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Nano-ordered regular arrangement of crystalline and liquidcrystalline phases in block copolymers and its applicability to storage medium materials

Research Project

Project/Area Number 22655073
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Polymer/Textile materials
Research InstitutionNagaoka University of Technology

Principal Investigator

SHIOMI Tomoo  長岡技術科学大学, 工学部, 教授 (10134967)

Co-Investigator(Kenkyū-buntansha) TAKESHITA Hiroki  長岡技術科学大学, 工学部, 助教 (80313568)
Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,350,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥2,700,000 (Direct Cost: ¥2,700,000)
Keywordsブロック共重合体 / ミクロ相分離 / 相転移 / 液晶 / 結晶 / UV応答性 / 光パターニング / 小角X線散乱 / 結晶化 / 液晶化 / 時分割小角X線散乱
Research Abstract

Crystalline and liquid crystalline phases were arranged in the several ten nanometer order employing the microphase separation in crystalline-amorphous and liquid crystalline-amorphous block copolymers. The change in the microphase separation structure caused by crystalline and liquid crystalline phase transitions was revealed. Especially, the change in the microphase separationstructure by the phase transition caused by UV-photoisomerization was found. The knowledge obtained here suggests a potential for application to switching or storage medium materials.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (63 results)

All 2012 2011 2010 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (49 results) Book (4 results) Remarks (3 results)

  • [Journal Article] Effects ofLiquid-Liquid Phase Separation onCrystallization of Poly(ethylene glycol) inBlends with Isotactic Poly(methylmethacrylate)2012

    • Author(s)
      F. Arai, H. Takeshita, M. Dobashi, K. Takenaka, M. Miya, T. Shiomi
    • Journal Title

      Polymer

      Volume: 50 Pages: 851-856

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of liquid-liquid phase separation on crystallization of poly(ethylene glycol) in blends with isotactic poly (methyl methacrylate)2012

    • Author(s)
      Fuminori Arai
    • Journal Title

      Polymer

      Volume: 50 Issue: 3 Pages: 851-856

    • DOI

      10.1016/j.polymer.2011.12.039

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Phase Structure and Crystallization Behaviorfrom Disordered Melt for Ethylene-IsopreneBlock Copolymers and Their Blends2010

    • Author(s)
      H. Takeshita, Y.-J. Gao, Y. Takata, K. Takenaka, T. Shiomi, C. Wu
    • Journal Title

      Polymer

      Volume: 51 Pages: 799-806

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization of GraftCopolymers 1. Graft Chains Miscible withMain Chains2010

    • Author(s)
      H. Takeshita, G. Sasagawa, K. Takenaka, M. Miya, T. Shiomi
    • Journal Title

      Polymer Journal

      Volume: 42 Pages: 482-488

    • NAID

      10026365711

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of phase structure and crystallization behavior from disordered melt for ethylene-isoprene block copolymers2010

    • Author(s)
      H.Takeshita
    • Journal Title

      Polymer

      Volume: 51 Pages: 799-806

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization of graft copolymers 1.Graft chains miscible with main chain2010

    • Author(s)
      H.Takeshita
    • Journal Title

      Polymer Journal

      Volume: 42 Pages: 482-488

    • NAID

      10026365711

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of hierarchical structure in liquid crystalline block copolymers

    • Author(s)
      H. Takeshita, S. Adachi, S. Taniguchi, K. Takenaka, M. Miya, T. Shiomi
    • Journal Title

      Transactions on GIGAKU

      Volume: (in print)

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Presentation] 側鎖型液晶性ブロック共重合体の相構造における側鎖スペーサ長の効果2012

    • Author(s)
      竹下宏樹
    • Organizer
      第29回PFシンポジウム
    • Place of Presentation
      つくば国際会議場エポカル(つくば)
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] アゾベンゼン型メソゲン基を有する液晶性ブロック共重合体のミクロ相分離構造2012

    • Author(s)
      竹下宏樹
    • Organizer
      第25回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      鳥栖市民文化会館(鳥栖)
    • Related Report
      2011 Final Research Report
  • [Presentation] アゾベンゼン型メソゲン基を有する液晶性ブロック共重合体のミクロ相分離構造2012

