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Analysis of transport phenomena in nano/micro porous electrodes for polymer electrolyte fuel cells by high-resolution in situ approaches.

Research Project

Project/Area Number 22686022
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Thermal engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

TSUSHIMA Shohji  東京工業大学, 理工学研究科, 准教授 (30323794)

Project Period (FY) 2010-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥24,050,000 (Direct Cost: ¥18,500,000、Indirect Cost: ¥5,550,000)
Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2012: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2011: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2010: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
Keywords燃料電池 / 物質輸送 / ナノ・マイクロ構造 / 多孔質 / 可視化 / 固体高分子形燃料電池 / ナノ・マイクロ工学 / 可視化計測
Research Abstract

Investigations on nano/micro porous electrode (catalyst layer) in polymer electrolyte fuel cells were conducted to clarify fabrication process and mass transfer in the electrodes. In situ and cross-sectional visualizations revealed that nano/micro structures of porous electrodes were intensively affected by ratio of ingredients applied to the fabrication process of the electrode. Influences of applying pressure by decal method and relative humidity under drying condition were also examined with fundamental mechanism for generations of micro cracks in the electrode considered. It was shown that transport phenomena on chemical species, ions and electrons in the porous electrode played a dominant role for high performance fuel cell, suggesting further improvements on design and control of the nano/micro porous electrode to enhance transport process in fuel cells.

Report

(5 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (28 results)

All 2013 2012 2011 2010 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (21 results)

  • [Journal Article] Fabrication and performance evaluation of structurally-controlled PEMFC catalyst layers by blending platinum-supported and stand-alone carbon black2013

    • Author(s)
      T. Suzuki, S.Tsushima, S. Hirai
    • Journal Title

      Journal of Power Sources

      Volume: 233 Pages: 269-276

    • DOI

      10.1016/j.jpowsour.2013.01.092

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microscopic Analysis of Interlayer Structure and Oxygen Transport Behaviors in Porous Electrode in PEMFC2013

    • Author(s)
      T. Suzuki, S. Tsushima, S. Hirai
    • Journal Title

      ECS Transactions

      Volume: Vol.58, No.1 Issue: 1 Pages: 489-494

    • DOI

      10.1149/05801.0489ecst

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural Control and Evaluation of PEMFC Catalyst Layers by Blending Platinum-Supported /Stand-Alone Carbon Black2012

    • Author(s)
      T. Suzuki, S. Tsushima, S. Hirai
    • Journal Title

      ECS Transactions

      Volume: Vol.50, No.2 Issue: 2 Pages: 1467-1473

    • DOI

      10.1149/05002.1467ecst

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Nafion^<[〇!R]> Ionomer and Carbon Particles on Structure Formation in a Proton-Exchange Membrane Fuel Cell Catalyst Layer Fabricated by the Decal Transfer Method2011

    • Author(s)
      T. Suzuki, S. Tsushima, S. Hirai
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: Vol.36, No.19 Issue: 19 Pages: 12361-12369

    • DOI

      10.1016/j.ijhydene.2011.06.090

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pore Structure and Cell Performance Analysis of PEMFC Catalyst Layers Fabricated by Decal Transfer Method with Variation of Hot Pressing Pressure2011

    • Author(s)
      T. Suzuki, S. Tsushima, S. Hirai
    • Journal Title

      ECS Transactions

      Volume: Vol.41, No.1 Issue: 1 Pages: 909-914

    • DOI

      10.1149/1.3635625

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of the PEMFC Catalyst Layer by Cross-sectional Visualization and Performance Evaluation2010

    • Author(s)
      T. Suzuki, S. Tsushima, S. Hirai
    • Journal Title

      ECS Transactions

      Volume: Vol.33, No.1 Issue: 1 Pages: 1465-1470

    • DOI

      10.1149/1.3484639

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of the PEMFC Catalyst Layer by Cross-sectional Visualization and Performance Evaluation2010

