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Developing Experimental Methods for Evaluating the Ideal Decohesive Strength of Grain Boundaries

Research Project

Project/Area Number 22686058
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Physical properties of metals
Research InstitutionTohoku University

Principal Investigator

MATSUKAWA Yoshitaka  東北大学, 金属材料研究所, 助教 (70566356)

Project Period (FY) 2010-04-01 – 2013-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥26,390,000 (Direct Cost: ¥20,300,000、Indirect Cost: ¥6,090,000)
Fiscal Year 2012: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2011: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2010: ¥16,250,000 (Direct Cost: ¥12,500,000、Indirect Cost: ¥3,750,000)
Keywords粒界物性 / 破壊 / 電子顕微鏡 / 金属物性 / 表面・界面物性 / 機械的性質 / 粒界 / 脆化 / 界面 / 不純物偏析 / 第一原理計算 / アトムプローブ
Research Abstract

Due to technical difficulties in experiments the atomic-scale physical mechanisms of intergranular failure that limits the structural lifetime of nuclear materials have been theorized primarily by computer simulations in the past decade. However, since simulations are always based on assumptions and numerical approximations, the obtained results are ultimately in need of assessments and validations by experiments. To overcome the dilemma, in the present study experimental assessments have been carried out on the inputs and outputs of first principle calculations. A technical challenge is how to measure the ideal decohesion strength of grain boundaries without including the effect of local stress concentration due to pile-up dislocations.

Report

(4 results)
  • 2013 Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (48 results)

All 2014 2013 2012 2011 2010

All Journal Article (14 results) (of which Peer Reviewed: 14 results) Presentation (34 results) (of which Invited: 4 results)

  • [Journal Article] Effects of Neutron Irradiation on Microstructures and Hardness of Stainless Steel Weld-overlay Cladding of Nuclear Reactor Pressure Vessels2014

    • Author(s)
      T.Takeuchi, Y.Kakubo, Y.Matsukawa, Y.Nozawa, T.Toyama, Y.Nagai, Y.Nishiyama, J.Katsuyama, Y.Yamaguchi, K.Onizawa
    • Journal Title

      Journal of Nuclear Materials

      Volume: 449 Issue: 1-3 Pages: 273-276

    • DOI

      10.1016/j.jnucmat.2014.01.004

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Post-irradiation Annealing and Reirradiation on Microstructure in Surveillance Test Specimens of the Loviisa-1 Reactor Studied by Atom Probe Tomography and Positron Annihilation2014

    • Author(s)
      T.Toyama, A.Kuramoto, Y.Nagai, K.Inoue, Y.Nozawa, Y.Shimizu, Y.Matsukawa, M.Hasegawa, M.Valo
    • Journal Title

      Journal of Nuclear Materials

      Volume: 449 Issue: 1-3 Pages: 207-212

    • DOI

      10.1016/j.jnucmat.2014.01.036

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transition of Deformation Mechanism with Grain Refinement in Interstitial-Free Steel2014

    • Author(s)
      S. Itoh, K. Nakazawa, T. Matsunaga, Y. Matsukawa, Y. Satoh, H. Abe
    • Journal Title

      ISIJ International

      Volume: 印刷中

    • NAID

      130004678466

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Neutron Irradiation on the Microstructure of the stainless steel Electroslag Weld Overlay Cladding of Nuclear Reactor Pressure Vessels2013

    • Author(s)
      T.Takeuchi, Y.Kakubo, Y.Matsukawa, Y.Nozawa, Y.Nagai, Y.Nishiyama, J.Katsuyama, K.Onizawa, M.Suzuki
    • Journal Title

      Journal of Nuclear Materials

      Volume: 443 Issue: 1-3 Pages: 266-273

    • DOI

      10.1016/j.jnucmat.2013.07.035

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct Observation of Solute-dislocation Interaction on Extended Edge Dislocation in Irradiated Austenitic Stainless Steel2013

    • Author(s)
      M.Hatakeyama, I.Yamagata, Y.Matsukawa, S.Tamura
    • Journal Title

      Philosophical Magazine Letters

      Volume: 94 Issue: 1 Pages: 18-24

    • DOI

      10.1080/09500839.2013.853135

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In-situ TEM Study on Elastic Interaction between a Prismatic Loop and a Gliding Dislocation2012