    • Author(s)
      竹下宏樹
    • Organizer
      第25回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      鳥栖市民文化会館(鳥栖市)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Formation of hierarchical phasestructure of liquid crystalline blockcopolymers2011

    • Author(s)
      T. Shiomi
    • Organizer
      Joint Research SeminarUSM-NUT(招待講演)
    • Place of Presentation
      Universiti Sains Malaysia(Penang, Malaysia)
    • Year and Date
      2011-10-17
    • Related Report
      2011 Final Research Report
  • [Presentation] Formation of hierarchical phase structure of liquid crystalline block copolymers2011

    • Author(s)
      Tomoo Shiomi
    • Organizer
      Joint Research Seminar USM-NUT
    • Place of Presentation
      Universiti Sains Malaysia (Penang, Malaysia)(招待講演)
    • Year and Date
      2011-10-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Formation of hierarchicalstructure of liquid crystalline blockcopolymers2011

    • Author(s)
      T. Shiomi
    • Organizer
      9th China-Japan Seminar onAdvanced Engineering Plastics, PolymerAlloys and Composites(招待講演)
    • Place of Presentation
      大連香洲大酒店(大連、中国)
    • Year and Date
      2011-09-11
    • Related Report
      2011 Final Research Report
  • [Presentation] Formation of hierarchical structure of liquid crystalline block copolymers2011

    • Author(s)
      Tomoo Shiomi
    • Organizer
      9th China-Japan Seminar on Advanced Engineering Plastics Polymer Alloys and Composites
    • Place of Presentation
      大連香洲大酒店(大連、中国)(招待講演)
    • Year and Date
      2011-09-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] ナノポリマーアロイ/ブレンドの構造形成メカニズム2011

    • Author(s)
      塩見友雄
    • Organizer
      技術情報協会セミナー(セミナー講演)
    • Place of Presentation
      北とぴあ(東京都)
    • Year and Date
      2011-07-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] 結晶性および液晶性高分子多相系の高次構造形成2011

    • Author(s)
      塩見友雄
    • Organizer
      高分子学会第56回高分子夏期大学(招待講演)
    • Place of Presentation
      ホテルフジタ福井(福井市)
    • Year and Date
      2011-07-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 結晶性および液晶性高分子多相系の高次構造形成2011

    • Author(s)
      塩見友雄
    • Organizer
      高分子学会第56回高分子夏期大学
    • Place of Presentation
      ホテルフジタ福井(福井市)(招待講演)
    • Year and Date
      2011-07-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 液晶性ブロック共重合体におけるミクロ相分離構造の光応答性2011

    • Author(s)
      萩野谷和大
    • Organizer
      第60回高分子学会北陸支部研究発表会
    • Place of Presentation
      金沢工業大学(石川県石川郡)
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] ブレンドにおけるPEGの結晶化に及ぼす液-液相分離の効果2011

    • Author(s)
      新井史紀
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学(岡山)
    • Related Report
      2011 Final Research Report
  • [Presentation] アゾベンゼン誘導体をメソゲン基とする液晶性ブロック共重合体のミクロドメインの光応答性2011

    • Author(s)
      竹下宏樹
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学(岡山)
    • Related Report
      2011 Final Research Report
  • [Presentation] Hierarchical structure and itsformation process in liquid crystalline blockcopolymers2011

    • Author(s)
      T. Shiomi
    • Organizer
      European Polymer Congress2011
    • Place of Presentation
      GranadaCongress Centre(Granada, Spain)
    • Related Report
      2011 Final Research Report
  • [Presentation] 相溶系高分子ブレンドの結晶化挙動と高次構造形成2011

    • Author(s)
      新井史紀
    • Place of Presentation
      大阪国際会議場(大阪)
    • Related Report
      2011 Final Research Report
  • [Presentation] 液晶性ブロック共重合体の階層構造とその形成過程2011

    • Author(s)
      横井達也
    • Place of Presentation
      大阪国際会議場(大阪)
    • Related Report
      2011 Final Research Report
  • [Presentation] アゾベンゼンを有する液晶性ブロック共重合体における高次構造の光応答性2011

