Catalytic Activity and Electron Structure of Bimetallic Nanoparticles with Sonochemically Designed Inner Structures
| Project/Area Number |
22686074
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Tohoku University |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥25,350,000 (Direct Cost: ¥19,500,000、Indirect Cost: ¥5,850,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
Fiscal Year 2010: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
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| Keywords | 触媒機能解析 / 二元金属ナノ粒子 / 超音波 / 合金ナノ粒子 / 光触媒 / 助触媒 / コア・シェル構造 / 触媒活性 / 光触媒活性 / 第一原理計算 / フラッシュフォトリシス / 電子構造 / シナジー効果 / 超音波化学 |
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| Research Abstract |
Bimetallic nanoparticles consisting of two metals among Au, Pd, and Pt were prepared and immobilized on TiO_2 by sonochemical method and the relationship between element distributions in the bimetallic nanoparticles and the (photo) catalytic performances were evaluated. Synergistic effect originated from the structure of nanoparticles was emphasized in dark reaction rather than photocatalysis. It was found that element with high work function such as Pt contributed to enhancement in photocatalytic activities even if the amount was small.
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Report
(4 results)
Research Products
(26 results)
