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Spectroscopy of Organic Molecule/Ferromagnetic Metal Interface for Highly Efficient Room Temperature Spin injection into Graphene

Research Project

Project/Area Number 22740206
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Condensed matter physics I
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

MATSUMOTO Yoshihiro  独立行政法人日本原子力研究開発機構, 先端基礎研究センター, 任期付研究員 (80455287)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords表面・界面 / グラフェン / 強磁性金属 / 界面 / 垂直磁気異方性 / X線磁気円二色性 / 分子スピントロニクス / スピントロニクス / X線吸収分光
Research Abstract

In this study, the spin structures across the interface between single-layer graphene and a Ni(111) thin film are explored by employing the depth-resolved x-ray absorption and magnetic circular dichroism spectroscopy with the atomic layer resolution. The depth-resolved Ni L2,3-edge analysis clarifies that the Ni atomic layers adjacent to the interface show a transition of the spin orientation to the perpendicular one in contrast with the in-plane one in the bulk region. The C K-edge analysis reveals the intensifying of the spin-orbital interactions induced by the p-d hybridization at the interface as well as out-of-plane spin polarization at the p band region of graphene. The present study indicates the importance of the interface design at the atomic layer level for graphene-based spintronics.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (51 results)

All 2013 2012 2011 2010 Other

All Journal Article (18 results) (of which Peer Reviewed: 18 results) Presentation (30 results) Remarks (3 results)

  • [Journal Article] High spin polarization at the Fe/C60 interface in the Fe-doped C_<60> film2013

    • Author(s)
      S. Sakai, Y. Matsumoto, M. Ohtomo, S. Entani, P. V. Avramov, P. B. Sorokin, H. Naramoto
    • Journal Title

      Synth. Met.

      Volume: 173 Pages: 22-22

    • DOI

      10.1016/j.synthmet.2012.10.027

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Contact-induced spin polarization in graphene/h-BN/Ni Nanocomposites2012

    • Author(s)
      P.V. Avramov, A.A. Kuzubov, S. Sakai, H. Naramoto, M. Ohtomo, S. Entani, Y. Matsumoto, P.B. Sorokin
    • Journal Title

      J. Appl. Phys.

      Volume: 112 Issue: 11 Pages: 114303-114303

    • DOI

      10.1063/1.4767134

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] High hydrogen-adsorption-rate material based on graphene decorated with alkali metals2012

    • Author(s)
      L.Y. Antipina, P.V. Avramov, S. Sakai, H. Naramoto, M. Ohtomo, S. Entani, Y. Matsumoto, P.B. Sorokin
    • Journal Title

      Phys. Rev. B

      Volume: 86 Issue: 8 Pages: 85435-85435

    • DOI

      10.1103/physrevb.86.085435

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intrinsic edge asymmetry in narrow zigzag hexagonal heteroatomic nanoribbons causes their subtle uniform curvature2012

    • Author(s)
      P.V. Avramov, D.G. Fedorov, P.B. Sorokin, S. Sakai, H. Naramoto, M. Ohtomo, S. Entani, Y. Matsumoto, H. Naramoto
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 3 Issue: 15 Pages: 2003-2003

    • DOI

      10.1021/jz300625t

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Bias voltage dependence of tunneling magnetoresistance in granular C_<60>-Co films with current-perpendicular-to-plane geometry2012

    • Author(s)
      S. Sakai, S. Mitani, Y. Matsumoto, S. Entani, P.V. Avramov, M. Ohtomo, H. Naramoto, K. Takanashi
    • Journal Title

      J. Magn. Magn. Mater

      Volume: 324 Issue: 12 Pages: 1970-1970

    • DOI

      10.1016/j.jmmm.2012.01.033

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Quashi-monochromatic pencil beam of laser-driven protons generated using a conical cavity target holder2012

