| Budget Amount *help |
¥30,474,324 (Direct Cost: ¥23,441,788、Indirect Cost: ¥7,032,536)
Fiscal Year 2013: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2012: ¥4,864,324 (Direct Cost: ¥3,741,788、Indirect Cost: ¥1,122,536)
Fiscal Year 2011: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2010: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
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| Research Abstract |
I found that transition-metal complexes could be used as catalyst for the synthesis and transformation of organosulfur compounds, and that a variety of reactions involving cleavage of heteroatom bonds such as C-S, C-F, C-C, C-O, S-S, P-P bonds were developed. The development of efficient catalysts, which decreases the activation energy of the reaction, provides equilibrium reactions, when the relative thermodynamic stabilities of the substrates and products are close. Then, equilibrium control methods using co-substrates and thermodynamically intermediate substrates were developed. Method employing the combination of transition-metal catalysis and equilibrium control can be generally used for the synthesis of organosulfur compounds.
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