    • Author(s)
      T.Suzuki, S.Tsushima, S.Hirai
    • Journal Title

      ECS Transactions

      Volume: 33 Pages: 1465-1470

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Microscopic Analysis of Interlayer Structure and Oxygen Transport Behaviors in Porous Electrode in PEMFC2013

    • Author(s)
      T. Suzuki, S. Tsushima, S. Hirai
    • Organizer
      224th meeting of Electrochemical Society
    • Place of Presentation
      San Francisco
    • Year and Date
      2013-10-29
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 固体高分子形燃料電池MEAにおけるクラック形成と発電性能への影響2013

    • Author(s)
      松井陽平, 鈴木崇弘, ディーワンサイ・ペンサイ, 津島将司, 平井秀一郎
    • Organizer
      第54回電池討論会
    • Place of Presentation
      大阪
    • Year and Date
      2013-10-08
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] Crack generation in catalyst layer and micro porous layer by wet-dry cycles and its impact on PEMFC performance2013

    • Author(s)
      Y. Matsui, T. Suzuki, P. Deevanhxay, S. Tsushima, S. Hirai
    • Organizer
      ASME 2013 11th Fuel Cell Science, Engineering and Technology Conference
    • Place of Presentation
      Minneapolis
    • Year and Date
      2013-07-15
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] PEFC多孔質積層電極の層間構造と水分滞留時の酸素輸送LBM解析2013

    • Author(s)
      鈴木崇弘, 津島将司, 平井秀一郎
    • Organizer
      第50回伝熱シンポジウム
    • Place of Presentation
      仙台
    • Year and Date
      2013-05-31
    • Related Report
      2013 Final Research Report
  • [Presentation] 乾湿サイクルによるPEFC 触媒層・マイクロポーラス層内クラック形成と発電性能低下2013

    • Author(s)
      松井陽平, ディーワンサイペンサイ, 鈴木崇弘, 津島将司, 平井秀一郎
    • Organizer
      第50回伝熱シンポジウム
    • Place of Presentation
      仙台
    • Year and Date
      2013-05-29
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] PEFC 多孔質積層電極の層間構造と水分滞留時の酸素輸送LBM 解析2013

    • Author(s)
      鈴木崇弘,津島将司,平井秀一郎
    • Organizer
      第50回伝熱シンポジウム
    • Place of Presentation
      仙台
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structural Control and Evaluation of PEMFC Catalyst Layers by Blending Platinum-Supported /Stand-Alone Carbon Black2012

    • Author(s)
      T. Suzuki, S. Tsushima, S. Hirai
    • Organizer
      222th meeting of Electrochemical Society
    • Place of Presentation
      Honolulu
    • Year and Date
      2012-10-07
    • Related Report
      2013 Final Research Report
  • [Presentation] 白金担持・非担持カーボン混合によるPEFC 触媒層構造の制御と評価2012

    • Author(s)
      鈴木崇弘, 津島将司, 平井秀一郎
    • Organizer
      第49回伝熱シンポジウム
    • Place of Presentation
      富山
    • Year and Date
      2012-06-01
    • Related Report
      2013 Final Research Report
  • [Presentation] Thickness and Platinum Loading Control of Catalyst Layers in PEMFC by Blending Platinum Supported Carbon and Stand-Alone Ketjenblack2011

    • Author(s)
      T. Suzuki, S. Tsushima, S. Hirai
    • Organizer
      The 4th International Forum on Multidisciplinary Education and Research for Energy Science
    • Place of Presentation
      Honolulu
    • Year and Date
      2011-12-18
    • Related Report
      2013 Final Research Report
  • [Presentation] Thickness and Platinum Loading Control of Catalyst Layers in PEMFC by Blending Platinum Supported Carbon and Stand-Alone Ketjenblack2011

