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Application of proton conduction of nickel oxide nanostructures to electrochromic devices

Research Project

Project/Area Number 22656142
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Inorganic materials/Physical properties
Research InstitutionThe University of Tokyo

Principal Investigator

KITA Koji  東京大学, 大学院・工学系研究科, 准教授 (00343145)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,700,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥600,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2010: ¥1,100,000 (Direct Cost: ¥1,100,000)
Keywords先端機能デバイス / 表面界面物性 / 欠陥準位 / エレクトロクロミック / 表面・界面物性 / イオン伝導 / 酸化物 / セラミックス / エレクトロクロノミック
Research Abstract

Applications of ionic conduction in defect-induced-oxide thin films for electrical devices were investigated. First, a proton-conducting electrolyte for an all-dry-processed electrochromic cell was demonstrated by using the hydrogenated-Ta2O5 films prepared by hydrogen-introduced sputtering, even though nano-structured NiO thin films did not show any expected ionic conductions. Next, voltage-induced nonvolatile change of magnetic anisotropy was demonstrated for TiO2-δ/ferromagnetic CoFeB stacks, by means of the oxygen vacancy transport in TiO2-δ layer. This result indicates a possible development of a new type of magnetic device driven by ionic conduction in oxides.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (55 results)

All 2013 2012 2011 2010 Other

All Journal Article (14 results) (of which Peer Reviewed: 8 results) Presentation (34 results) (of which Invited: 1 results) Book (3 results) Remarks (4 results)

  • [Journal Article] Conduction band offset at Ge02/Ge interface determined by internal photoemission and charge-corrected x-rav photoelectron spectroscopies2013

    • Author(s)
      W. F. Zhang
    • Journal Title

      Applied Physics Letters

      Volume: 102 Issue: 10 Pages: 102106-1

    • DOI

      10.1063/1.4794417

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] QuantitativeCharacterization of Band-Edge EnergyPositions in High-k Dielectrics byX-ray Photoelectron Spectroscopy2013

    • Author(s)
      Y. Chikata, K. K i ta , T. Nishimura, K.Nagashio, and A. Toriumi
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 52 Issue: 2R Pages: 21101-21101

    • DOI

      10.7567/jjap.52.021101

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Counter DipoleLayer Formation in Multilayer High-kGate Stacks2012

    • Author(s)
      S. Hibino, T. Nishimura, K. Nagashio, K. Kita, and A. Toriumi
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 51 Issue: 8R Pages: 81303-81303

    • DOI

      10.1143/jjap.51.081303

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Study on Dipole Layer Formation between Two Oxides :Experimental Evidences and Possible Models2011

    • Author(s)
      K . K i ta and A. Toriumi
    • Journal Title

      MRS Proceedings

      Volume: 1331

    • DOI

      10.1557/opl.2011.1519

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation ofDipole Layers at Oxide Interfaces inHigh-k Gate Stacks2010

    • Author(s)
      K . Ki t aL.Q.Zhu T.Nishimura,MV/cm by Using Substrate BiasK.Nagashio, A.Toriumi
    • Journal Title

      ECS Transactions

      Volume: 33(6) Issue: 6 Pages: 463-477

    • DOI

      10.1149/1.3487577

    • Related Report
      2012 Final Research Report
  • [Journal Article] GeO2/Ge界面反応の理解に基づくGeO2膜物性の化現象の制御2010

    • Author(s)
      喜 多 浩之 , 王盛凱, 李忠賢, 吉田まほろ, 西村知紀, 長汐晃輔, 鳥海明
    • Journal Title

      電子情報通信学会技術研究報告

      Volume: 110(90) Pages: 55-60

    • URL

      http://www.ieice.org/ken/paper/20100622CaZb/

    • Related Report
      2012 Final Research Report
  • [Journal Article] Desorption kinetics of GeO from GeO2/Ge structure2010

    • Author(s)
      S. K. Wang, K . K it a , C. H. Lee, T. Tabata, T. Nishimura, K. Nagashio, and A. Toriumi
    • Journal Title

      J. Appl. Phys

      Volume: 108 Issue: 5 Pages: 54104-54104

    • DOI

      10.1063/1.3475990

    • Related Report
      2012 Final Research Report
  • [Journal Article] Resistive Switching Behaviors of NiO Bilayer Films with Different Crystallinity Layers2010

    • Author(s)
      K . K it a , A. Eika, T. Nishimura, K.Nagashio, and A. Toriumi
    • Journal Title

      ECS Trans.

