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Hybridization of organosilicon polymersand carbon nanotube and integration of the aligned hybrid

Research Project

Project/Area Number 22655065
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Organic industrial materials
Research InstitutionHiroshima University

Principal Investigator

OHSHITA Joji  広島大学, 大学院・工学研究院, 教授 (90201376)

Co-Investigator(Renkei-kenkyūsha) KUNUGI Yoshihito  東海大学, 工学部, 教授 (90243518)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,610,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥510,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,400,000 (Direct Cost: ¥1,400,000)
Keywordsハイブリッド材料 / ナノチューブ / 有機ケイ素ポリマー / 有機電子デバイス / 有機薄膜 / π電子系 / 有機ケイ素化学 / カーボンナノチューブ / 色素憎悪感太陽電池
Research Abstract

Organosilicon polymers that bear an alternating arrangement of an organosilicon unit and a π-electron system, such as pyrene and oligothiophene, were hybridized with carbon nanotube was performed to form hybrid materials that were characterized spectroscopic analyses, including NIR spectroscopy. The hybrids with Si-Si bonds were successfully attached to the surface of titanium oxide and the applications of the hybrid-attached titanium oxide were demonstrated.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (26 results)

All 2013 2012 2011 2010 Other

All Journal Article (5 results) (of which Peer Reviewed: 4 results) Presentation (18 results) (of which Invited: 1 results) Remarks (3 results)

  • [Journal Article] Synthesis of disilanylene polymers with donor-acceptor-type π-conjugated units and applications to dye-sensitized solar cells2012

    • Author(s)
      D. Tanaka, J. Ohshita, Y. Ooyama, T. Mizumo, Y. Harima
    • Journal Title

      J. Organomet. Chem

      Volume: 719巻 Pages: 30-35

    • DOI

      10.1016/j.jorganchem.2012.08.019

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation, Hybrid Formation with Single-walled Carbon Nanotube, and Film Morphology of Pyrene-containing Polysiloxanes2012

    • Author(s)
      Z. Lu
    • Journal Title

      Composite Interfaces

      Volume: 19 Issue: 9 Pages: 573-581

    • DOI

      10.1080/15685543.2012.762866

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] ケイ素-オリゴチオフェンからなる機能性高分子材料の開発と無機酸化物とのハイブリッド化2011

    • Author(s)
      大下浄治
    • Journal Title

      ネットワークポリマー

      Volume: 32巻 Pages: 276-282

    • NAID

      130004991224

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Journal Article] Hybridization of Carbon Nanotubes with Si- π Polymers and Attachment of Resulting Hybrids to TiO_2 Surface2011

    • Author(s)
      J. Ohshita, D. Tanaka, J. Matsukawa, T. Mizumo, H. Yoshida, Y. Ooyama, Y. Harima
    • Journal Title

      Chem. Lett

      Volume: 40巻 Issue: 1 Pages: 87-89

    • DOI

      10.1246/cl.2011.87

    • NAID

      130004426035

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hybridization of Carbon Nanotubes with Si-π Polymers and Attachment of Resulting Hybrids to TiO_2 Surface2011

    • Author(s)
      J.Ohshita
    • Journal Title

      Chem.Lett.

      Volume: 40 Pages: 87-89

    • NAID

      10027655404

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Solubilization of Single Walled Carbon Nanotube with Organosilicon Polymers and Application to Dye Sensitized Solar Cells2013

    • Author(s)
      Daiki Tanaka
    • Organizer
      International Workshop on Nanodevice Technologies 2013
    • Place of Presentation
      Hiroshima
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis of New Donor-Acceptor Organosilicon Polymers and Application to Dye Sensitized Solar Cells2012

    • Author(s)
      Daiki Tanaka, Joji Ohshita, Yousuke Ooyama, Yutaka Harima
    • Organizer
      4th Asian Silicon Symposium
    • Place of Presentation
      Tsukuba
    • Related Report
      2012 Final Research Report
  • [Presentation] Formation of Hybrid Materials of Si-pi Alternate Polymers with Carbon Nanotube and Their Applications to Dye-Sensitized Solar Cells2012

    • Author(s)
      J.Ohshita
    • Organizer
      17th Malaysian Chemical Congress
    • Place of Presentation
      Kuala Lumpur, Malaysia
    • Related Report
      2012 Final Research Report
  • [Presentation] Solubilization of Single Walled Carbon Nanotube with Organosilicon Polymers and Application to Dye Sensitized Solar Cells2012

