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Control of Spatio-temporal Structures of Polymer Microspheres toward Advanced Materials

Research Project

Project/Area Number 22685024
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Polymer/Textile materials
Research InstitutionShinshu University

Principal Investigator

SUZUKI Daisuke  信州大学, 繊維学部, 准教授 (90547019)

Project Period (FY) 2010-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥25,220,000 (Direct Cost: ¥19,400,000、Indirect Cost: ¥5,820,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2012: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2011: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2010: ¥15,470,000 (Direct Cost: ¥11,900,000、Indirect Cost: ¥3,570,000)
Keywords高分子微粒子 / コロイド / 高分子ゲル / 時空間構造 / フォトニック結晶 / 微粒子集積 / ゲル / 化学振動反応 / アクチュエーター / 機能性材料 / アクチュエータ― / バイオミメティック / ハイドロゲル微粒子 / フォトニッククリスタル
Research Abstract

We prepared a series of functional polymer microspheres which will be able to be constituents of advanced materials. To synthesize oscillating microspheres, the catalysts of the chemical oscillating reaction were incorporated to hydrogel particles. The structures of the particles were characterized by dynamic light scattering, electron microscopy, and small-angle X-ray scattering. By assembling the microgels, we were able to obtain oscillating soft actuators, which were formed easily by bonding the microgels.

Report

(5 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (58 results)

All 2014 2013 2012 2011 2010 Other

All Journal Article (20 results) (of which Peer Reviewed: 17 results) Presentation (36 results) (of which Invited: 6 results) Book (2 results)

  • [Journal Article] Internal Structures of Thermosensitive Hybrid Microgels Investigated by Means of Small-Angle X-ray Scattering2014

    • Author(s)
      Daisuke Suzuki, Yasuhisa Nagase, Takuma Kureha, and Takaaki Sato
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 118 Issue: 8 Pages: 2194-2204

    • DOI

      10.1021/jp410983x

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multilayered Composite Microgels Synthesized by Surfactant-Free Seeded Polymerization2013

    • Author(s)
      Daisuke Suzuki, Tomoyo Yamagata, and Masaki Murai
    • Journal Title

      Langmuir

      Volume: 29 Issue: 33 Pages: 10579-10585

    • DOI

      10.1021/la4025537

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Soft actuators of organized self-oscillating microgels2012

    • Author(s)
      D. Suzuki
    • Journal Title

      Soft Matter

      Volume: 8 Issue: 45 Pages: 11447-11449

    • DOI

      10.1039/c2sm26477c

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogel Particles as a Particulate Stabilizer for Dispersion Polymerization2012

    • Author(s)
      Daisuke Suzuki
    • Journal Title

      Langmuir

      Volume: 28 Issue: 29 Pages: 10629-10634

    • DOI

      10.1021/la301127q

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Drying Mechanism of Poly(N-isopropylacrylamide) Microgel Dispersions2012

    • Author(s)
      Koji Horigome
    • Journal Title

      Langmuir

      Volume: 28 Issue: 36 Pages: 12962-12970

    • DOI

      10.1021/la302465w

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Colloidal Crystallization of Thermo-sensitive Gel Spheres of Poly (N-isopropyl acrylamide). Influence of Gel Size2012

    • Author(s)
      Daisuke Suzuki
    • Journal Title

      Colloid and Polymer Science

      Volume: 290 Pages: 107-117

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Drying Dissipative Structures of Thermo-sensitive Gel Spheres of Poly(N-isopropyl acrylamide) with Low Degree of Cross-linking2012

    • Author(s)
      Tsuneo Okubo
    • Journal Title

      Colloid and Polymer Science

      Volume: 290 Pages: 411-421

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Binary Mixtures of Cationic and Anionic Microgels2011

    • Author(s)
      Daisuke Suzuki and Koji Horigome
    • Journal Title

      Langmuir

      Volume: 27 Issue: 20 Pages: 12368-12374

    • DOI

      10.1021/la203035e

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Colloidal Crystallization of Thermo-sensitive Gel Spheres of Poly (N-isopropyl acrylamide)2011

    • Author(s)
      Daisuke Suzuki, Koji Horigome, Tomoyo Yamagata, Kiyoshi Shibata, Akira Tsuchida, and Tsuneo Okubo
    • Journal Title

