High functionalization of nano-size coordination space based on itsinternal magnetic field for a specific reaction in the cavity
Project/Area Number |
22710089
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Single-year Grants |
Research Field |
Nanostructural science
|
Research Institution | Josai University (2012) Osaka Electro-Communication University (2011) Hiroshima University (2010) |
Principal Investigator |
AKITA Motoko 城西大学, 理学部, 教授 (30370125)
|
Project Period (FY) |
2010 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
|
Keywords | 配位ナノ空間 / 磁性ホスト化合物 / 磁場効果 / 分子性磁性体 / 金属錯体 / 水熱合成 / 配位ナノ空 |
Research Abstract |
A series of metal-organic molecular-based magnets which included organic molecules as reactants were synthesized, and their crystal structure and magnetic properties were studied. Hydrothermal synthesis of D-, L-, and DL-amino acid with several transition metals gave a variety of molecular-based magnets which shows ferromagneism, antiferromagnetism and weak-ferromagnetism. New chiral magnets were successfully obtained from only achiral species by spontaneously resolution of enantiomers. Magnetic measurements revealed that those magnetic structures also might be chiral.
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Report
(4 results)
Research Products
(19 results)