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Studies on characteristics and natural formation mechanisms of dioxins in kaolin clays

Research Project

Project/Area Number 22710021
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Environmental dynamic analysis
Research InstitutionCenter for Environmental Science in Saitama

Principal Investigator

HORII Yuichi  埼玉県環境科学国際センター, 化学物質担当, 主任 (30509534)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords環境計測 / 地球化学 / ダイオキシン / 天然生成 / カオリン粘土 / 窯業 / 安定同位体 / インベントリ / 環境分析 / ダイオキシン類 / ボールクレイ / ダイオキシン類インベントリ
Research Abstract

The presence of dioxins in ancient clays presented an interesting scientific quandary. We investigated occurrence and profiles of dioxins in nationwide kaolin clays, and estimated inventory of dioxins in ceramic industry based on combustion experiments of kaolin clay. Moreover, this study focused on relationship between depositional process of kaolin clay and distribution of dioxins in related materials, as well as isotope ratios of dioxins in kaolin clay to reveal origin of dioxins contained in kaolin clay.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (28 results)

All 2013 2012 2011 2010 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (14 results) Book (2 results) Remarks (4 results)

  • [Journal Article] 有機ハロゲン化合物の安定同位体組成-分析法からダイオキシン天然生成解析への応用まで-2013

    • Author(s)
      堀井勇一、山下信義
    • Journal Title

      ぶんせき

      Volume: No.3 Pages: 140-145

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] 残留性有機汚染物質の安定同位体比解析 -分析法からダイオキシン天然生成解析への応用まで-2013

    • Author(s)
      堀井勇一
    • Journal Title

      ぶんせき

      Volume: 3 Pages: 140-145

    • NAID

      10031156871

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Distribution and characteristics of dioxins in depositional process of kaolinitic clay sediment2012

    • Author(s)
      Yuichi Horii
    • Journal Title

      Organohalogen Compounds

      Volume: 74 Pages: 1425-1428

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Distribution, characteristics, and worldwide inventory of dioxins in kaolin ball clays2011

    • Author(s)
      Horii et al.
    • Journal Title

      Environ Sci Technol

      Volume: Vol.45 Issue: 17 Pages: 7517-7524

    • DOI

      10.1021/es2012512

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Environmental analysis of chlorinated and brominated polycyclic aromatic hydro-carbons by comprehensive two-dimensional gas chromatography coupled to high-resolution time-of-flight mass spectrometry2011

    • Author(s)
      T. Ieda, 他4名
    • Journal Title

      J. Chromatogr. A

      Volume: 1218 Issue: 21 Pages: 3224-3232

    • DOI

      10.1016/j.chroma.2011.01.013

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comprehensive two-dimensional gas chromatography coupled to high-resolution time-of-flight mass spectrometry for analysis of Cl-/Br-PAHs in environmental sample2011

    • Author(s)
      Ieda T, Ochiai N, Miyawaki T, Ohura T, Horii Y
    • Journal Title

      Organohalogen Compounds

      Volume: 73 Pages: 2155-2158

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A nationwide survey of dioxins in kaolin clays from Japan2010

    • Author(s)
      Horii et al.
    • Journal Title

      Organohalogen Compoounds

      Volume: Vol.72 Pages: 876-879

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A nationwide survey of dioxins in kaolin clays from Japan2010

    • Author(s)
      堀井勇一
    • Journal Title

      Organohalogen Compounds

      Volume: 72 Pages: 876-879

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Distribution and characteristics of dioxins in depositional process of kaolinitic clay sediment2012

    • Author(s)
      Horii et al.
    • Organizer
      32nd International Symposium on Halogenated Persistent Organic Pollutants
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      2012-08-22
    • Related Report
      2012 Final Research Report
  • [Presentation] カオリン粘土鉱物中のダイオキシン天然生成と地球規模の分布・動態予測について2012

    • Author(s)
      堀井勇一
    • Organizer
      「残留性有機フッ素化合物群の全球動態解明のための海洋科学的研究」講演会
    • Place of Presentation
      産業技術総合研究所
    • Year and Date
      2012-02-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] カオリン粘土に関するダイオキシンの天然生成について2011

    • Author(s)
      堀井勇一
    • Organizer
      統計数理研究所共同研究発表会
    • Place of Presentation
      統計数理研究所
    • Year and Date
      2011-12-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] Mass balance assessment of dioxins in kaolin ball clay used in ceramic industry2011