    • Author(s)
      Daiki Tanaka, Junya Matsukawa, Tomonobu Mizumo, Yousuke Ooyama, Joji Ohshita, Yutaka Harima
    • Organizer
      International Union of Materials Research Societies - International Conference of Electronic Materials 2012
    • Place of Presentation
      Yokohama
    • Related Report
      2012 Final Research Report
  • [Presentation] Sythesis of New Donor-Acceptor Organosilicon Polymers and Application to Dye Sensitized Solar Cells2012

    • Author(s)
      Daiki Tanaka
    • Organizer
      4th Asian Silicon Symposium
    • Place of Presentation
      Tsukuba
    • Related Report
      2012 Annual Research Report
  • [Presentation] Solubilization of Single Walled Carbon Nanotube with Organosilicon Polymers and Application to Dye Sensitized Solar Cells2012

    • Author(s)
      Daiki Tanaka
    • Organizer
      International Union of Materials Research Slcieties - International Conference of Electonic Materials 2012
    • Place of Presentation
      Yokohama
    • Related Report
      2012 Annual Research Report
  • [Presentation] Formation of Hybrid Materials of Si-π Alternate Polymers with Carbon Nanotube and Their Applications to Dye-Sensitized Solar Cells2012

    • Author(s)
      J. Ohshita
    • Organizer
      17th Malaysian Chemical Congress
    • Place of Presentation
      Kuala Lumpur, マレーシア
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ドナーアクセプター構造を有する新規有機ケイ素ポリマーの合成と有機太陽電池への応用2011

    • Author(s)
      田中大樹,大下浄治,大山陽介,播磨 裕,森原 靖,伊澤隆文,杉岡 尚
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] Formation of Hybrid Materials by the Reactions of Si-π Alternate Polymers with Inorganic Oxides2010

    • Author(s)
      J. Ohshita
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Waikiki, USA
    • Year and Date
      2010-12-19
    • Related Report
      2012 Final Research Report
  • [Presentation] Solubilization of Single Walled Carbon Nanotube and Attachment on Inorganic Oxide Surface2010

    • Author(s)
      D. Tanaka, Junya Matsukawa, Tomonobu Mizumo, Joji Ohshita, Yoshihito Kunugi
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Waikiki, USA
    • Year and Date
      2010-12-19
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Presentation] Formation of Hybrid Materials by the Reactions of Si-π Alternate Polymers with Inorganic Oxides2010

    • Author(s)
      J.Ohshita
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Waikiki, USA(招待講演)
    • Year and Date
      2010-12-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] σ-π交互ポリマーと単層カーボンナノチューブの複合化と無機酸化物表面への固定2010

    • Author(s)
      田中大樹,松川純也,水雲智信,大下浄治
    • Organizer
      第14回ケイ素化学協会シンポジウム
    • Place of Presentation
      湯河原
    • Year and Date
      2010-11-19
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Presentation] Preparation of Organic-Inorganic Hybrids from Si-π Alternate Polymers2010

    • Author(s)
      J. Ohshita
    • Organizer
      3rdAsian Silicon Symposium
    • Place of Presentation
      杭州,中国
    • Year and Date
      2010-10-19
    • Related Report
      2012 Final Research Report
  • [Presentation] Preparation of Organic-Inorganic Hybrids from Si-π Alternate Polymers2010

    • Author(s)
      J.Ohshita
    • Organizer
      3^<rd> Asian Silicon Symposium
    • Place of Presentation
      杭州,中国(招待講演)
    • Year and Date
      2010-10-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] 有機ケイ素ポリマーの光反応によるハイブリッド材料の合成2010

    • Author(s)
      大下浄治
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      札幌(依頼講演)
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Solubilization of Single Walled Carbon Nanotube and Aattachment on Inorganic Oxide Surface2010

    • Author(s)
      Daiki Tanaka, Junya Matsukawa, Tomonobu Mizumo, Joji Ohshita, Yoshihito Kunugi
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2010
    • Place of Presentation
      Kyoto
    • Year and Date
      2010-07-07
    • Related Report
      2012 Final Research Report
  • [Presentation] Solubilization of Single Walled Carbon Nanotube and Attachment on Inorganic Oxide Surface2010

    • Author(s)
      D.Tanaka
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2010
    • Place of Presentation
      京都
    • Year and Date
      2010-07-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] 有機ケイ素ポリマーの光反応によるハイブリッド材料の合成2010

    • Author(s)
      大下浄治
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      札幌
    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://home.hiroshima-u.ac.jp/orgmtrls/Ohshita_Group/Ohshita_Group-Home.html

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://home.hiroshima-u.ac.jp/orgmtrls/Ohshita_Group/Ohshita_Group-Home.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://home.hiroshima-u.ac.jp/orgmtrls/Ohshita_Group/Ohshita_Group-Research.html

    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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