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Preparation of novel emulsion gel adsorbents and designs and operations of adsorption process for heavy-metal ions

Research Project

Project/Area Number 22686071
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

TOKUYAMA Hideaki  東京農工大学, 工学(系)研究科(研究院), 准教授 (10363029)

Project Period (FY) 2010-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥25,870,000 (Direct Cost: ¥19,900,000、Indirect Cost: ¥5,970,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2012: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2011: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2010: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
Keywords反応・分離工学 / 化学工学 / 高分子合成 / 吸着 / ゲル / レアメタル / エマルション
Research Abstract

Enhanced metal separation techniques that are energy-saving and environment-friendly are desirable in industrial chemistry, as they can be used in applications to separate valuable metal ions from industrial effluents. Novel emulsion gel adsorbents, that is, polymeric hydrogels containing randomly distributed oil microdroplets of an organic extractant (an oil-soluble complexing agent), were developed for metal adsorption. The emulsion gels successfully adsorbed metal ions from aqueous media. Monodisperse emulsion gel beads, which were approximately 1 mm in diameter, were prepared using a production method combining sedimentation polymerization and two-fluid atomization. A continuous process for adsorption of metal ions from a solution onto emulsion gel beads using the fixed bed method was established and designed.

Report

(5 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (39 results)

All 2014 2013 2012 2011 2010 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (28 results) (of which Invited: 2 results) Book (2 results) Remarks (5 results)

  • [Journal Article] Temperature-swing adsorption process of Au(III) ions using poly(N-isopropylacrylamide) hydrogel beads prepared by sedimentation polymerization combined with two-fluid atomization2014

    • Author(s)
      Hideaki Tokuyama, Gakuto Kato
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 53 Issue: 19 Pages: 8251-8220

    • DOI

      10.1021/ie500435w

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Emulsion gel beads prepared by sedimentation polymerization using two-fluid atomization and their Pd(II) ion adsorption properties2013

    • Author(s)
      Hideaki Tokuyama, Takuro Yoshida
    • Journal Title

      Reactive & Functional Polymers

      Volume: 73 Issue: 3 Pages: 550-554

    • DOI

      10.1016/j.reactfunctpolym.2012.12.006

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of novel emulsion gel adsorbents and their adsorption properties for heavy-metal ions2011

    • Author(s)
      Hideaki Tokuyama, Takuro Yoshida, Liangliang He
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 50 Issue: 22 Pages: 10270-10277

    • DOI

      10.1021/la701492u

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of poly(N-isopropylacrylamide) hydrogel beads by circulation polymerization2010

    • Author(s)
      Hideaki Tokuyama, Nobuyuki Yazaki
    • Journal Title

      Reactive & Functional Polymers

      Volume: 70 Issue: 12 Pages: 967-971

    • DOI

      10.1016/j.reactfunctpolym.2010.10.004

    • Related Report
      2013 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] エマルションゲルおよび多孔質ゲルの開発2013

    • Author(s)
      徳山英昭
    • Organizer
      第23回日本MRS年次大会
    • Place of Presentation
      万国橋会議センター, 横浜
    • Year and Date
      2013-12-10
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 抽出剤内包エマルションゲルの開発とレアメタルの吸着特性2013

    • Author(s)
      加藤岳人, 吉田拓郎, 徳山英昭
    • Organizer
      第32回溶媒抽出討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2013-11-22
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] Application of emulsion gels for metal ion adsorption2013

    • Author(s)
      Hideaki Tokuyama, Takuro Yoshida, Gakuto Kato
    • Organizer
      International Soft Matter Conference 2013
    • Place of Presentation
      Rome, Italy
    • Year and Date
      2013-09-17
    • Related Report
      2013 Final Research Report
  • [Presentation] 二流体微粒化法を用いた感温性ゲル粒子の作製と金イオンの吸着特性2013