    • Author(s)
      M. Nishiuchi, A.S. Pirozhkov, H. Sakai, K. Ogura, T.Zh. Esirkepov, T. Tanimoto, M Kanasaki, A. Yogo, T. Hori, A. Sagisaka, Y. Fukuda, Y. Matsumoto, S. Entani, S. Sakai, C.M. Brenner, D. Neely, T. Yamauchi, S.V. Bulanov, K. Kondo
    • Journal Title

      Phys. Plasmas

      Volume: 19 Issue: 3 Pages: 30706-30706

    • DOI

      10.1063/1.3697843

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Precise control of single- and bi-layer graphene growths on epitaxial Ni(111) thin film2012

    • Author(s)
      S. Entani, Y. Matsumoto, M. Ohtomo, P.V. Avramov, H. Naramoto, S. Sakai
    • Journal Title

      J. Appl. Phys.

      Volume: 111 Issue: 6 Pages: 64324-64324

    • DOI

      10.1063/1.3694662

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Local structures and magnetic properties of Fullerene-Co systems studied by XAFS and XMCD analyses2012

    • Author(s)
      I. Hojo, A. Koide, Y. Matsumoto, T. Maruyama, S. Nagamatsu, S. Entani, S. Sakai, T. Fujikawa
    • Journal Title

      J. Elect. Spect. Relat. Phenom.

      Volume: 185 Pages: 32-32

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Local structures and magnetic properties of fullerene-Co systems studied by XAFS and XMCD analyses2012

    • Author(s)
      I.Hojo, A.koide, Y.Matsumoto, T.Maruyama, S.Nagamatsu, S.Entani, S.Sakai, Fujikawa
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena

      Volume: 185 Issue: 1-2 Pages: 32-38

    • DOI

      10.1016/j.elspec.2011.11.001

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ferromagnetic interlayer coupling in C_<60>-Co compound/Ni bilayer structure2011

    • Author(s)
      Y.Matsumoto, S.Sakai, S.Entani, Y.Takagi, T.Nakagawa, H.Naramoto, P.Avramov, T.Yokoyama
    • Journal Title

      Chem.Phys.Lett.

      Volume: 511 Issue: 1-3 Pages: 68-72

    • DOI

      10.1016/j.cplett.2011.05.038

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ab initio LC-DFT study of graphene, multilayer graphene and graphite2011

    • Author(s)
      P.V. Avramov, S. Sakai, S. Entani, Y. Matsumoto, H. Naramoto
    • Journal Title

      Chem. Phys. Lett.

      Volume: 508 Issue: 1-3 Pages: 86-86

    • DOI

      10.1016/j.cplett.2011.04.016

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interface Properties of Ag and Au/Graphene Heterostructures Studied by Micro-Raman Spectroscopy2011

    • Author(s)
      S. Entani, S. Sakai, Y. Matsumoto, T. Hao, H. Naramoto, Y. Maeda
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 50

    • NAID

      210000070404

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of cotunneling and spin polarization on the large tunneling magnetoresistance effect in granular C_<60>-Co films2011

    • Author(s)
      S.Sakai, S.Mitani, I.Sugai, K.Takanashi, Y.Matsumoto, S.Entani, H.Naramoto, P.V.Avramov, Y.Maeda
    • Journal Title

      Physical Review B

      Volume: 83 Issue: 17 Pages: 174422-174422

    • DOI

      10.1103/physrevb.83.174422

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interface properties of Ag and Au/graphene heterostructure studied by micro Raman spectroscopy2011

    • Author(s)
      S.Entani, S.Sakai, Y.Matsumoto, T.Hao, H.Naramoto, Y.Maeda
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 50 Issue: 4S Pages: 04DN03-04DN03

    • DOI

      10.1143/jjap.50.04dn03

    • NAID

      210000070404

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interface Properties of Metal/graphene Hetero- structures Studied by Micro-Raman Spectroscopy2010

    • Author(s)
      S. Entani, S. Sakai, Y. Matsumoto, T. Hao, H. Naramoto, Y. Maeda
    • Journal Title

      J. Phys. Chem. C

      Volume: 114 Issue: 47 Pages: 20042-20042

    • DOI

      10.1021/jp106188w

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Observation of intermolecular N-I interaction during the growth of a 4-cyano-4'- iodobiphenyl molecular crystal on GeS(001)2010

    • Author(s)
      R. Sumii, M. Sakamaki, Y. Matsumoto, K. Amemiya, K. Kanai, K. Seki
    • Journal Title

      Surf. Sci.