      Volume: 28(2) Issue: 2 Pages: 315-315

    • DOI

      10.1149/1.3372585

    • Related Report
      2012 Final Research Report
  • [Journal Article] Observation of Dipole Layer Formed at High-k Dielectrics/SiO2 Interface with X-ray Photoelectron Spectroscopy2010

    • Author(s)
      L. Q. Zhu, K. Kita, T. Nishimura, K. Nagashio, S. K. Wang, and A. Toriumi
    • Journal Title

      Appl. Phys. Express

      Volume: 3 Issue: 6 Pages: 61501-61501

    • DOI

      10.1143/apex.3.061501

    • NAID

      210000014682

    • Related Report
      2012 Final Research Report
  • [Journal Article] Formation of Dipole Layers at Oxide Interfaces in High-k Gate Stacks2010

    • Author(s)
      K.Kita, L.Q.Zhu T.Nishimura, K.Nagashio, A.Toriumi
    • Journal Title

      ECS Transactions

      Volume: 33(6) Pages: 463-477

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] GeO_2/Ge界面反応の理解に基づくGeO_2膜物性の劣化現象の制御2010

    • Author(s)
      喜多浩之, 王盛凱, 李忠賢, 吉田まほろ, 西村知紀, 長汐晃輔, 鳥海明
    • Journal Title

      電子情報通信学会技術研究報告

      Volume: 110(90) Pages: 55-60

    • NAID

      110007890345

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Desorption kinetics of GeO from GeO_2/Ge structure2010

    • Author(s)
      S.K.Wang, K.Kita, C.H.Lee, T.Tabata, T.Nishimura, K.Nagashio, A.Toriumi
    • Journal Title

      Journal of Applied Physics

      Volume: 108

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Resistive Switching Behaviors of NiO Bilayer Films with Different Crystallinity Layers2010

    • Author(s)
      K.Kita, A.Eika, T.Nishimura, K.Nagashio, A.Toriumi
    • Journal Title

      ECS Transactions

      Volume: 28(2) Pages: 315-322

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of Dipole Layer Formed at High-k Dielectrics/SiO_2 Interface with X-ray Photoelectron Spectroscopy2010

    • Author(s)
      L.Q.Zhu, K.Kita, T.Nishimura, K.Nagashio, S.K.Wang, A.Toriumi
    • Journal Title

      Applied Physics Express

      Volume: 3

    • NAID

      10027015062

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] MOx/CoFeB 界面磁気異方性の様々なMに対して普遍的な電圧応答2013

    • Author(s)
      栗原隆帆,古場治朗,宮川成人,喜多浩之
    • Organizer
      第60回応用物理学会春季学術講演会 29a-A8-2
    • Place of Presentation
      神奈川工科大学(厚木)
    • Year and Date
      2013-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] 「Internal Photo-emission法によるGeO/Ge 界面における伝導帯バンドオフセットの決定」2013

    • Author(s)
      張文峰, 西村知紀, 長汐晃輔, 喜多浩之,鳥海明
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学(厚木)
    • Year and Date
      2013-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] Characterization of VoltageControl of Magnetic Anisotropy up to 8MV/cm by Using Substrate BiasStructure2013

    • Author(s)
      J. Koba, T. Kuribara, N. Miyakawa, andK. Kita
    • Organizer
      12th Joint MMM/IntermagConference, BF-05
    • Place of Presentation
      米国 Chicago 市
    • Year and Date
      2013-01-13
    • Related Report
      2012 Final Research Report
  • [Presentation] Characterization of Voltage Control of Magnetic Anisotropy Up to 8 MV/cm by Using Substrate Bias Structure2013

    • Author(s)
      Jiro Koba, Nartuo Miyakawa, and Koji Kita
    • Organizer
      12th Joint MMM/Intermag Conference
    • Place of Presentation
      Chicago, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] MOx/CoFeB界面磁気異方性の様々なMに対して普遍的な電圧応答2013

    • Author(s)
      栗原隆帆,古場治朗,宮川成人,喜多浩之
    • Organizer
      第60回春季 応用物理学会学術講演会
    • Place of Presentation
      神奈川工科大学,厚木
    • Related Report
      2012 Annual Research Report
  • [Presentation] Internal Photo-emission 法によるGeO2/Ge 界面における伝導帯バンドオフセットの決定2013