    • Author(s)
      藤瀬知也
    • Place of Presentation
      大阪国際会議場(大阪)
    • Related Report
      2011 Final Research Report
  • [Presentation] 相溶系高分子ブレンドの結晶化挙動と高次構造形成2011

    • Author(s)
      新井史紀
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪市)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 液晶性ブロック共重合体の階層構造とその形成過程2011

    • Author(s)
      横井達也
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪市)
    • Related Report
      2011 Annual Research Report
  • [Presentation] アゾベンゼンを有する液晶性ブロック共重合体における高次構造の光応答性2011

    • Author(s)
      藤瀬知也
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪市)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Hierarchical structure and its formation process in liquid crystalline block copoly2011

    • Author(s)
      Tomoo Shiomi
    • Organizer
      European Polymer Congress 2011
    • Place of Presentation
      Granada Congress Centre (Granada, Spain)
    • Related Report
      2011 Annual Research Report
  • [Presentation] ブレンドにおけるPEGの結晶化に及ぼす液-液相分離の効果2011

    • Author(s)
      新井史紀
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学(岡山市)
    • Related Report
      2011 Annual Research Report
  • [Presentation] アゾベンゼン誘導体をメソゲン基とする液晶性ブロック共重合体のミクロドメインの光応答性2011

    • Author(s)
      竹下宏樹
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学(岡山市)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 光応答性液晶を含むブロック共重合体の高次構造形成2010

    • Author(s)
      藤瀬知也
    • Organizer
      第59回高分子学会北陸支部研究発表会
    • Place of Presentation
      富山大学(富山)
    • Year and Date
      2010-11-20
    • Related Report
      2011 Final Research Report
  • [Presentation] 液晶性ブロック共重合体の階層構造とその形成過程2010

    • Author(s)
      横井達也
    • Organizer
      第59回高分子学会北陸支部研究発表会
    • Place of Presentation
      富山大学(富山)
    • Year and Date
      2010-11-20
    • Related Report
      2011 Final Research Report
  • [Presentation] 光応答性液晶を含むブロック共重合体の高次構造形成2010

    • Author(s)
      藤瀬知也
    • Organizer
      第59回高分子学会北陸支部研究発表会
    • Place of Presentation
      富山
    • Year and Date
      2010-11-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] 液晶性ブロック共重合体の階層構造とその形成過程2010

    • Author(s)
      横井達也
    • Organizer
      第59回高分子学会北陸支部研究発表会
    • Place of Presentation
      富山
    • Year and Date
      2010-11-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] 結晶性成分を含む高分子ブレンドの相構造と結晶化挙動2010

    • Author(s)
      何新于
    • Organizer
      第59回高分子学会北陸支部研究発表会
    • Place of Presentation
      富山大学(富山)
    • Year and Date
      2010-11-19
    • Related Report
      2011 Final Research Report
  • [Presentation] 結晶性成分を含む高分子ブレンドの相構造と結晶化挙動2010

    • Author(s)
      何新宇
    • Organizer
      平成22年度北陸地区高分子若手研究会
    • Place of Presentation
      富山
    • Year and Date
      2010-11-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] 結晶性および液晶性ブロック共重合体の高次構造形成2010

    • Author(s)
      塩見友雄
    • Organizer
      東工大有機・高分子物質専攻セミナー
    • Place of Presentation
      東京
    • Year and Date
      2010-11-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] 高分子結晶の高次構造と結晶化のメカニズム2010

    • Author(s)
      塩見友雄
    • Organizer
      技術情報協会セミナー
    • Place of Presentation
      東京
    • Year and Date
      2010-11-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] 液晶性ブロック共重合体におけるミクロ相分離と液晶化の相関による階層構造形成2010

    • Author(s)
      塩見友雄
    • Organizer
      第54回日本学術会議材料工学連合講演会(依頼講演)
    • Place of Presentation
      京大会館(京都)
    • Year and Date
      2010-10-25
    • Related Report
      2011 Final Research Report
  • [Presentation] 液晶性ブロック共重合体におけるミクロ相分離と液晶化の相関による階層構造形成2010

    • Author(s)
      塩見友雄
    • Organizer
      第54回日本学術会議材料工学連合講演会
    • Place of Presentation
      京都
    • Year and Date
      2010-10-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリ(N-イソプロピルアクリルアミド)マイクロゲル分散系の相挙動2010