    • Author(s)
      徳山英昭, 加藤岳人
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館
    • Year and Date
      2013-05-31
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 感温性ゲル粒子を用いた金イオンの温度スイング吸着プロセス2013

    • Author(s)
      加藤岳人, 徳山英昭
    • Organizer
      分離技術会年会2013
    • Place of Presentation
      日本大学
    • Year and Date
      2013-05-24
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 二流体微粒化法を用いた感温性ゲル粒子の作製と金イオンの温度スイング吸着プロセスの構築2013

    • Author(s)
      加藤岳人, 徳山英昭
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      大阪大学
    • Year and Date
      2013-03-17
    • Related Report
      2013 Final Research Report
  • [Presentation] Application of emulsion gels for metal ion adsorption2013

    • Author(s)
      Hideaki Tokuyama, Takuro Yoshida, Gakuto Kato
    • Organizer
      International Soft Matter Conference 2013
    • Place of Presentation
      Sapienza University of Rome, Rome, Itaty
    • Related Report
      2013 Annual Research Report
  • [Presentation] Preparation of novel emulsion gel beads for metal adsorption2012

    • Author(s)
      Hideaki Tokuyama, Takuro Yoshida
    • Organizer
      10th Japan-Korea Symposium on Materials & Interfaces
    • Place of Presentation
      Kyoto
    • Year and Date
      2012-11-08
    • Related Report
      2013 Final Research Report
  • [Presentation] 抽出剤内包エマルションゲルビーズの開発と金属イオンの吸着特性2012

    • Author(s)
      徳山英昭, 吉田拓郎
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      東北大学
    • Year and Date
      2012-09-21
    • Related Report
      2013 Final Research Report
  • [Presentation] 機能性高分子ゲルの製造と応用展開, 紛体操作に伴う諸現象に関する勉強会2012

    • Author(s)
      徳山英昭
    • Organizer
      紛体工学会
    • Place of Presentation
      山喜旅館, 伊東市
    • Year and Date
      2012-08-02
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] He Liangliang, 抽出剤内包エマルションゲルの開発と応用展開2012

    • Author(s)
      徳山英昭, 吉田拓郎
    • Organizer
      分離技術会年会2012
    • Place of Presentation
      関西大学
    • Year and Date
      2012-06-02
    • Related Report
      2013 Final Research Report
  • [Presentation] He Liangliang, 抽出剤内包エマルションゲルを用いたレアメタルの吸着分離2012

    • Author(s)
      徳山英昭, 吉田拓郎
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2012-05-30
    • Related Report
      2013 Final Research Report
  • [Presentation] Preparation and swelling/mechanical properties of emulsion gel adsorbents2012

    • Author(s)
      Hideaki Tokuyama, Liangliang He, Takuro Yoshida
    • Organizer
      The 14th Asia Pacific Confederation of Chemical Engineering Congress (APCChE 2012)
    • Place of Presentation
      Singapore
    • Year and Date
      2012-02-23
    • Related Report
      2013 Final Research Report
  • [Presentation] Preparation and swelling/mechanical properties of emulsion gel adsorbents2012

    • Author(s)
      H.Tokuyama, L.He, T.Yoshida
    • Organizer
      14th Asia Pacific Confederation of Chenical Engineering Congress
    • Place of Presentation
      シンガポール、サンテック・シンガポール国際会議展示場(招待講演)
    • Year and Date
      2012-02-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] Recovery of rare metal ions from an aqueous solution using novel emulsion gel adsorbents2012

    • Author(s)
      Liangliang He, Takuro Yoshida, Hideaki Tokuyama
    • Organizer
      The 14th Asia Pacific Confederation of Chemical Engineering Congress (APCChE 2012)
    • Place of Presentation
      Singapore
    • Year and Date
      2012-02-22
    • Related Report
      2013 Final Research Report
  • [Presentation] Recovery of rare metal ions from an aqueous solution using novel emulsion gel adsorbents2012