    • Author(s)
      張文峰, 西村 知紀, 長汐 晃輔, 喜多 浩之, 鳥海 明
    • Organizer
      第60回春季 応用物理学会学術講演会
    • Place of Presentation
      神奈川工科大学,厚木
    • Related Report
      2012 Annual Research Report
  • [Presentation] XPS によるGeO2/Ge 界面の価電子帯バンドオフセットの決定2013

    • Author(s)
      張文峰, 西村 知紀, 長汐 晃輔, 喜多 浩之, 鳥海 明
    • Organizer
      第60回春季 応用物理学会学術講演会
    • Place of Presentation
      神奈川工科大学,厚木
    • Related Report
      2012 Annual Research Report
  • [Presentation] Challengesand Opportunities in Voltage Control ofMagnetic Anisotropy of UltrathinFerromagnetic Metals for FutureSpintronics2012

    • Author(s)
      K. Kita and D. C. Worledge
    • Organizer
      International Conferenceon Emerging Advanced Nanomaterials(ICEAN2012)
    • Place of Presentation
      オーストラリア,Brisbane 市) 招待講演
    • Year and Date
      2012-10-22
    • Related Report
      2012 Final Research Report
  • [Presentation] Interface DipoleConcellation in SiO/High-k/SiO2/SiGate Stacks2012

    • Author(s)
      S. Hibino, T. Nishimura, K. Nagashio, K.Kita and A. Toriumi
    • Organizer
      2012 Pacific Rim Meetingon Electrochemical and Solid-StateScience (PRiME 2012)
    • Place of Presentation
      米国 Honolulu 市
    • Year and Date
      2012-10-09
    • Related Report
      2012 Final Research Report
  • [Presentation] ConductionBand-offset in GeO/Ge Stack Determinedby Internal PhotoemissionSpectroscopy2012

    • Author(s)
      W. Zhang, T. Nishimura, K. Nagashio, K.Kita and A. Toriumi
    • Organizer
      2012 Pacific Rim Meetingon Electrochemical and Solid-StateScience (PRiME 2012), (
    • Place of Presentation
      米国 Honolulu 市
    • Year and Date
      2012-10-09
    • Related Report
      2012 Final Research Report
  • [Presentation] 「EC セル用 Ta薄膜へのプロトン導入法による導電性の変化」電気化学会2012

    • Author(s)
      小橋啓史,喜多浩之
    • Organizer
      第79回大会
    • Place of Presentation
      浜松市
    • Year and Date
      2012-03-31
    • Related Report
      2012 Final Research Report
  • [Presentation] ECセル用Ta_2O_5薄膜へのプロトン導入法による導電性の変化2012

    • Author(s)
      小橋啓史, 喜多浩之
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      浜松アクトシティ(静岡県浜松市)
    • Year and Date
      2012-03-31
    • Related Report
      2011 Annual Research Report
  • [Presentation] Control of Ge/High-kInterface for Ge CMOS Technology2012

    • Author(s)
      K. Kita, T. Nishimura, K. Nagashio, andA. Toriumi
    • Organizer
      39thConference on the Physics and Chemistryof Surfaces and Interfaces (PCSI-39)(招待講演)(
    • Place of Presentation
      米国SantaFe 市
    • Year and Date
      2012-01-25
    • Related Report
      2012 Final Research Report
  • [Presentation] Control of Ge/High-k Interface for Ge CMOS Technology2012

    • Author(s)
      K.Kita, T.Nishimura, K.Nagashio, A.Toriumi
    • Organizer
      39th Conference on the Physics and Chemistry of Surfaces and Interfaces (PCSI-39)
    • Place of Presentation
      米国SantaFe, NM(招待講演)
    • Year and Date
      2012-01-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Challenges and Opportunities in Voltage Control of Magnetic Anisotropy of Ultrathin Ferromagnetic Metals for Future Spintronics2012

    • Author(s)
      Koji Kita and D. C. Worledge
    • Organizer
      International Conference on Emerging Advanced Nanomaterials
    • Place of Presentation
      Brisbane, Australia
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Interface Dipole Cancellation in SiO2/High-k/SiO2/Si Gate Stacks2012