    • Author(s)
      T.Suzuki, S.Tsushima, S.Hirai
    • Organizer
      The 4th International Forum on Multidisciplinary Education and Research for Energy Science
    • Place of Presentation
      ハワイ(米国)
    • Year and Date
      2011-12-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] PEFC触媒層細孔構造の形成と特性評価2011

    • Author(s)
      鈴木崇弘, 津島将司, 平井秀一郎
    • Organizer
      第52回電池討論会
    • Place of Presentation
      船堀
    • Year and Date
      2011-10-18
    • Related Report
      2013 Final Research Report
  • [Presentation] PEFC触媒層細孔構造の形成と特性評価2011

    • Author(s)
      鈴木崇弘, 津島将司, 平井秀一郎
    • Organizer
      第52回電池討論会
    • Place of Presentation
      船堀(東京)
    • Year and Date
      2011-10-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] Pore Structure and Cell Performance Analysis of PEMFC Catalyst Layers Fabricated by Decal Transfer Method with Variation of Hot Pressing Pressure2011

    • Author(s)
      T. Suzuki, S. Tsushima, S. Hirai
    • Organizer
      220th meeting of Electrochemical Society
    • Place of Presentation
      Boston
    • Year and Date
      2011-10-14
    • Related Report
      2013 Final Research Report
  • [Presentation] Pore Structure and Cell Performance Analysis of PEMFC Catalyst Layers Fabricated by Decal Transfer Method with Variation of Hot Pressing Pressure2011

    • Author(s)
      T.Suzuki, S.Tsushima, S.Hirai
    • Organizer
      220th meeting of Electrochemical Society
    • Place of Presentation
      ボストン(米国)
    • Year and Date
      2011-10-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] PEFCの触媒層構造形成と発電性能2011

    • Author(s)
      鈴木崇弘, 津島将司, 平井秀一郎
    • Organizer
      第48回伝熱シンポジウム
    • Place of Presentation
      岡山
    • Year and Date
      2011-06-03
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] CCM断面構造可視化と発電性能試験によるPEFC特性評価2010

    • Author(s)
      鈴木崇弘, 津島将司, 平井秀一郎
    • Organizer
      第51回電池討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2010-11-11
    • Related Report
      2013 Final Research Report 2010 Annual Research Report
  • [Presentation] 固体高分子形燃料電池触媒層のAFM 計測2010

    • Author(s)
      永井邦雄, 津島将司, 平井秀一郎
    • Organizer
      熱工学コンファレンス2010
    • Place of Presentation
      長岡
    • Year and Date
      2010-10-31
    • Related Report
      2013 Final Research Report
  • [Presentation] 固体高分子形燃料電池触媒層のAFM計測2010

    • Author(s)
      永井邦雄, 津島将司, 平井秀一郎
    • Organizer
      熱工学コンファレンス2010
    • Place of Presentation
      長岡
    • Year and Date
      2010-10-31
    • Related Report
      2010 Annual Research Report
  • [Presentation] Characterization of the PEMFC Catalyst Layer by Cross-Sectional Visualization and Performance Evaluation2010

    • Author(s)
      T. Suzuki, S. Tsushima, S. Hirai
    • Organizer
      218th meeting of Electrochemical Society
    • Place of Presentation
      Las Vegas
    • Year and Date
      2010-10-12
    • Related Report
      2013 Final Research Report 2010 Annual Research Report
  • [Presentation] Structural Control and Evaluation of PEMFC Catalyst Layers by Blending Platinum-Supported/Stand-Alone Carbon Black

    • Author(s)
      T. Suzuki, S. Tsushima, S. Hirai
    • Organizer
      222th meeting of Electrochemical Society
    • Place of Presentation
      ハワイ(米国)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 白金担持・非担持カーボン混合によるPEFC触媒層構造の制御と評価

    • Author(s)
      鈴木崇弘,津島将司,平井秀一郎
    • Organizer
      第49回伝熱シンポジウム
    • Place of Presentation
      富山国際会議場(富山)
    • Related Report
      2012 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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