      Influence of Degree of Cross-linking of the Gels Colloid and Polymer Science

      Volume: 289 Issue: 17-18 Pages: 1799-1808

    • DOI

      10.1007/s00396-011-2499-4

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Colloidal Crystallization of Thermo-sensitive Gel Spheres of Poly (N-isopropyl acrylamide)2011

    • Author(s)
      Tsuneo Okubo
    • Journal Title

      Colloid and Polymer Science

      Volume: 289 Pages: 291-299

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of pH and Temperature on Assembly of Multiresponsive Janus Microgels2011

    • Author(s)
      Yoshitaka Umeda
    • Journal Title

      Colloid and Polymer Science

      Volume: 289 Pages: 729-737

    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Drying Dissipative Structures of Thermo-sensitive Gel Spheres of Poly (N-isopropyl acrylamide)2011

    • Author(s)
      Tsuneo Okubo
    • Journal Title

      Colloid and Polymer Science

      Volume: 289 Pages: 807-816

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Colloidal Crystallization of Thermo-sensitive Gel Spheres of Poly (N-isopropyl acrylamide) with Low Degree of Cross-linking2011

    • Author(s)
      Tsuneo Okubo
    • Journal Title

      Colloid and Polymer Science

      Volume: 289 Pages: 1273-1281

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Colloidal Crystallization of Thermo-sensitive Gel Spheres of Poly (N-isopropyl acrylamide). Influence of Degree of Cross-linking of the Gels2011

    • Author(s)
      Daisuke Suzuki
    • Journal Title

      Colloid and Polymer Science

      Volume: 289 Pages: 1799-1808

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photo-Induced Hydrogen Nano-Generators2011

    • Author(s)
      Kosuke Okeyoshi
    • Journal Title

      Small

      Volume: 7 Pages: 311-315

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Colloidal Crystallization of Thermo-sensitive Gel Spheres of Poly(N-isopropyl acrylamide)2011

    • Author(s)
      Tsuneo Okubo
    • Journal Title

      Colloid and Polymer Science

      Volume: 289 Pages: 291-299

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Drying Dissipative Structures of Thermo-sensitive Gel Spheres of Poly(N-isopropylacrylamide)2011

    • Author(s)
      Tsuneo Okubo
    • Journal Title

      Colloid and Polymer Science

      Volume: (In press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Janus Hydrogel Particles2011

    • Author(s)
      Daisuke Suzuki
    • Journal Title

      高分子

      Volume: 60 Pages: 5-5

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Oscillating Soft Actuators of Hydrogel Particles2010

    • Author(s)
      Takeshi Kobayashi
    • Journal Title

      高分子

      Volume: 59 Pages: 694-694

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Control of Temporal Structures for Polymer Particle2010

    • Author(s)
      Daisuke Suzuki
    • Journal Title

      高分子

      Volume: 59 Pages: 774-774

    • Related Report
      2010 Annual Research Report
  • [Presentation] 機能性ヒドロゲル微粒子の創製と集積2013

    • Author(s)
      鈴木大介
    • Organizer
      第23回日本MRS年次大会
    • Place of Presentation
      横浜市開港記念会館
    • Year and Date
      2013-12-07
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Invited
  • [Presentation] Keynote Lecture : Control of Spatio-Temporal Structures for Polymer Colloids toward Advanced Soft Materials2012

    • Author(s)
      Daisuke Suzuki, Takeshi Kobayashi, Ryo Yoshida, Toshihiro Hirai
    • Organizer
      International Association of Colloid and Interface Scientists Conference (IACIS 2012)
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      2012-05-16
    • Related Report
      2013 Final Research Report
  • [Presentation] Smart Hydrogel Particles2011

    • Author(s)
      Daisuke Suzuki
    • Organizer
      6^<th> International Conference on Advanced Fiber/Textile Materials 2011
    • Place of Presentation
      Ueda, Japan(招待講演)
    • Year and Date
      2011-12-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] 機能性ハイドロゲル微粒子の展望2011

    • Author(s)
      鈴木大介
    • Organizer
      第5回超分子若手懇談会
    • Place of Presentation
      戸倉上山田(招待講演)
    • Year and Date
      2011-07-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] Self-oscillating Core/Shell Microgels : Effect of a Crosslinked Nanoshell on Autonomous Oscillation of the Core2011