    • Author(s)
      Y.Matsukawa & G.S.Liu
    • Journal Title

      Journal of Nuclear Materials

      Volume: 425 Issue: 1-3 Pages: 54-59

    • DOI

      10.1016/j.jnucmat.2011.12.001

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Grain Boundary Segregation in Neutron-irradiated 304 Stainless Steel Studied by Atom Probe Tomography2012

    • Author(s)
      T.Toyama, Y.Nozawa, W.Van Renterghem, Y.Matsukawa, M.Hatakeyama, Y.Nagai, A.Al Mazouzi & S.Van Dyck
    • Journal Title

      Journal of Nuclear Materials

      Volume: 425 Issue: 1-3 Pages: 71-75

    • DOI

      10.1016/j.jnucmat.2011.11.072

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microstructural Changes of a Thermally Aged Stainless Steel Submerged Arc Weld Overlay Cladding of Nuclear Reactor Pressure Vessels2012

    • Author(s)
      T.Takeuchi, J.Kameda, Y.Nagai, T.Toyama, Y.Matsukawa, Y.Nishiyama, K.Onizuka
    • Journal Title

      Journal of Nuclear Materials

      Volume: 425 Issue: 1-3 Pages: 60-64

    • DOI

      10.1016/j.jnucmat.2011.12.004

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In-situ TEM study on Elastic Interaction Between a Prismatic Loop and a Gliding Dislocation2012

    • Author(s)
      Y.Matsukawa, G.S.Liu
    • Journal Title

      Journal of Nuclear Materials

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Grain Boundary Segregation in Neutron-irradiated 304 Stainless Steel Studied by Atom Probe Tomography2012

    • Author(s)
      T.Toyama, Y.Matsukawa, et al
    • Journal Title

      Journal of Nuclear Materials

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microstructural Changes of a Thermally Aged Stainless Steel Submerged Arc Weld Overlay Cladding of Nuclear Reactor Pressure Vessels2012

    • Author(s)
      T.Takeuchi, Y.Matsukawa, et al
    • Journal Title

      Journal of Nuclear Materials

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Positron annihilation in Cr, Cu, and Au layers embedded in Al and quantum confinement of positrons in Au clusters2011

    • Author(s)
      P.Pikart, C.Hugenschmidt, M.Horisberger, Y.Matsukawa, M.Hatakeyama, T.Toyama, Y.Nagai
    • Journal Title

      Phys.Rev.B

      Volume: 84 Issue: 1 Pages: 14106-14106

    • DOI

      10.1103/physrevb.84.014106

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Irradiation-induced precipitates in a neutron irradiated 304 stainless steel studied by three-dimensional atom probe2011

    • Author(s)
      T.Toyama, Y.Nozawa, W.Van Renterghem, Y.Matsukawa, M.Hatakeyama, Y.Nagai, A.Al Mazouzi, S.Van Dyck
    • Journal Title

      J.Nucl.Mater.

      Volume: 418 Issue: 1-3 Pages: 62-68

    • DOI

      10.1016/j.jnucmat.2011.07.027

    • Related Report
      2013 Final Research Report 2011 Annual Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Positron Annihilation in Cr, Cu, and Au Layers Embedded in Al and Quantum Confinement of Positrons in Au Clusters2011

    • Author(s)
      P.Pikart, Y.Matsukawa, et al
    • Journal Title

      Physical Review B

      Volume: 84 Pages: 14106-14106

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 原子力材料におけるG 相析出物について2013

    • Author(s)
      松川義孝、鹿窪勇太、野沢康子、外山健、永井康介、叶野翔、J.J. Shen、畠山賢彦、阿部弘亨、鈴土知明、山口正剛、永瀬丈嗣、保田英洋、山本琢也
    • Organizer
      金研ワークショップ2013"より安全な原子力技術、核融合技術に向けての材料研究の展開"
    • Place of Presentation
      東北大学
    • Related Report
      2013 Final Research Report
  • [Presentation] 軽水炉圧力容器オーバレイクラッド中のG 相析出物及びその前駆体についてのTEM 結晶構造解析2013

