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High functionalization of nano-size coordination space based on itsinternal magnetic field for a specific reaction in the cavity

Research Project

Project/Area Number 22710089
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Nanostructural science
Research InstitutionJosai University (2012)
Osaka Electro-Communication University (2011)
Hiroshima University (2010)

Principal Investigator

AKITA Motoko  城西大学, 理学部, 教授 (30370125)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords配位ナノ空間 / 磁性ホスト化合物 / 磁場効果 / 分子性磁性体 / 金属錯体 / 水熱合成 / 配位ナノ空
Research Abstract

A series of metal-organic molecular-based magnets which included organic molecules as reactants were synthesized, and their crystal structure and magnetic properties were studied. Hydrothermal synthesis of D-, L-, and DL-amino acid with several transition metals gave a variety of molecular-based magnets which shows ferromagneism, antiferromagnetism and weak-ferromagnetism. New chiral magnets were successfully obtained from only achiral species by spontaneously resolution of enantiomers. Magnetic measurements revealed that those magnetic structures also might be chiral.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (19 results)

All 2012 2011 2010

All Presentation (19 results)

  • [Presentation] o-メチル置換フェニルニトロニルニトロキシド及びその遷移金属錯体の構造と磁性---軸不斉に基づくキラル磁性体の構築2012

    • Author(s)
      秋田素子、込宮良輔、青山政嗣、飯島英亮、花井章博、保坂孝平、小林啓二
    • Organizer
      第21回有機結晶シンポジウム
    • Place of Presentation
      横浜
    • Year and Date
      2012-11-08
    • Related Report
      2012 Final Research Report
  • [Presentation] ジメトキシ置換フェニルニトロニルニトロキシドの遷移金属錯体の構造と磁性2012

    • Author(s)
      込宮良輔、秋田素子、小林啓二
    • Organizer
      2012 年第21回有機結晶シンポジウム
    • Place of Presentation
      横浜
    • Year and Date
      2012-11-08
    • Related Report
      2012 Final Research Report
  • [Presentation] ニトロニルニトロキシドラジカルを用いたキラルな遷移金属錯体の合成、構造及び磁気的性質2012

    • Author(s)
      北尾大樹,秋田素子,西原禎文,井上克也
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山
    • Year and Date
      2012-09-21
    • Related Report
      2012 Final Research Report
  • [Presentation] W-Cu シアノ架橋型錯体を骨格としたキラル磁性体の合成と物性2012

    • Author(s)
      能美耕太郎,西原禎文,秋田素子,井上克也
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-09-21
    • Related Report
      2012 Final Research Report
  • [Presentation] メトキシ置換フェニルニトロニルニトロキシドラジカルの遷移金属錯体の構造多様性と磁性-自然分晶による構造的及び磁気的キラリティの発現2011

    • Author(s)
      秋田素子、佐藤翔矢、井上克也
    • Organizer
      第20回有機結晶シンポジウム
    • Place of Presentation
      富山
    • Year and Date
      2011-10-20
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] Chemical/Physical properties of iron(III) phosphates in sorption processes2011

    • Author(s)
      Masao Hadano, Motoko Akita, Sadafumi Nishihara, Motoko Akita, Katsuya Inoue
    • Organizer
      The Fifth Japanese-Russian Workshop
    • Place of Presentation
      Awaji, Japan
    • Year and Date
      2011-10-14
    • Related Report
      2012 Final Research Report
  • [Presentation] トリメトキシ置換フェニルニトロニルニトロキシドラジカルの遷移金属錯体の構造と磁気的性質2011

    • Author(s)
      秋田素子、佐藤翔矢、 Mohamedally Kurmoo, 井上克也
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      つくば
    • Year and Date
      2011-09-21
    • Related Report
      2012 Final Research Report
  • [Presentation] メトキシ置換フェニルニトロニルニトロキシドを配位子とする遷移金属錯体の結晶構造と磁性2011

    • Author(s)
      秋田素子
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      つくば
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] オクタシアノメタルイオンを用いた新規分子磁性体の合成と物性2011

    • Author(s)
      石本哲也,秋田素子,西原禎文,井上克也
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-18
    • Related Report
      2012 Final Research Report
  • [Presentation] アミノ酸を用いた遷移金属錯体の合成、構造と物性2011

    • Author(s)
      能美耕太郎,西原禎文,秋田素子,井上克也
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-17
    • Related Report
      2012 Final Research Report
  • [Presentation] Chiral and Achiral Organic Radical - Transition MetalMagnetic Coordination Polymers2011

    • Author(s)
      Motoko Akita, Shoya Sato, Chikako Suzuki, Sadafumi Nishihara, Katsuya Inoue, Mohamedally Kurmoo
    • Organizer
      14th, Asian Chemical Congress
    • Place of Presentation
      Bangkok, Thailand
    • Year and Date
      2011-09-06
    • Related Report
      2012 Final Research Report
  • [Presentation] Chiral and Achiral Organic Radical-Transition Metal Magnetic Coordination Polymers2011

    • Author(s)
      Motoko AKITA
    • Organizer
      14th Asian Chemical Congress
    • Place of Presentation
      Bangkok
    • Year and Date
      2011-09-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] トリメトキシ置換フェニルニトロニルニトロキシド-遷移金属錯体の合成、構造及び磁気的性質2011

    • Author(s)
      北尾大樹、秋田素子、西原禎文、井上克也
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水熱法によるコバルト-アミノ酸錯体の合成、構造と物性2011

    • Author(s)
      能美耕太郎、秋田素子、西原禎文、井上克也
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] トリメトキシフェニルニトロニルニトロキシドラジカル及びその遷移金属錯体の合成、構造と磁気的性質2010

    • Author(s)
      佐藤翔矢、北尾大樹、鈴木知佳子、秋田素子、西原禎文、井上克也
    • Organizer
      第4回有機πシンポジウム
    • Place of Presentation
      兵庫
    • Year and Date
      2010-11-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] メトキシ置換フェニルニトロニルニトロキシド及びその遷移金属錯体の構造と磁気的性質2010

    • Author(s)
      佐藤翔矢、北尾大樹、鈴木知佳子、秋田素子、西原禎文、井上克也
    • Organizer
      第19回有機結晶シンポジウム
    • Place of Presentation
      大阪
    • Year and Date
      2010-11-12
    • Related Report
      2010 Annual Research Report
  • [Presentation] 層状構造を有する新規コバルト化合物の水熱合成、構造及び磁気的性質2010

    • Author(s)
      川上竜司、秋田素子、Mohamedally Kurmoo、西原禎文、井上克也
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本
    • Year and Date
      2010-11-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis, Crystal Structures and Magnetic Properties of Transition Metal Complexes with Methoxy-substituted Phenylnitronyl Nitroxide Radicals2010

    • Author(s)
      秋田素子、佐藤翔矢、北尾大樹、鈴木知佳子、西原禎文、井上克也
    • Organizer
      第12回分子磁性国際会議(ICMM 2010)
    • Place of Presentation
      北京・中国
    • Year and Date
      2010-10-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] トリアジン骨格を有する新規トリスニトロキシドラジカルの合成、構造と磁気的性質2010

    • Author(s)
      佐藤翔矢、秋田素子、西原禎文、井上克也
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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