    • Author(s)
      Daisuke Suzuki
    • Organizer
      60th SPSJ Annual Meeting
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2011-05-26
    • Related Report
      2013 Final Research Report
  • [Presentation] Self-oscillating Core/Shell Microgels : Effect of a Crosslinked Nanoshell on Autonomous Oscillation of the Core2011

    • Author(s)
      Daisuke Suzuki
    • Organizer
      60^<th> SPSJ Annual Meeting
    • Place of Presentation
      Osaka, Japan(招待講演)
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Controlled Assembly of Stimuli-Responsive Hydrogel Particles2011

    • Author(s)
      Koji Horigome
    • Organizer
      International Conference on Biomaterials Science 2010 (ICBS2011)
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2010 Annual Research Report
  • [Presentation] Design and fabrication of stimuli-responsive Janus microgels2010

    • Author(s)
      Daisuke Suzuki
    • Organizer
      PACHIFICHEM2010
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] 高分子ミクロスフェアの空間・時間構造制御2010

    • Author(s)
      鈴木大介
    • Organizer
      平成22年度繊維学会秋季研究発表会
    • Place of Presentation
      山形大学工学部
    • Year and Date
      2010-09-27
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 化学振動反応応答型ゲル粒子の集積化による新規ソフトアクチュエータの創製2010

    • Author(s)
      小林勇志
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Functional Hydrogel Microspheres-Design, Fabrication, and Characterization2010

    • Author(s)
      Daisuke Suzuki
    • Organizer
      39^<th> Seminar of Advanced Particle Handling Science
    • Place of Presentation
      Kyoto, Japan(invited lecture)
    • Year and Date
      2010-07-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新規ソフトデバイス創製を目指した高分子微粒子の空間・時間構造制御2010

    • Author(s)
      鈴木大介
    • Organizer
      第56回高分子研究発表会
    • Place of Presentation
      兵庫県民会館
    • Year and Date
      2010-07-16
    • Related Report
      2013 Final Research Report
  • [Presentation] Introduction of Temporal Structures to Polymer Colloid2010

    • Author(s)
      Daisuke Suzuki
    • Organizer
      59^<th> SPSJ Annual Meeting
    • Place of Presentation
      Yokohama, Japan(invited lecture)
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] ミクロゲル微粒子間架橋による新規自己拍動アクチュエータの創製2010

    • Author(s)
      小林勇志
    • Organizer
      第59回高分子年次大会
    • Place of Presentation
      パシフィコ横浜(招待講演)
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新規ソフトデバイス創製を目指した高分子微粒子の空間・時間構造制御2010

    • Author(s)
      鈴木大介
    • Organizer
      第56回高分子研究発表会
    • Place of Presentation
      兵庫県民会館(招待講演)
    • Related Report
      2010 Annual Research Report
  • [Presentation] 高分子ミクロスフェアの空間・時間構造制御2010

    • Author(s)
      鈴木大介
    • Organizer
      平成22年度繊維学会秋季研究発表会
    • Place of Presentation
      山形大学工学部(招待講演)
    • Related Report
      2010 Annual Research Report
  • [Presentation] ヤヌス型ハイドロゲル微粒子の創製と集合挙動の検討2010

    • Author(s)
      鈴木大介
    • Organizer
      第16回高分子ミクロスフェア討論会
    • Place of Presentation
      福井大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] 小角X線散乱法によるハイドロゲル微粒子の体積相転移と内部微細構造2010

    • Author(s)
      蓮岡和幸
    • Organizer
      第16回高分子ミクロスフェア討論会
    • Place of Presentation
      福井大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] 高分子微粒子の時空間構造制御による新規材料創製2010

    • Author(s)
      小林勇志
    • Organizer
      第16回高分子ミクロスフェア討論会
    • Place of Presentation
      福井大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] 異符号電荷を有するハイドロゲル微粒子混合系の検討2010

    • Author(s)
      堀込幸司
    • Organizer
      第16回高分子ミクロスフェア討論会
    • Place of Presentation
      福井大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] コアシェル構造の導入によるハイドロゲル微粒子の新機能創出2010

