| Budget Amount *help |
¥25,480,000 (Direct Cost: ¥19,600,000、Indirect Cost: ¥5,880,000)
Fiscal Year 2012: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2011: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2010: ¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
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| Research Abstract |
Porous materials using organic molecules have attracted much attention due to their potential application such as gas absorption and so on. During this period, we have proposed a novel hierarchical method to construct porous structures through diamond network. In this method, the first step is to build up molecular assemblies: supramolecular cluster. These assemblies act to sustain porous structures with larger inclusion spaces. Then, the assemblies are accumulated by intermolecular interactions between assemblies to achieve both robustness and dynamics of the porous structures. Balance between robustness and dynamics leaded to drastic luminescent color change according to chemical stimuli.
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