Synthesis of belt-shaped fused conjugated molecule "pi belt": actualization as a key material in novel non-planar nano-carbon
| Project/Area Number |
22685006
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
AMAYA Toru 大阪大学, 工学(系)研究科(研究院), 助教 (20397615)
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| Project Period (FY) |
2010-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥24,310,000 (Direct Cost: ¥18,700,000、Indirect Cost: ¥5,610,000)
Fiscal Year 2013: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2011: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Fiscal Year 2010: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
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| Keywords | スマネン / πベルト / πボウル / カーボンナノチューブ / ビスマネニリデン / ボウル型π共役系分子 / ナノカーボン / 酸化的環化 / π共役 |
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| Research Abstract |
This study was conducted toward the synthesis of a belt-shaped fused conjugated molecule (pi belt). The strategy for the synthesis of pi belt was designed based on the use of bowl-shaped molecule sumanene with curved and fused benzene rings as a building block. The methods for linking the sumanene units were investigated. Sumanenes were coupled via three routes based on cross-coupling, oxidative coupling, and reductive coupling. The method to construct the curved and fused structure by intramolecular dehydrogenative oxidation was developed.
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Report
(5 results)
Research Products
(36 results)