      Volume: 604 Issue: 13-14 Pages: 1100-1100

    • DOI

      10.1016/j.susc.2010.03.020

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Composition dependence of magnetic and magnetotransport properties in C_<60>-Co granular thin films2010

    • Author(s)
      I. Sugai, S. Sakai, Y. Matsumoto, H. Naramoto, S. Miani, K. Takanashi, Y. Maeda
    • Journal Title

      J. Appl. Phys.

      Volume: 108 Issue: 6 Pages: 693920-693920

    • DOI

      10.1063/1.3471800

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Interface properties of metal/graphene heterostructures studied by micro-Raman spectroscopy.2010

    • Author(s)
      圓谷志郎
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 114 Pages: 20042-20048

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 単層グラフェン/Ni(111)薄膜に於ける界面スピン再配列2013

    • Author(s)
      松本吉弘
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Year and Date
      2013-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation] 単層グラフェン/Ni(111)薄膜に於ける界面スピン再配列2013

    • Author(s)
      松本 吉弘
    • Organizer
      2013年 第60回 応用物理学会春季学術講演会
    • Place of Presentation
      神奈川県厚木市
    • Related Report
      2012 Annual Research Report
  • [Presentation] Electronic and magnetic states of single- and bi-layer graphene / Ni interface2012

    • Author(s)
      Y. Matsumoto
    • Organizer
      2nd International Conference of Asia Union of Magnetic Societies
    • Place of Presentation
      奈良県新公会堂
    • Year and Date
      2012-10-04
    • Related Report
      2012 Final Research Report
  • [Presentation] Depth-resolved x-ray magnetic circular dichroism spectroscopy on single layer graphene / Ni structure2012

    • Author(s)
      Y. Matsumoto
    • Organizer
      4th International Meeting on Spins in Organic Semiconductors
    • Place of Presentation
      クイーンメリー大学, 英国
    • Year and Date
      2012-09-13
    • Related Report
      2012 Final Research Report
  • [Presentation] Depth-resolved XMCD study on single- and bi-layer graphene / Ni structures2012

    • Author(s)
      Y. Matsumoto
    • Organizer
      XAFS theory workshop: XAFS theory and nanoparticles
    • Place of Presentation
      千葉大学
    • Year and Date
      2012-07-19
    • Related Report
      2012 Final Research Report
  • [Presentation] Depth-resolved XMCD spectroscopy on single-layer graphen / Ni(111) structure2012

    • Author(s)
      Y. Matsumoto
    • Organizer
      Conference on Magnetism,
    • Place of Presentation
      BEXCO, 韓国
    • Year and Date
      2012-07-09
    • Related Report
      2012 Final Research Report
  • [Presentation] Spin-polarized states of the CVD-grown graphene on the Ni(111)2012

    • Author(s)
      松本吉弘,
    • Organizer
      International Symposium on Surface Science-6
    • Place of Presentation
      早稲田大学, 東京
    • Year and Date
      2012-03-16
    • Related Report
      2012 Final Research Report
  • [Presentation] Electronic and magnetic states of single- and bi-layer graphene / Ni interface2012

    • Author(s)
      Yoshihiro Matsumoto
    • Organizer
      2nd International Conference of Asia Union of Magnetic Societies (ICAUMS2012)
    • Place of Presentation
      Nara, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Depth-resolved x-ray magnetic circular dichroism spectroscopy on single layer graphene / Ni structure2012

