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Optical and electric properties of metal-molecule-metal junctions

Research Project

Project/Area Number 22750001
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionHokkaido University

Principal Investigator

IKEDA Katsuyoshi  北海道大学, 大学院・理学研究院, 准教授 (50321899)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsプラズモン / コンダクタンス / 自己組織化単分子膜 / ラマン / 界面
Research Abstract

To obtain information of optical and electric properties of metal-molecule-metal junctions, plasmon resonances of metal nanogap structures have been measured by alternating molecular spacers with different thickness and conductivities. In this project, the gap distance in the nanogap structures was precisely controlled by the use of single crystalline metal substrates. It was experimentally confirmed that the optical property of the metal nanogap system was significantly affected by tunneling effects via the molecular layer.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (54 results)

All 2012 2011 2010 Other

All Journal Article (12 results) (of which Peer Reviewed: 10 results) Presentation (41 results) Remarks (1 results)

  • [Journal Article] Optical antenna for photo-functional molecular system2011

    • Author(s)
      K. Ikeda, K. Uosaki
    • Journal Title

      Chem. Euro. J.

      Volume: 18 Issue: 6 Pages: 1564-1570

    • DOI

      10.1002/chem.201102013

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopy and photo electrochemistry of organic monolayers within sphere-plane gold nano-gaps2011

    • Author(s)
      K. Ikeda
    • Journal Title

      Electrochemistry

      Volume: 79 Pages: 768-772

    • NAID

      130002150468

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal face dependent chemical effects in surface enhanced Raman scattering at atomically defined gold facets2011

    • Author(s)
      K. Ikeda, S. Suzuki, K. Uosaki
    • Journal Title

      Nano Lett

      Volume: 11 Issue: 4 Pages: 1716-1722

    • DOI

      10.1021/nl200251a

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Surface-enhanced Raman scattering at well-defined single crystalline faces of platinum-group metals induced by gap-mode plasmon excitation2011

    • Author(s)
      K. Ikeda, J. Sato, K. Uosaki
    • Journal Title

      J. Photochem. Photobiol. A : Chem

      Volume: 221 Issue: 2-3 Pages: 175-180

    • DOI

      10.1016/j.jphotochem.2011.02.022

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 界面構造を規制したプラズモニック光化学2011

    • Author(s)
      池田勝佳
    • Journal Title

      月刊化学工業

      Volume: 62(5) Pages: 1-6

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Journal Article] 原子・分子レベルで制御された金属-有機分子界面におけるプラズモニック光化学2011

    • Author(s)
      池田勝佳
    • Journal Title

      Molecular Science

      Volume: 5

    • NAID

      130000886449

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopy and pnotoelectrochemistry of organic monolayers within sphere-plane gold nano-gaps2011

    • Author(s)
      K.Ikeda
    • Journal Title

      Electrochemistry

      Volume: 79 Pages: 768-772

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal face dependent chemical effects in surface enhanced Raman scattering at atomically defined gold facets2011

    • Author(s)
      K.Ikeda, S.Suzuki, K.Uosaki
    • Journal Title

      Nano Letters

      Volume: 11 Pages: 1716-1722

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface-enhanced Raman scattering at well-defined single crystalline faces of platinum-group metals induced by gap-mode plasmon excitation2011

    • Author(s)
      K.Ikeda, J.Sato, K.Uosaki
    • Journal Title

      Journal of Phyotochemistry and Photobiology A

      Volume: 221 Pages: 175-180

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 構造規制界面におけるプラズモニック光化学2010

    • Author(s)
      池田勝佳
    • Journal Title

      化学と工業

      Volume: 63(6) Pages: 488-488

    • NAID

      10026384852

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 金属単結晶表面での増強ラマン分光2010

    • Author(s)
      池田勝佳, 魚崎浩平
    • Journal Title

      光化学

      Volume: 41(1) Pages: 10-14

    • NAID

      10026355165

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Journal Article] 飛翔する若手研究者"構造規制界面におけるプラズモニック光化学2010