    • Author(s)
      竹下宏樹
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      札幌
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 結晶性および液晶性ブロック共重合体の相構造形成2010

    • Author(s)
      竹下宏樹
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2010-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] PEG/i-PMMAブレンドにおけるPEGの結晶化挙動2010

    • Author(s)
      新井史紀
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2010-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] 結晶性-液晶性ブロック共重合体の結晶化挙動2010

    • Author(s)
      竹下宏樹
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2010-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] 結晶性および液晶性ブロック共重合体の相構造形成2010

    • Author(s)
      竹下宏樹
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      札幌
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] PEG/i-PMMAブレンドにおけるPEGの結晶化挙動2010

    • Author(s)
      新井史紀
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      札幌
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 結晶性・液晶性ブロック共重合体の結晶化挙動2010

    • Author(s)
      竹下宏樹
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      札幌
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Formation of hierarchy structurein liquid crystalline block copolymers2010

    • Author(s)
      T. Shiomi
    • Organizer
      43rdIUPAC World Polymer Congress MACRO2010
    • Place of Presentation
      Glasgow(UK)
    • Year and Date
      2010-07-13
    • Related Report
      2011 Final Research Report
  • [Presentation] Formation of hierarchy structure in liquid crystalline block copolymers2010

    • Author(s)
      塩見友雄
    • Organizer
      43rd IUPAC World Polymer Congress MACRO 2010
    • Place of Presentation
      Glasgow (UK)
    • Year and Date
      2010-07-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] ミクロ相分離構造内における液晶メソゲン基の配向挙動2010

    • Author(s)
      横井達也
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜パシフィコ(横浜)
    • Year and Date
      2010-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] 液晶性.結晶性ブロック共重合体における高次構造と結晶化挙動2010

    • Author(s)
      咲間勇気
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜パシフィコ(横浜)
    • Year and Date
      2010-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] ミクロ相分離構造内における液晶メソゲン基の配向挙動2010

    • Author(s)
      横井達也
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 液晶性-結晶性ブロック共重合体における高次構造と結晶化挙動2010

    • Author(s)
      咲間勇気
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリNIPAマイクロゲルのコロイド結晶化挙動2010

    • Author(s)
      中野将太
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] エチレン.イソプレンブロック共重合体の高次構造形成2010

    • Author(s)
      塩見友雄
    • Organizer
      第8回日中先進高分子材料研究討論会
    • Place of Presentation
      東工大(東京)
    • Year and Date
      2010-05-17
    • Related Report
      2011 Final Research Report
  • [Presentation] エチレン-イソプレンブロック共重合体の高次構造形成2010

    • Author(s)
      塩見友雄
    • Organizer
      第8回日中先進高分子材料研究討論会
    • Place of Presentation
      東京
    • Year and Date
      2010-05-17
    • Related Report
      2010 Annual Research Report
  • [Book] Chapter 19, Crystallization of cyclic andbranched polymers2012

    • Author(s)
      H. Takeshita, T. Shiomi
    • Publisher
      World ScientificPublishing,"Topological Polymer Chemistry/Progress in cyclic polymers : syntheses, properties and functions"
    • Related Report
      2011 Final Research Report
  • [Book] 第6章第1節,ナノ分散構造形成のメカニズム2010

    • Author(s)
      塩見友雄,竹下宏樹
    • Publisher
      情報協会,ポリマーアロイの混練条件の最適化
    • Related Report
      2011 Final Research Report
  • [Book] ブロック共重合体にお第22章,ブロック共重合体における結晶相を含むミクロ相構造の制御2010

    • Author(s)
      塩見友雄,竹下宏樹
    • Publisher
      シーエムシー出版
    • Related Report
      2011 Final Research Report
  • [Book] ポリマーアロイの相溶化と混練条件の最適化2010

    • Author(s)
      塩見友雄
    • Publisher
      技術情報協会
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://mst.nagaokaut.ac.jp/polymer/

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://mst.nagaokaut.ac.jp/polymer/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://mst.nagaokaut.ac.jp/polymer/

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2016-04-21  

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