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Catalytic Activity and Electron Structure of Bimetallic Nanoparticles with Sonochemically Designed Inner Structures

Research Project

Project/Area Number 22686074
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Catalyst/Resource chemical process
Research InstitutionTohoku University

Principal Investigator

MIZUKOSHI Yoshiteru  東北大学, 金属材料研究所, 准教授 (60342523)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥25,350,000 (Direct Cost: ¥19,500,000、Indirect Cost: ¥5,850,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
Fiscal Year 2010: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Keywords触媒機能解析 / 二元金属ナノ粒子 / 超音波 / 合金ナノ粒子 / 光触媒 / 助触媒 / コア・シェル構造 / 触媒活性 / 光触媒活性 / 第一原理計算 / フラッシュフォトリシス / 電子構造 / シナジー効果 / 超音波化学
Research Abstract

Bimetallic nanoparticles consisting of two metals among Au, Pd, and Pt were prepared and immobilized on TiO_2 by sonochemical method and the relationship between element distributions in the bimetallic nanoparticles and the (photo) catalytic performances were evaluated. Synergistic effect originated from the structure of nanoparticles was emphasized in dark reaction rather than photocatalysis. It was found that element with high work function such as Pt contributed to enhancement in photocatalytic activities even if the amount was small.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (26 results)

All 2013 2012 2011 2010 Other

All Journal Article (9 results) (of which Peer Reviewed: 8 results) Presentation (16 results) Remarks (1 results)

  • [Journal Article] Effect of CeO_2 support properties on structure of Pt-Cu nanoparticles synthesized by electron beam irradiation method for preferential CO oxidation2013

    • Author(s)
      J. Kugai、T. Moriya、S. Seino、T. Nakagawa、Y. Ohkubo、H. Nitani、T. Akita、Y. Mizukoshi、T. A. Yamamoto
    • Journal Title

      Chemical Engineering Journal

      Volume: 223巻 Pages: 347-355

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of visible-light-responsive titanium dioxide layer on titanium using anodic oxidization in nitric acid2013

    • Author(s)
      Mizukoshi, Y.
    • Journal Title

      Appl. Surf. Sci.

      Volume: 270 Pages: 513-518

    • DOI

      10.1016/j.apsusc.2013.01.071

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of CeO_2 support properties on structure of Pt-Cu nanoparticles synthesized by electron beam irradiation method for preferential CO oxidation2013

    • Author(s)
      J. Kugai, T. Moriya, S. Seino, T. Nakagawa, Y. Ohkubo, et al.
    • Journal Title

      Chemical Engineering Journal

      Volume: Vol.223 Pages: 347-355

    • DOI

      10.1016/j.cej.2013.02.116

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of for Pt-Cu bimetallic catalysts synthesized by electron beam irradiation method on preferential CO oxidation2012

    • Author(s)
      Junichiro Kugai
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: Vol.126 Pages: 306-314

    • DOI

      10.1016/j.apcatb.2012.07.028

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Visible Light Responsive TiO_2 Photocatalyst Prepared by Anodization of Ti-6Al-4V Alloy2012

    • Author(s)
      Y. Mizukoshi、N. Masahashi
    • Journal Title

      Chemistry Letters

      Volume: 41巻 Issue: 5 Pages: 544-545

    • DOI

      10.1246/cl.2012.544

    • NAID

      10030619884

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photo-induced properties of anodic oxide films on Ti6Al4V2012

    • Author(s)
      N. Masahashi、Y. Mizukoshi、S. Semboshi、 K. Ohmura、S. Hanada
    • Journal Title

      Thin Solid Films

      Volume: 520巻 Issue: 15 Pages: 4956-4964

    • DOI

      10.1016/j.tsf.2012.03.026

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Angle resolved XPS studies on an anodic oxide formed on Ti-Nb-Sn alloy and the photo-induced change in carbon contaminants adsorbed on its surface2012

    • Author(s)
      N. Ohtsu、N. Masahashi、Y. Mizukoshi
    • Journal Title

      Applied Surface Science

      Volume: 258巻 Issue: 16 Pages: 6502-6055

    • DOI

      10.1016/j.apsusc.2012.02.132

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visible light response of nitrogen and sulfur co-doped TiO2 photocatalysts fabricated by anodic oxidation2011

    • Author(s)
      Y. Komai、K. Okitsu、R. Nishimura、N. Ohtsu、 G. Miyamoto、T. Furuhara 、S. Semboshi、Y. Mizukoshi、N. Masahashi
    • Journal Title

      Catalysis Today

      Volume: 164巻 Issue: 1 Pages: 399-403

    • DOI

      10.1016/j.cattod.2010.10.085

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 超音波を利用した磁性ナノ材料の開発2010

    • Author(s)
      水越克彰、正橋直哉
    • Journal Title

      ケミカルエンジニアリング

      Volume: 56巻 Pages: 36-41

    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Presentation] 二元金属ナノ粒子の二酸化チタン光触媒に対する助触媒効果2013