    • Author(s)
      Horii Y, Ohtsuka N, Kotaro M, Nojiri K
    • Organizer
      SETAC North America
    • Place of Presentation
      Hynes Convention Center(ボストン)
    • Year and Date
      2011-11-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Comprehensive two-dimensional gas chromatography coupled to high-resolution time-of-flight mass spectrometry for analysis of Cl-/Br-PAHs in environmental samples2011

    • Author(s)
      Ieda T, Ochiai N, Miyawaki T, Ohura T, Horii Y
    • Organizer
      31^<st> International Symposium on Halogenated Persistent Organic Pollutants
    • Place of Presentation
      Crown Plaza Brussels(ブリュッセル)
    • Year and Date
      2011-08-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] GC x GC-高分解能TOF-MSによる環境試料中有機ハロゲン化合物の網羅的分析-EI/NCI-2011

    • Author(s)
      家田曜世, 落合伸夫, 宮脇俊文, 堀井勇一, 大浦健
    • Organizer
      第20回環境化学討論会
    • Place of Presentation
      熊本県立大学
    • Year and Date
      2011-07-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] ダイオキシン類天然生成の検証:カオリン質粘土層の堆積過程とダイオキシン類の特徴2011

    • Author(s)
      堀井勇一, 金丸龍夫, 竹村貴人, 古川邦之, 大塚宜寿, 蓑毛康太郎, 野尻喜好
    • Organizer
      第20回環境化学討論会
    • Place of Presentation
      熊本県立大学
    • Year and Date
      2011-07-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] GC x GC-高分解能TOF-MSによる塩素化・臭素化PAHsの分析その2-負イオン化学イオン化法の適用-2011

    • Author(s)
      家田曜世, 落合伸夫, 宮脇俊文, 堀井勇一, 大浦健
    • Organizer
      第20回環境化学討論会
    • Place of Presentation
      熊本県立大学
    • Year and Date
      2011-07-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] Study on natural formation of dioxins in kaolin clays: a new approach to trace the origin of POPs2010

    • Author(s)
      Horii et al.
    • Organizer
      Pacifichem
    • Place of Presentation
      Honolulu, USA,
    • Year and Date
      2010-12-19
    • Related Report
      2012 Final Research Report
  • [Presentation] Study on natural formation of dioxins in kaolin clays-A new approach to trace the origin of POPs2010

    • Author(s)
      堀井勇一
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Hawaii Convention Center(ホノルル・米国)
    • Year and Date
      2010-12-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] A nationwide survey of dioxins in kaolin clays from Japan2010

    • Author(s)
      堀井勇一
    • Organizer
      30^<th> International Symposium on Halogenated Persistent Organic Pollutants
    • Place of Presentation
      Marriott Rivercenter(サンアントニオ・米国)
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] カオリン粘土中ダイオキシン類の分布と天然生成プロセスに関する研究2010

    • Author(s)
      堀井勇一
    • Organizer
      第19回環境化学討論会
    • Place of Presentation
      中部大学(愛知県)
    • Year and Date
      2010-06-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] カオリン質粘土の窯業利用に伴うダイオキシン類の動態と環境負荷量推定

    • Author(s)
      堀井勇一
    • Organizer
      第21回環境化学討論会
    • Place of Presentation
      松山市
    • Related Report
      2012 Annual Research Report
  • [Presentation] Distribution and characteristics of dioxins in depositional process of kaolinitic clay sediment

    • Author(s)
      Yuichi Horii
    • Organizer
      32nd International Symposium on Halogenated Persistent Organic Pollutants
    • Place of Presentation
      Cairns, Australia
    • Related Report
      2012 Annual Research Report
  • [Book] 同位体環境分析2013

    • Author(s)
      堀井勇一(共著)
    • Publisher
      丸善出版
    • Related Report
      2012 Final Research Report
  • [Book] 同位体環境分析2013

    • Author(s)
      馬淵久夫
    • Total Pages
      331
    • Publisher
      丸善出版
    • Related Report
      2012 Annual Research Report
  • [Remarks] 埼玉県環境科学国際センター研究員紹介

    • Related Report
      2012 Final Research Report
  • [Remarks] 埼玉県環境科学国際センター 研究員紹介

    • URL

      http://www.kankyou.pref.saitama.lg.jp/web/staff/horii.yuichi.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.pref.saitama.lg.jp/site/cess-shikenkenkyunotorikumi/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.kankyou.pref.saitama.lg.jp/repository/cess_repository.html

    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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