct Cost: ¥1,600,000)
|
Keywords | レニウム / N-混乱ポルフィリンカルベン錯体 / 酸素移動反応 / 触媒 / N-混乱ポルフィリン / カルベン錯体 / カルベン / ポルフィリン |
Research Abstract |
Four isomers of N-methylated N-confused porphyrin were synthesized as precursors of N-heterocyclic carbene ligand, each of which exhibited different electronic properties reflecting the corresponding tautomeric forms and gave carbine complexes by a treatment with Re regents. Some carbene complexes show the pi-extension reaction with aromatic solvents.
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Report
(3 results)
Research Products
(53 results)