    • Author(s)
      Yoshihiro Matsumoto
    • Organizer
      4th International Meeting on Spins in Organic Semiconductors (SpinOS2012)
    • Place of Presentation
      London, United Kingdom
    • Related Report
      2012 Annual Research Report
  • [Presentation] Depth-resolved XMCD spectroscopy on single-layer graphen / Ni(111) structure2012

    • Author(s)
      Yoshihiro Matsumoto
    • Organizer
      19th International Conference on Magnetism (ICM2012)
    • Place of Presentation
      Busan, Korea
    • Related Report
      2012 Annual Research Report
  • [Presentation] Depth-resolved XMCD study on single- and bi-layer graphene / Ni structures2012

    • Author(s)
      Yoshihiro Matsumoto
    • Organizer
      XAFS theory workshop: XAFS theory and nanoparticles
    • Place of Presentation
      Chiba, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] 単層グラフェン/強磁性金属界面の電子・スピン状態2012

    • Author(s)
      松本吉弘, 圓谷志郎, 大伴真名歩, アブラモフパベル, 楢本洋, 雨宮健太, 境誠司
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学、東京
    • Related Report
      2011 Annual Research Report
  • [Presentation] Spin-polarized states of the CVD-grown graphene on the Ni(111)2011

    • Author(s)
      Y. Matsumoto
    • Organizer
      International Symposium on Surface Science-6
    • Place of Presentation
      タワーホール船堀, 東京
    • Year and Date
      2011-12-14
    • Related Report
      2012 Final Research Report
  • [Presentation] 単層・二層グラフェン/磁性金属のスピン偏極状態2011

    • Author(s)
      松本吉弘
    • Organizer
      第35回日本磁気学会学術講演会
    • Place of Presentation
      新潟
    • Year and Date
      2011-09-27
    • Related Report
      2012 Final Research Report
  • [Presentation] 磁性金属上の単層・二層グラフェンの電子・スピン状態2011

    • Author(s)
      松本吉弘
    • Organizer
      第72回応用物理学関係連合講演会
    • Place of Presentation
      山形大学, 山形
    • Year and Date
      2011-09-01
    • Related Report
      2012 Final Research Report
  • [Presentation] Magnetic structure of the C_<60>-Co compound layer at the interface with magnetic metal2011

    • Author(s)
      Y. Matsumoto
    • Organizer
      5th International Workshop on Spin Currents
    • Place of Presentation
      仙台国際センター, 宮城
    • Year and Date
      2011-07-27
    • Related Report
      2012 Final Research Report
  • [Presentation] X線磁気円二色性を利用したナノ炭素/磁性金属界面の元素選択的磁気状態分光2011

    • Author(s)
      松本吉弘
    • Organizer
      第17回シリサイド系半導体と関連物質研究会
    • Place of Presentation
      明治大学駿河台校舎(東京)
    • Year and Date
      2011-03-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] C_<60>-Co 化合物/Ni 積層薄膜界面における磁気交換結合2011

    • Author(s)
      松本吉弘
    • Organizer
      第58回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学, 神奈川
    • Year and Date
      2011-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] Spin-polarized states of the CVD-grown graphene on the Ni(111)2011

    • Author(s)
      Y. Matsumoto
    • Organizer
      2nd ASRC International Workshop on Magnetic Materials and Nanostructures
    • Place of Presentation
      原子力機構先端基礎研究センター, 茨城
    • Related Report
      2012 Final Research Report
  • [Presentation] Spin-polarized states of the CVD-grown graphene on the Ni(111)2011

    • Author(s)
      Y.Matsumoto, S Entani, M.Ohtomo, P.V.Avramov, H.Naramoto, K.Amemiya, S.Sakai
    • Organizer
      International Symposium on Surface Science (ISSS-6)
    • Place of Presentation
      Tower Hall Funabori, Tokyo
    • Related Report
      2011 Annual Research Report
  • [Presentation] Magnetic structure of the C_<60>-Co compound layer at the interface with magnetic meta2011

