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Elucidation of occurring mechanism for spin properties in organic semiconductor devices using combining techniques of spectroscopy and magnetic resonance

Research Project

Project/Area Number 22740235
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Condensed matter physics II
Research InstitutionOsaka City University

Principal Investigator

KANEMOTO Katsuichi  大阪市立大学, 大学院・理学研究科, 准教授 (40336756)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywordsスピンエレクトロニクス / 光物性 / 磁気共鳴 / ポリマーデバイス
Research Abstract

The purpose of this research is to reveal the occurring mechanism for spin properties of organic semiconductor devices by developing a new analytical technique combining magnetic resonance with a combination technique of semiconductor device operation and a spectroscopic technique. We indeed succeeded in developing a system enabling to observe spectroscopic signals in an ESR apparatus. In order to identify the presence of the ESR response in the signals from device modulation measurements, we attempted several experiments. However, we were not able to observe such signals, unfortunately. We concluded that the reason would be because the amount of carriers contributable to the signals was smaller than expected.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (26 results)

All 2012 2011 2010 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (15 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Ultrafast photoexcitation dynamics ofπ-conjugated bodipy-anthracene-radical triad system : electron transfer, energy transfer and charge-separated ion-pair state toward a uniquely electron-polarized photo-excited quartet state2012

    • Author(s)
      Katsuichi Kanemoto, Atsushi Fukunaga, Motoaki Yasui, Daisuke Kosumi, Hideki Hashimoto, Hirotaka Tamekuni, Yuichi Kawahara, Yohei Takemoto, Jun Takeuchi, Yozo Miura, Yoshio Teki
    • Journal Title

      RSC Advances

      Volume: 2 Pages: 5150-5153

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast Photo-Excitation Dynamics ofπConjugated Bodipy-Anthracene-Radical Triad system : Electron Transfer, Energy Transfer and Charge-Separated Ion-Pair State Toward a Uniquely Electron-Polarized Photo-Excited Quartet State2012

    • Author(s)
      K. Kanemoto, A. Fukunaga, M. Yasui, D. Kosumi, H. Hashimoto, H. Tamekuni, Y. Kawahara, Y. Takemoto, J. Takeuchi, Y. Miura, and Y. Teki
    • Journal Title

      RSC Advances

      Volume: 2巻 Issue: 12 Pages: 5150-5153

    • DOI

      10.1039/c2ra20473h

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic investigation of excitons, photocarriers and bias-induced carriers in regioregular poly(3-alkylthiophene)2011

    • Author(s)
      Katsuichi Kanemoto, Motoaki Yasui, Tatsuya Higuchi, Daisuke Kosumi, Ichiro Akai, Tsutomu Karasawa, and Hideki Hashimoto
    • Journal Title

      Physical Review B

      Volume: 83 Pages: 205203-205203

    • NAID

      120006539741

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Morphology dependent exciton formation in regioregular poly(3-alkyl) thiophenes2011

    • Author(s)
      Katsuichi Kanemoto, M. Yasui, D. Kosumi, M. Sugisaki, T. Karasawa, H. Hashimoto
    • Journal Title

      Physica Status Solidi(c)

      Volume: 8 Pages: 88-91

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast Excited State Dyanmics of Monomeric Bacteriochlorophyll a2011

    • Author(s)
      Daisuke Kosumi, Satoshi Maruta, Ritsuko Fujii, Katsuichi Kanemoto, Mitsuru Sugisaki, and Hideki Hashimoto
    • Journal Title

      Physica Status Solidi(c)

      Volume: 8 Pages: 92-95

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic investigation of excitons, photocarriers and bias-induced carriers in regioregular poly(3-alkylthiophene).2011

    • Author(s)
      K.Kanemoto, M.Yasui, T.Higuchi, D.Kosumi, I.Akai, T.Karasawa, H.Hashimoto
    • Journal Title

      Physical Review B

      Volume: (印刷中)

    • NAID

      120006539741

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast Excited State Dyanmics of Monomeric Bacteriochlor ophyll a2011

    • Author(s)
      D.Kosumi, S.Maruta, R.Fujii, K.Kanemoto, M.Sugisaki, H.Hashimoto
    • Journal Title

      Physica Status Solidi (c)

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Morphology dependent exciton formation in regioregular poly(3-alkyl)thiophenes2011

    • Author(s)
      K.Kanemoto, M.Yasui, D.Kosumi, M.Sugisaki, T.Karasawa., H.Hashimoto
    • Journal Title

      Physica Status Solidi (c)

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] π共役ポリマーを用いた有機ダイオードにおけるスピンペアの役割の解明2012

    • Author(s)
      上田裕二郎, 竹本圭佑, 松岡秀展, 鐘本勝一
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学
    • Related Report
      2011 Final Research Report
  • [Presentation] 有機半導体デバイスにおけるESR誘起分極電流の発現機構の解明2012