    • Author(s)
      松川義孝、鹿窪勇太、野沢康子、外山健、永井康介、武内伴照、山口義仁、勝山仁哉、西山裕孝
    • Organizer
      2013秋の金属学会
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Final Research Report
  • [Presentation] TEM その場観察実験とMD シミュレーションの直接比較における問題点と改良の糸口について~ 転位―照射欠陥クラスタ相互作用過程の研究の場合 ~2013

    • Author(s)
      松川義孝
    • Organizer
      2013春の金属学会
    • Place of Presentation
      東京理科大学
    • Related Report
      2013 Final Research Report
  • [Presentation] Crystal Structure Analysis of Precipitates/Solute-Clusters Detected by Atom-Probe Tomography : G-phase, Solute Cluster, or G-phase Precursor?2013

    • Author(s)
      Y.Matsukawa, Y.Kakubo, T.Takeuchi, K.Arakawa, T.Toyama, Y.Nozawa, H.Terashima, T.Kojima, Y.Yamaguchi, J.Katsuyama, Y.Nishiyama, Y.Nagai
    • Organizer
      The Minerals, Metals & Materials Society 2013 Annual Meeting (TMS2013
    • Place of Presentation
      San Antonio, USA
    • Related Report
      2013 Final Research Report
  • [Presentation] Crystal structure analysis of nanometer-sized G-phase precipitates in a δ/γ duplex stainless steel weld overlay cladding of light-water reactor pressure vessel steels2013

    • Author(s)
      Y. Matsukawa, Y. Kakubo, N. Ebisawa, Y. Nagai, T. Toyama, T. Takeuchi, Y. Yamaguchi, J. Katsuyama, Y. Nishiyama
    • Organizer
      The Minerals, Metals & Materials Society 2013 Annual Meeting (TMS2013)
    • Place of Presentation
      San Antonio (USA)
    • Related Report
      2012 Annual Research Report
  • [Presentation] TEMその場観察実験とMDシミュレーションの直接比較における問題点と改良の糸口について2013

    • Author(s)
      松川義孝
    • Organizer
      日本金属学会2013年春期大会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 軽水炉圧力容器オーバレイクラッド中のG相析出物及びその前駆体についてのTEM結晶構造解析2013

    • Author(s)
      松川義孝、鹿窪勇太、野沢康子、外山健、永井康介、武内伴照、山口義仁、勝山仁哉、西山裕孝
    • Organizer
      日本金属学会2013年秋期大会
    • Place of Presentation
      金沢
    • Related Report
      2012 Annual Research Report
  • [Presentation] 原子力材料におけるG相析出物について2013

    • Author(s)
      松川義孝、鹿窪勇太、野沢康子、外山健、永井康介、叶野翔、J.J. Shen、畠山賢彦、阿部弘亨、鈴土知明、山口正剛、永瀬丈嗣、保田英洋、山本琢也
    • Organizer
      金研ワークショップ2013「より安全な原子力技術、核融合技術に向けての材料研究の展開」
    • Place of Presentation
      仙台
    • Related Report
      2012 Annual Research Report
  • [Presentation] 軽水炉圧力容器鋼A533B における照射誘起析出物‘G 相’の電子照射その場観察2013

    • Author(s)
      松川義孝、J.J. Shen、叶野翔、畠山賢彦、阿部弘亨、永井康介、鈴土知明、山口正剛、永瀬丈嗣、保田英洋、山本琢也
    • Organizer
      日本金属学会2014年春期大会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 原子炉燃料被覆管の安全設計基準に資する環境劣化評価手法に関する研究開発 (4) 環境劣化材の組織観察分析試験2013

    • Author(s)
      松川義孝、申晶潔、叶野翔、李艶芬、畠山賢彦、佐藤裕樹、松永哲也、阿部弘亨、牟田浩明、山中伸介
    • Organizer
      日本原子力学会2014年春の年会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] Updating the Theory of Dislocation : In-situ TEM Studies Exploring the Final Stage of Plastic Deformation Leading to Crack Nucleation2012

    • Author(s)
      Y.Matsukawa
    • Organizer
      SMS2012 : Summit of Materials Science
    • Place of Presentation
      Sendai, JAPAN
    • Related Report
      2013 Final Research Report
  • [Presentation] Atom-probe Quantitative Analysis on Compositional Change of Intermetallic Compound Precipitates in Zircaloy-2 upon Corrosion2012