    • Author(s)
      Y.Matsumoto, S Entani, M.Ohtomo, P.V.Avramov, H.Naramoto, T.Yokoyama, S.Sakai
    • Organizer
      5th International Workshop on Spin Currents
    • Place of Presentation
      Sendai International Center, Miyagi
    • Related Report
      2011 Annual Research Report
  • [Presentation] 磁気円二色性で探る分子・ナノ炭素-磁性金属系のスピン状態2011

    • Author(s)
      松本吉弘, 圓谷志郎, 大伴真名歩, アブラモフパベル, 楢本洋, 雨宮健太, 境誠司
    • Organizer
      PF研究会「磁性薄膜・多層膜を究める:キャラクタライゼーションから新奇材料の創製へ」
    • Place of Presentation
      高エネ研、茨城(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 単層・二層グラフェン/磁性金属のスピン偏極状態2011

    • Author(s)
      松本吉弘, 圓谷志郎, 大伴真名歩, アブラモフパベル, 楢本洋, 雨宮健太, 境誠司
    • Organizer
      第35回日本磁気学会学術講演会
    • Place of Presentation
      新潟コンベンションセンター、新潟
    • Related Report
      2011 Annual Research Report
  • [Presentation] 強磁性金属上の単層・二層グラフェン/磁性金属の電子・スピン状態2011

    • Author(s)
      松本吉弘, 圓谷志郎, 大伴真名歩, アブラモフパベル, 楢本洋, 雨宮健太, 境誠司
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学、山形
    • Related Report
      2011 Annual Research Report
  • [Presentation] 円偏光放射光による分子スピントロニクス材料の元素選択的電子・磁気状態分光2010

    • Author(s)
      松本吉弘
    • Organizer
      2010 年秋期日本金属学会
    • Place of Presentation
      北海道大学工学部, 北海道
    • Year and Date
      2010-09-25
    • Related Report
      2012 Final Research Report
  • [Presentation] 円偏光放射光による分子スピントロニクス材料の元素選択的電子・磁気状態分光2010

    • Author(s)
      松本吉弘
    • Organizer
      日本金属学会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2010-09-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] 磁気円二色性によるC_<60>-Co 化合物 / Ni 積層薄膜の界面磁気状態分光2010

    • Author(s)
      松本吉弘
    • Organizer
      第71回応用物理学会学術講演会
    • Place of Presentation
      長崎大学, 長崎
    • Year and Date
      2010-09-14
    • Related Report
      2012 Final Research Report
  • [Presentation] C_<60>-Co 化合物/Ni 積層薄膜における磁気交換結合2010

    • Author(s)
      松本吉弘
    • Organizer
      第34回日本磁気学会学術講演会
    • Place of Presentation
      つくば国際会議場, 茨城
    • Year and Date
      2010-09-07
    • Related Report
      2012 Final Research Report
  • [Presentation] XMCD study of localized d spins in the C_<60>-Co compound affecting giant TMR effect in C_<60>-Co Films2010

    • Author(s)
      Y. Matsumoto
    • Organizer
      ISSP-MDF Joint International Workshop
    • Place of Presentation
      東大物性研, 千葉
    • Year and Date
      2010-06-03
    • Related Report
      2012 Final Research Report
  • [Presentation] Magnetic exchange interaction in the C_<60>-Co compound / Ni layer structure2010

    • Author(s)
      Y. Matsumoto
    • Organizer
      3rd Topical Meeting on Spins in Organic Semiconductors
    • Place of Presentation
      アムステルダム, オランダ
    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://asrc.jaea.go.jp/soshiki/gr/sakai-gr/index.html

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://asrc.jaea.go.jp/soshiki/gr/sakai-gr/index.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://asrc.jaea.go.jp/soshiki/gr/MolSpintronics%20HP/index.html

    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2020-05-15  

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