    • Author(s)
      山縣智世
    • Organizer
      第16回高分子ミクロスフェア討論会
    • Place of Presentation
      福井大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] 感温性ゲル球のコロイド結晶化2010

    • Author(s)
      大久保恒夫
    • Organizer
      第11回構造色シンポジウム
    • Place of Presentation
      立教大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] ヒドロゲル微粒子の構造制御と機能創出

    • Author(s)
      鈴木大介
    • Organizer
      微粒子設計セミナー-微粒子設計の基礎から応用まで
    • Place of Presentation
      フォーラムミカサエコ(東京都千代田区)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Surfactant Free Seeded Emulsion Polymerization in the presence of Hydrogel Particles

    • Author(s)
      Daisuke Suzuki and Tomoyo Yamagata
    • Organizer
      62th SPSJ Annual Meeting
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Electrodynamic Phenomenon of Temperature-responsive Microgels

    • Author(s)
      Takuma Kureha, Takaaki Sato and Daisuke Suzuki
    • Organizer
      62th SPSJ Annual Meeting
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] ヒドロゲル微粒子をコアとした水系シード乳化重合法による複合粒子の創製

    • Author(s)
      鈴木大介、山縣智世、村井将紀、小林千玲
    • Organizer
      第64回コロイドおよび界面化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Control of Spatio-Temporal Structures for Polymer Colloids toward Advanced Soft Materials

    • Author(s)
      Daisuke Suzuki
    • Organizer
      International Association of Colloid and Interface Scientists Conference (IACIS 2012)
    • Place of Presentation
      Sendai
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 機能性高分子微粒子の創製・展開

    • Author(s)
      鈴木大介
    • Organizer
      2012年度白樺夏季大学
    • Place of Presentation
      関東甲信越地区国公立大学草津セミナーハウス
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 高分子ミクロスフェアの時空間構造制御

    • Author(s)
      鈴木大介
    • Organizer
      第2回機能性材料研究会
    • Place of Presentation
      信州大学繊維学部
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Soft Oscillating Actuators Composed of Microgel Particles

    • Author(s)
      Daisuke Suzuki
    • Organizer
      61th SPSJ Annual Meeting
    • Place of Presentation
      Yokohama
    • Related Report
      2012 Annual Research Report
  • [Presentation] Colloidal Behavior of Smart Microgels: Drying Mechanism of Microgel Dispersions

    • Author(s)
      Daisuke Suzuki
    • Organizer
      Gelsympo2012
    • Place of Presentation
      Tsukuba
    • Related Report
      2012 Annual Research Report
  • [Presentation] Investigation of Interactions between Cationic and Anionic Microgels

    • Author(s)
      Koji Horigome
    • Organizer
      Gelsympo2012
    • Place of Presentation
      Tsukuba
    • Related Report
      2012 Annual Research Report
  • [Presentation] ゲル微粒子薄膜形成メカニズム

    • Author(s)
      堀込幸司
    • Organizer
      第17回高分子ミクロスフェア討論会
    • Place of Presentation
      東北大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] ゲル微粒子界面動電現象の新解釈

    • Author(s)
      呉羽拓真
    • Organizer
      第17回高分子ミクロスフェア討論会
    • Place of Presentation
      東北大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 多段階応答性ゲル微粒子のサイズ制御

    • Author(s)
      村井将紀
    • Organizer
      第24回高分子ゲル研究討論会
    • Place of Presentation
      東京大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 体積相転移を示すゲル微粒子の界面動電現象

    • Author(s)
      呉羽拓真
    • Organizer
      第24回高分子ゲル研究討論会
    • Place of Presentation
      東京大学
    • Related Report
      2012 Annual Research Report
  • [Book] Oscillating Microgels Driven by Chemical Reactions Hydrogel Micro- Nanoparticles (Serpe, Lyon Eds.)2012

    • Author(s)
      Daisuke Suzuki
    • Publisher
      Wiley InterScience
    • Related Report
      2013 Final Research Report
  • [Book] Hydrogel Micro- Nanoparticles (Serpe, Lyon Eds.)2012

    • Author(s)
      Daisuke Suzuki
    • Publisher
      Wiley InterScience
    • Related Report
      2012 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

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