    • Author(s)
      Y.Matsukawa, N.Ebisawa, K.Saito, Y.Nagai, N.Okada, K.Sakamoto, K.Une
    • Organizer
      NuMat2012 : the Nuclear Materials conference
    • Place of Presentation
      Osaka, JAPAN
    • Related Report
      2013 Final Research Report
  • [Presentation] ジルカロイ2 表面酸化被膜のアトムプローブ分析2012

    • Author(s)
      松川義孝、齋藤健、海老澤直樹、外山健、永井康介、岡田徳行、坂本寛、宇根勝巳
    • Organizer
      2012秋の原子力学会
    • Place of Presentation
      広島大学
    • Related Report
      2013 Final Research Report
  • [Presentation] 軽水炉圧力容器オーバレイクラッドのG 相析出物についてのTEM 結晶構造解析2012

    • Author(s)
      松川義孝、鹿窪勇太、野沢康子、外山健、永井康介、武内伴照、山口義仁、勝山仁哉、西山裕孝
    • Organizer
      2012秋の金属学会
    • Place of Presentation
      愛媛大学
    • Related Report
      2013 Final Research Report
  • [Presentation] Zr-Nb合金の腐食、水素化および照射効果に関する研究 (4) イオン照射材における照射誘起析出のアトムプローブ分析2012

    • Author(s)
      松川義孝
    • Organizer
      日本原子力学会2011年春期大会
    • Place of Presentation
      福井
    • Related Report
      2011 Annual Research Report
  • [Presentation] 軽水炉圧力容器オーバーレイクラッドのG相析出物についてのTEM結晶構造解析2012

    • Author(s)
      松川義孝
    • Organizer
      日本金属学会2012年秋期大会
    • Place of Presentation
      松山
    • Related Report
      2011 Annual Research Report
  • [Presentation] ジルカロイ2表面酸化被膜のアトムプローブ分析2012

    • Author(s)
      松川義孝
    • Organizer
      日本原子力学会2012年秋期大会
    • Place of Presentation
      広島
    • Related Report
      2011 Annual Research Report
  • [Presentation] Zr-Nb 二元系合金のイオン照射誘起析出のアトムプローブ分析2011

    • Author(s)
      松川義孝、齋藤健、永井康介、外山健、村上有美、円山健志、金思雄、阿部弘亨、岩井岳夫、篠原靖周
    • Organizer
      2011秋の金属学会
    • Place of Presentation
      沖縄
    • Related Report
      2013 Final Research Report
  • [Presentation] Irradiation-induced Precipitation in a Zr-Nb Alloy2011

    • Author(s)
      Y.Matsukawa, K.Saito, Y.Murakami, Y.Nagai, T.Toyama, S.Kim, Y.Satoh, H.Abe
    • Organizer
      International Workshop on Nuclear Materials : Ion Implantation as a Neutron Irradiation Analogue
    • Place of Presentation
      Oxford, UK
    • Related Report
      2013 Final Research Report
  • [Presentation] In-situ TEM Study on Slip Transfer across Grain Boundaries and Crack Nucleation in Polycrystalline Metals2011

    • Author(s)
      Y.Matsukawa
    • Organizer
      International Workshop on Predictability of Long-term Ageing Mechanisms of Reactor Components Based on Modeling and Laboratory Experiments (PAMELA) from PERFORM 60
    • Place of Presentation
      Mol, BELGIUM
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Zr-Nb 合金の水素化および照射効果に関する研究(3)無垢材とイオン照射材の微細組織分析2011

    • Author(s)
      松川義孝、斉藤健、外山健、永井康介、阿部弘亨、金思雄、佐藤裕樹、山口正剛、岩井岳夫、関村直人、篠原靖周
    • Organizer
      2011春の原子力学会
    • Place of Presentation
      福井大学
    • Related Report
      2013 Final Research Report
  • [Presentation] In-situ TEM Study on Elastic Interaction between a Prismatic Dislocation Loop and a Gliding Dislocation2011

    • Author(s)
      Y.Matsukawa, G.S.Liu, I.M.Robertson
    • Organizer
      The Minerals, Metals & Materials Society 2011 Annual Meeting (TMS2011)
    • Place of Presentation
      San Diego, USA
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] In-situ TEM study on slip transfer across grain boundaries & crack nucleation in polycrystalline metals2011