    • Author(s)
      L.He, T.Yoshida, H.Tokuyama
    • Organizer
      14th Asia Pacific Confederation of Chemical Engineering Congress
    • Place of Presentation
      シンガポール、サンテック・シンガポール国際会議展示場(招待講演)
    • Year and Date
      2012-02-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] 新規な抽出剤内包エマルションゲルの開発と金属イオンの吸着特性2011

    • Author(s)
      吉田拓郎, He Liangliang, 徳山英昭
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2011-09-15
    • Related Report
      2013 Final Research Report
  • [Presentation] 新規な抽出剤内包エマルションゲルの開発と金属イオンの吸着特性2011

    • Author(s)
      吉田拓郎, He Liangliang, 徳山英昭
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学(招待講演)
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] Application of polymer gels for adsorption of heavy metal ions2010

    • Author(s)
      Hideaki Tokuyama, Shuji Sakohara
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010)
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-17
    • Related Report
      2013 Final Research Report
  • [Presentation] Application of polymer gels for adsorption of heavy metal ions2010

    • Author(s)
      H.Tokuyama, S.Sakohara
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      アメリカ合衆国ホノルル市ハワイコンベンションセンター
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 旋回撹拌重合法によるミリオーダー球状高分子ゲルの作製2010

    • Author(s)
      吉田拓郎, 矢崎将崇, 徳山英昭
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学
    • Year and Date
      2010-09-07
    • Related Report
      2013 Final Research Report
  • [Presentation] 旋回撹拌重合法によるミリオーダー球状高分子ゲルの作製2010

    • Author(s)
      吉田拓郎, 矢崎将崇, 徳山英昭
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学(京都市)
    • Year and Date
      2010-09-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] 抽出剤内包エマルションゲルを用いたレアメタルの吸着分離

    • Author(s)
      徳山英昭
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] 抽出剤内包エマルションゲルの開発と応用展開

    • Author(s)
      徳山英昭
    • Organizer
      分離技術年会2012
    • Place of Presentation
      関西大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 機能性高分子ゲルの製造と応用展開

    • Author(s)
      徳山英昭
    • Organizer
      紛体操作に伴う諸現象に関する勉強会(紛体工学会)
    • Place of Presentation
      山喜旅館(伊東市)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 抽出剤内包エマルションゲルビーズの開発と金属イオンの吸着特性

    • Author(s)
      徳山英昭
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      東北大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Preparation of novel emulsion gel beads for metal adsorption

    • Author(s)
      Hideaki Tokuyama
    • Organizer
      10th Japan-Korea Symposium on Materials & Interfaces
    • Place of Presentation
      Coop Inn Kyoto, Kyoto
    • Related Report
      2012 Annual Research Report
  • [Presentation] 二流体微粒化法を用いた感温性ゲル粒子の作製と金イオンの温度スイング吸着プロセスの構築

    • Author(s)
      加藤岳人
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      大阪大学
    • Related Report
      2012 Annual Research Report
  • [Book] エマルションゲルおよび多孔質ゲルの開発, 「ゲルの安定化と機能性付与・次世代への応用開発」, 第1章 第5節2013

    • Author(s)
      徳山英昭
    • Publisher
      技術情報協会
    • Related Report
      2013 Final Research Report
  • [Book] ゲルの安定化と機能性付与・次世代への応用開発(第1章 第5節、エマルションゲルおよび多孔質ゲルの開発)2013

    • Author(s)
      徳山英昭
    • Total Pages
      552
    • Publisher
      技術情報協会
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~tokuyama/

    • Related Report
      2013 Final Research Report
  • [Remarks] 東京農工大学大学院工学府応用化学専攻徳山研究室ホームページ

    • URL

      http://www.tuat.ac.jp/~tokuyama/

    • Related Report
      2013 Annual Research Report
  • [Remarks] 東京農工大学大学院工学府応用化学専攻徳山研究室ホームページ

    • URL

      http://www.tuat.ac.jp/~tokuyama/

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~tokuyama/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~tokuyama/

    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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