    • Author(s)
      竹本圭佑, 上田裕二郎, 松岡秀展, 鐘本勝一
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学
    • Related Report
      2011 Final Research Report
  • [Presentation] 有機半導体ダイオードのESRによって誘起される分極電流2011

    • Author(s)
      鐘本勝一, 松岡秀展, 上田裕二郎, 竹本圭佑
    • Organizer
      電子スピンサイエンス学会2011
    • Place of Presentation
      仙台国際センター
    • Related Report
      2011 Final Research Report
  • [Presentation] 発光及び光電流検出ESRを用いたπ共役ポリマーにおけるスピンペアの研究2011

    • Author(s)
      上田裕二郎, 鐘本勝一, 橋本秀樹
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学
    • Related Report
      2011 Final Research Report
  • [Presentation] デバイス変調吸収分光法からみたポリマーELデバイスの一重項と三重項励起子の関係2011

    • Author(s)
      金信真理子, 鐘本勝一, 橋本秀樹
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 有機薄膜デバイスにおける光電流の巨大電子スピン共鳴応答2011

    • Author(s)
      松岡秀展、鐘本勝一、橋本秀樹
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟大学
    • Related Report
      2011 Final Research Report
  • [Presentation] デバイス変調分光法によるポリマーELデバイスの動作過程についての研究2011

    • Author(s)
      金信真理子, 鐘本勝一, 橋本秀樹
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟大学
    • Related Report
      2011 Final Research Report
  • [Presentation] A Polarization Current Induced by ESR in an Organic Semiconductor Diode2011

    • Author(s)
      K.Kanemoto
    • Organizer
      The 5th Japanese-Russian Workshop on Open Shell Compounds and Molecular Spin Devices
    • Place of Presentation
      Awaji International Conference Center, Awaji Island, Japan(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 有機半導体ダイオードのESRによって誘起される分極電流2011

    • Author(s)
      鐘本勝一, 松岡秀展, 上田裕二郎, 竹本圭佑
    • Organizer
      電子スピンサイエンス学会
    • Place of Presentation
      仙台国際センター
    • Related Report
      2011 Annual Research Report
  • [Presentation] Morphology dependent excitons and carriers in the diode of regioregular poly(3-hexyl) thiophene2010

    • Author(s)
      K. Kanemoto, M. Yasui, D. Kosumi, M. Sugisaki, H. Hashimoto and T. Karasawa
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies(PACIFICHEM 2010)
    • Place of Presentation
      Honolulu, USA
    • Related Report
      2011 Final Research Report
  • [Presentation] Bleaching信号からみたポリ3ヘキシルチオフェン薄膜の光励起ダイナミクス2010

    • Author(s)
      鐘本勝一, 安井基晃, 小澄大輔, 橋本秀樹, 唐沢力
    • Organizer
      第4回分子科学討論会
    • Place of Presentation
      大阪大学
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Morphology dependent exciton formation in regioregular poly(3-alkyl) thiophenes2010

    • Author(s)
      Katsuichi Kanemoto, Motoaki Yasui, Daisuke Kosumi, Mitsuru Sugisaki, Tsutomu Karasawa and Hideki Hashimoto
    • Place of Presentation
      Brisbane, Australia
    • Related Report
      2011 Final Research Report
  • [Presentation] Photocarrier Dynamics of The P3HT/PCBM Composite Photovoltaic Device as Revealed by Bleaching Spectroscopy2010

    • Author(s)
      K. Kanemoto, A. Ogata, D. Kosumi, H. Hashimoto
    • Organizer
      International conference on science and technology of synthetic metals 2010(ICSM 2010)
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2011 Final Research Report
  • [Presentation] Photocarrier Dynamics of The P3HT/PCBM Composite Photovoltaic Device as Revealed by Bleaching Spectroscopy2010

    • Author(s)
      K.Kanemoto, A.Ogata, D.Kosumi, H.Hashimoto
    • Organizer
      International conference on science and technology of synthetic metals 2010 (ICSM2010)
    • Place of Presentation
      京都大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] Morphology dependent excitons and carriers in the diode of regioregular poly(3-hexyl)thiophene2010

    • Author(s)
      K.Kanemoto, M.Yasui, D.Kosumi, M.Sugisaki, H.Hashimoto, T.Karasawa
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010)
    • Place of Presentation
      Honolulu, USA
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.sci.osaka-cu.ac.jp/phys/ppes/index-j.html

    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 電流制御方法および電流制御装置2011

    • Inventor(s)
      鐘本勝一、松岡秀展
    • Industrial Property Rights Holder
      鐘本勝一、松岡秀展、公立大学法人大阪市立大学
    • Filing Date
      2011-06-20
    • Related Report
      2011 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 磁気読取装置、磁気読取方法および磁気記録再生装置2011

    • Inventor(s)
      鐘本勝一
    • Industrial Property Rights Holder
      鐘本勝一、公立大学法人大阪市立大学
    • Industrial Property Number
      2011-286828
    • Filing Date
      2011-12-27
    • Related Report
      2011 Final Research Report

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Published: 2010-08-23   Modified: 2020-05-15  

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