    • Author(s)
      Y. Matsukawa
    • Organizer
      An International Workshop on Predictability of Long-term Ageing Mechanisms of Reactor Components Based on Modeling and Laboratory Experiments (PAMELA) from PERFORM 60
    • Place of Presentation
      Belgium (Mol)
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] Irradiation-induced precipitation in a Zr-Nb alloy2011

    • Author(s)
      Y. Matsukawa
    • Organizer
      An International Workshop on Nuclear Materials: Ion Implantation as a Neutron Irradiation Analogue
    • Place of Presentation
      UK (Oxford)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 原子炉先進燃料被覆管材料Zr-Nb合金の照射誘起析出2011

    • Author(s)
      松川義孝
    • Organizer
      日本金属学会2011年秋期大会
    • Place of Presentation
      沖縄
    • Related Report
      2011 Annual Research Report
  • [Presentation] In-situ TEM Study on Elastic Interaction between a Prismatic Dislocation Loop and a Gliding Dislocation2011

    • Author(s)
      Yoshitaka Matsukawa, Grace S.Liu, Ian M.Robertson
    • Organizer
      The Minerals, Metals & Materials Society 2011 Annual Meeting (TMS2011)
    • Place of Presentation
      San Diego, USA(Invited)
    • Related Report
      2010 Annual Research Report
  • [Presentation] 原子炉先進燃料被覆管材料Zr-Nb合金の照射誘起析出2011

    • Author(s)
      松川義孝、齋藤健、永井康介、外山健、金思雄、佐藤裕樹、阿部弘亨、岩井岳夫、関村直人、篠原靖周
    • Organizer
      第148回日本金属学会2011年春期大会
    • Place of Presentation
      東京
    • Related Report
      2010 Annual Research Report
  • [Presentation] Zr-Nb合金の水素化および照射効果に関する研究(3)無垢材とイオン照射材の微細組織分析2011

    • Author(s)
      松川義孝、齋藤健、外山健、永井康介、阿部弘亨、金思雄、佐藤裕樹、山口正剛、岩井岳夫、関村直人、篠原靖周
    • Organizer
      日本原子力学会2011年春の大会
    • Place of Presentation
      福井
    • Related Report
      2010 Annual Research Report
  • [Presentation] In-situ TEM Study on Slip Transfer Across Grain Boundaries & Crack Nucleation in Polycrystalline Metals2011

    • Author(s)
      Yoshitaka Matsukawa
    • Organizer
      Predictability of Long-term Ageing Mechanisms of Reactor Components Based on Modeling and Laboratory Experiments (PAMELA) from PERFORM 60
    • Place of Presentation
      Mol, BELGIUM(Invited)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Irradiation-induced precipitation in a Zr-Nb alloy2011

    • Author(s)
      Yoshitaka Matsukawa, et al
    • Organizer
      An International Workshop on Nuclear Materials : Ion Implantation as a Neutron Irradiation Analogue
    • Place of Presentation
      Oxford, UK
    • Related Report
      2010 Annual Research Report
  • [Presentation] EBSD・FIB・アトムプローブを用いたΣ3 粒界における偏析不純物の定量分析2010

    • Author(s)
      松川義孝、村上有美、永井康介
    • Organizer
      2010秋の金属学会
    • Place of Presentation
      北海道大学
    • Related Report
      2013 Final Research Report
  • [Presentation] Deformation Twin in Coarse-grained Pure Aluminum2010

    • Author(s)
      Y.Matsukawa
    • Organizer
      The 12th International Conference on Aluminum Alloys (ICAA12)
    • Place of Presentation
      Yokohama, JAPAN
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Deformation Twinning in Bulk Aluminum with Coarse Grains2010

    • Author(s)
      Yoshitaka Matsukawa
    • Organizer
      The 12th International Conference on Aluminum Alloys (ICAA12)
    • Place of Presentation
      Yokohama, JAPAN(Invited)
    • Related Report
      2010 Annual Research Report
  • [Presentation] EBSD・FIB・アトムプローブを用いたΣ3粒界における偏析不純物の定量分析2010

    • Author(s)
      松川義孝、村上有美、永井康介
    • Organizer
      第147回日本金属学会2010年秋期大会
    • Place of Presentation
      札幌
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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