    • Author(s)
      水越克彰、正橋直哉
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Year and Date
      2013-03-22
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Formation Mechanism of Noble Metal Nanoparticles in Aqueous Solution by Solution2012

    • Author(s)
      Y. Mizukoshi、N. Masahashi、S. Tanabe
    • Organizer
      International Conference on Emerging Advanced Nanomaterials (ICEAN2012)
    • Place of Presentation
      豪
    • Year and Date
      2012-10-23
    • Related Report
      2012 Final Research Report
  • [Presentation] 液相プラズマ法による貴金属ナノ粒子の創製とその生成機構の考察2012

    • Author(s)
      水越克彰、正橋直哉、田邉秀二
    • Organizer
      日本金属学会2012年秋季大会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2012-09-18
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Au-Pd二元合金担時TiO_2の電子状態解析2012

    • Author(s)
      村井俊文、長島正剛、内田純、趙顕秀、畠田大介、齊藤良行、水越克彰、正橋直哉
    • Organizer
      日本金属学会2012年秋季大会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2012-09-17
    • Related Report
      2012 Final Research Report
  • [Presentation] Formation Mechanism of Noble Metal Nanoparticles in Aqueous Solution by Solution2012

    • Author(s)
      Yoshiteru Mizukoshi
    • Organizer
      International Conference on Emerging Advanced Nanomaterials (ICEAN2012)
    • Place of Presentation
      オーストラリア ブリスベン
    • Related Report
      2012 Annual Research Report
  • [Presentation] Au-Pd二元合金担時TiO2の電子状態解析2012

    • Author(s)
      村井俊文
    • Organizer
      日本金属学会2012年秋季大会
    • Place of Presentation
      愛媛大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 金・パラジウム二元金属ナノ粒子のコア・シェル構造に対する触媒活性の依存性2011

    • Author(s)
      水越克彰、正橋直哉
    • Organizer
      日本金属学会2011年秋季大会
    • Place of Presentation
      沖縄県
    • Year and Date
      2011-11-09
    • Related Report
      2012 Final Research Report
  • [Presentation] 金・パフジウム二元金属ナノ粒子のコア・シェル構造に対する触媒活性の依存性2011

    • Author(s)
      水越克彰、正橋直哉
    • Organizer
      日本金属学会2011年秋季大会
    • Place of Presentation
      沖縄コンベンションセンターおよびカルチャーリゾートフェストーネ(沖縄)
    • Year and Date
      2011-11-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] Sonochemically designed internal structure of Au/Pd bimetallic nanoparticles and the promotional effect on photocatalysis2010

    • Author(s)
      Y. Mizukoshi、K. Sato、Y. Saito、T. J. Konno、 N. Masahashi
    • Organizer
      PACIFICHEM 2010 : 2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      米国
    • Year and Date
      2010-12-16
    • Related Report
      2012 Final Research Report
  • [Presentation] Sonochemically designed internal structure of Au/Pd bimetallic nanoparticles and the promotional effect on photocatalysis2010

    • Author(s)
      Y.Mizukoshi, K.Sato, Y.Saito, T.J.Konno, N.Masahashi
    • Organizer
      PACIFICHEM 2010 : 2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      米国ホノルル
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 超音波還元法による磁気回収および再使用可能な貴金属・磁性体複合ナノ触媒の調製2010

    • Author(s)
      出端大樹、興津健二、西村六郎、水越克彰、正橋直哉
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2010-11-07
    • Related Report
      2012 Final Research Report
  • [Presentation] 金・パラジウム二元合金ナノ粒子の触媒機能2010

    • Author(s)
      水越克彰、正橋直哉
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2010-11-07
    • Related Report
      2012 Final Research Report
  • [Presentation] 金・パラジウム二元合金ナノ粒子の触媒機能2010

    • Author(s)
      水越克彰、正橋直哉
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      熊本大学(熊本)
    • Year and Date
      2010-11-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] 超音波還元法による磁気回収および再使用可能な貴金属・磁性体複合ナノ触媒の調製2010

    • Author(s)
      出端大樹、興津健二、西村六郎、水越克彰、正橋直哉
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      熊本大学(熊本)
    • Year and Date
      2010-11-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] 超音波/逆沈殿法による超常磁性酸化鉄ナノ粒子の調製2010

    • Author(s)
      水越克彰、首藤達也、正橋直哉、田辺秀二
    • Organizer
      第19回日本ソノケミストリー学会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2010-10-21
    • Related Report
      2012 Final Research Report
  • [Presentation] 超音波/逆沈殿法による超常磁性酸化鉄ナノ粒子の調製2010

    • Author(s)
      水越克彰、首藤達也、正橋直哉、田辺秀二
    • Organizer
      第19回日本ソノケミストリー学会
    • Place of Presentation
      東京工業大学(神奈川)
    • Year and Date
      2010-10-21
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://polar.imr.tohoku.ac.jp/

    • Related Report
      2012 Final Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

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