    • Author(s)
      Shinji Hibino, Tomonori Nishimura, Kosuke Nagashio, Koji Kita and Akira Toriumi
    • Organizer
      2012 Pacific Rim Meeting on Electrochemical and Solid-State Science
    • Place of Presentation
      Honolulu, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Conduction Band-offset in GeO2/Ge Stack Determined by Internal Photoemission Spectroscopy2012

    • Author(s)
      Weng F. Zhang, Tomonori Nishimura, Kosuke Nagashio, Koji Kita and Akira Toriumi
    • Organizer
      2012 Pacific Rim Meeting on Electrochemical and Solid-State Science
    • Place of Presentation
      Honolulou, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] CMOS ゲートスタック応用へ向けたGeO/Ge 界面反応の理解2011

    • Author(s)
      喜多浩之,西村知紀,長汐晃輔,鳥海明
    • Organizer
      第31回表面科学学術講演会
    • Place of Presentation
      京都江戸川区
    • Year and Date
      2011-12-17
    • Related Report
      2012 Final Research Report
  • [Presentation] CMOSゲートスタック応用へ向けたGeO_2/Ge界面反応の理解2011

    • Author(s)
      喜多浩之, 西村知紀, 長汐晃輔, 鳥海明
    • Organizer
      第31回表面科学学術講演会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)(招待講演)
    • Year and Date
      2011-12-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Electric-field InducedChange of Magnetic Anisotropy inCoFeB/Oxide Stacks2011

    • Author(s)
      K. Kita, D. W. Abraham, M. J. Gajek, andD. C. Worledge
    • Organizer
      56th Conference onMagnetism and Magnetic Materials (MMM)(
    • Place of Presentation
      米国 Scottsda
    • Year and Date
      2011-11-02
    • Related Report
      2012 Final Research Report
  • [Presentation] ElectricElectric-field Induced Change of Magnetic Anisotropy in CoFeB/Oxide Stacks2011

    • Author(s)
      Koji Kita, D.W.Abraham, M.J.Gajek, D.C.Worledge
    • Organizer
      56th Conference on Magnetism and Magnetic Materials (MMM)
    • Place of Presentation
      米国Scottsdale, AZ
    • Year and Date
      2011-11-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] Study on Dipole Layer Formation between Two Oxides : Experimental Evidences and Possible Models2011

    • Author(s)
      K.Kita, A.Toriumi
    • Organizer
      2011 MRS Spring Meeting
    • Place of Presentation
      米国San Francisco, CA(招待講演)
    • Year and Date
      2011-04-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Study on DipoleLayer Formation between Two Oxides :Experimental Evidences and PossibleModels2011

    • Author(s)
      K. Kita and A. Toriumi
    • Organizer
      2011 MRS Spring Meeting
    • Place of Presentation
      米国 San Francisco 市
    • Related Report
      2012 Final Research Report
  • [Presentation] Understanding of GeOMaterial Properties for Advanced Ge MISStacks2010

    • Author(s)
      K. Kita
    • Organizer
      The 41th IEEE SemiconductorInterface Specialists Conference(SISC)
    • Place of Presentation
      米国 SanDiego
    • Year and Date
      2010-12-08
    • Related Report
      2012 Final Research Report
  • [Presentation] Understanding of GeO2 Material Properties for Advanced Ge MIS Stacks2010

    • Author(s)
      Koji Kita
    • Organizer
      The 41th IEEE Semiconductor Interface Specialists Conference (SISC)
    • Place of Presentation
      San Diego, USA 招待講演
    • Year and Date
      2010-12-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] Formation of Dipole Layers at Oxide lnterfaces in High-k Gate Stacks2010

    • Author(s)
      K.Kita, L.Q.Zhu T.Nishimura, K.Nagashio, A.Toriumi
    • Organizer
      The 218th Electrochemical Society Meeting
    • Place of Presentation
      Las Vegas, USA 招待講演
    • Year and Date
      2010-10-12
    • Related Report
      2010 Annual Research Report
  • [Presentation] GeO/Ge界面反応の理解に基づく GeO膜物性の劣化現象の制御2010

    • Author(s)
      西村知紀, 長汐晃輔, 鳥海明
    • Organizer
      応用物理学会シリコンテクノロジー分科会/電気通信学会合同研究会「ゲート絶縁薄膜,容量膜,機能膜およびメモリ技術」(
    • Place of Presentation
      東京大学,目黒区
    • Year and Date
      2010-06-22
    • Related Report
      2012 Final Research Report
  • [Presentation] GeO_2/Ge界面反応の理解に基づくGeO_2膜物性の劣化現象の制御2010

    • Author(s)
      喜多浩之, 王盛凱, 李忠賢, 吉田まほろ, 西村知紀, 長汐晃輔, 鳥海明
    • Organizer
      応用物理学会シリコンテクノロジー分科会/電気通信学会合同研究会「ゲート絶縁薄膜,容量膜,機能膜およびメモリ技術」
    • Place of Presentation
      東京大学,目黒区
    • Year and Date
      2010-06-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] Resistiveswitching in NiO bilayer films withdifferent crystallinity layers2010

    • Author(s)
      K. Kita, A. Eika, T. Nishimura, K.Nagashio, and A. Toriumi
    • Organizer
      International Symposium on TechnologyEvolution for Silicon Nano-Electronics(ISTESNE) (
    • Place of Presentation
      東京工業大学,目黒区
    • Year and Date
      2010-06-04
    • Related Report
      2012 Final Research Report
  • [Presentation] Resistive switching in NiO bilayer films with different crystallinity layers2010

    • Author(s)
      K.Kita, A.Eika, T.Nishimura, K.Nagashio, A.Toriumi
    • Organizer
      International Symposium on Technology Evolution for Silicon Nano-Electronics (ISTESNE)
    • Place of Presentation
      東京工業大学,目黒区
    • Year and Date
      2010-06-04
    • Related Report
      2010 Annual Research Report
  • [Presentation] Resistiveswitching in NiO bilayer films withdifferent crystallinity layers2010

    • Author(s)
      K. Kita, A. Eika, T. Nishimura, K.Nagashio, and A. Toriumi
    • Organizer
      The217th Electrochemical Society Meeting
    • Place of Presentation
      カナダ Vancouver
    • Year and Date
      2010-04-27
    • Related Report
      2012 Final Research Report
  • [Presentation] Resistive switching in NiO bilayer films with different crystallinity layers2010

    • Author(s)
      K.Kita, A.Eika, T.Nishimura, K.Nagashio, A.Toriumi
    • Organizer
      The 217th The Electrochemical Society Meeting
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2010-04-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] XPS による GeO2/Ge 界面の価電子帯バンドオフセットの決定2010

    • Author(s)
      張文峰, 西村知紀, 長汐晃輔, 喜多浩之,鳥海明
    • Organizer
      第60回 応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学(厚木)
    • Related Report
      2012 Final Research Report
  • [Presentation] Formation ofDipole Layers at Oxide lnterfaces inHigh-k Gate Stacks2010

    • Author(s)
      K. Kita, L. Q. Zhu T. Nishimura, K.Nagashio, and A. Toriumi
    • Organizer
      The 218thElectrochemical Society Meeting
    • Place of Presentation
      米国 Las Vegas
    • Related Report
      2012 Final Research Report
  • [Book] The ElectrochemicalSociety, Pennington, NJ, USA2012

    • Author(s)
      Editors: S. Kar,S. Van Elshocht, K.
    • Publisher
      Kita, and D. Misra, ECS TransactionsVol. 50, No.4
    • Related Report
      2012 Final Research Report
  • [Book] Dielectric Materials and Metals for Nanoelectronics and Photonics 102012

    • Author(s)
      Editors: S. Kar, S. Van Elshocht, K. Kita, and D. Misra
    • Total Pages
      358
    • Publisher
      The Electrochemical Society, Pennington, NJ, USA
    • Related Report
      2012 Annual Research Report
  • [Book] Physicsand Technology of High-k Materials 9",The Electrochemical Society,Pennington, NJ, USA (2011

    • Author(s)
      Editors: S. Kar , M. Houssa, S. VanElshocht, D. Misra, and K. Kita
    • Publisher
      ECSTransactions
    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://www.scio.t.u-tokyo.ac.jp/index.h

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://www.adam.t.u-tokyo.ac.jp/top.html

    • Related Report
      2012 Final Research Report
  • [Remarks] 喜多研究室

    • URL

      http://www.scio.t.u-tokyo.ac.jp/publication.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.adam.t.u-tokyo.ac.jp/publication.html

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

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