    • Author(s)
      池田勝佳
    • Journal Title

      化学と工業

      Volume: 63 Pages: 488-488

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 電位制御下における単結晶金属-吸着分子界面のギャップモード増強ラマン観察2012

    • Author(s)
      池田勝佳
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      アクトシティ浜松(浜松市)
    • Year and Date
      2012-03-29
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] VIII B族金属を用いたナノ構造基板作成とそのプラズモン共鳴特性の評価2012

    • Author(s)
      内山紗里
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学(横浜市)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 金単結晶電極上における自己組織化単分子膜のin-situギャップモード増強ラマン観察2012

    • Author(s)
      木村文
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学(横浜市)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 白金族の金属を用いたナノ構造基板作成とそのプラズモン共鳴特性の評価2012

    • Author(s)
      内山紗里
    • Organizer
      化学系学協会北海道支部2012年冬季研究発表会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2012-01-31
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 異種原子層修飾単結晶金属電極表面でのギャップモードSERS分光2011

    • Author(s)
      池田勝佳
    • Organizer
      第31回表面科学学術講演会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2011-12-16
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Plasmonic Nanoantenna-Induced SERS Spectra at Atomically Defined Catalytic Pt-Group Metal Surfaces2011

    • Author(s)
      K. Ikeda
    • Organizer
      220th ECS Meeting
    • Place of Presentation
      Boston Convention Center(USA)
    • Year and Date
      2011-10-12
    • Related Report
      2011 Final Research Report
  • [Presentation] Plasmonic Nanoantenna-Induced SERS Spectra at Atomically Defined Catalytic Pt-Group Metal Surfaces2011

    • Author(s)
      Katsuyoshi Ikeda
    • Organizer
      220th ECS Meeting
    • Place of Presentation
      Boston Convention Center (USA)
    • Year and Date
      2011-10-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] 表面増強ラマン散乱における金属-分子界面の問題2011

    • Author(s)
      池田勝佳
    • Organizer
      2011年度分光学会北海道支部会シンポジウム
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2011-10-06
    • Related Report
      2011 Final Research Report
  • [Presentation] 表面増強ラマン散乱における金属-分子界面の問題2011

    • Author(s)
      池田勝佳
    • Organizer
      2011年度 分光学会北海道支部会シンポジウム
    • Place of Presentation
      北海道大学(札幌市)(招待講演)
    • Year and Date
      2011-10-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] 構造規制電極界面での酸素還元反応機構の検討2011

    • Author(s)
      田邉昌大
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター(札幌市)
    • Year and Date
      2011-09-22
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 原子・分子レベルで制御された金属-有機分子界面におけるプラズモニック光化学2011

    • Author(s)
      池田勝佳
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター(札幌市)
    • Year and Date
      2011-09-20
    • Related Report
      2011 Final Research Report
  • [Presentation] 原子・分子レベルで制御された金属-有機分子界面におけるプラズモニック光化学2011

    • Author(s)
      池田勝佳
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター(札幌市)(招待講演)
    • Year and Date
      2011-09-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] Sphere-plane coupled gap-mode enhanced Raman spectroscopy at well-defined catalytic metal surfaces2011

    • Author(s)
      K. Ikeda
    • Organizer
      62nd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      朱鷺メッセ(新潟市)
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 構造規制された電極触媒表面におけるギャップモード増強ラマン観察2011

    • Author(s)
      池田勝佳
    • Organizer
      2011年電気化学秋季大会
    • Place of Presentation
      朱鷺メッセ(新潟市)
    • Year and Date
      2011-09-10
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] プラズモニックな金属ナノギャップ構造における光誘起電子移動およびエネルギー移動2011

    • Author(s)
      池田勝佳
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎観光ホテル(宮崎市)
    • Year and Date
      2011-09-06
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Crystal face dependent SERS spectra at atomically defined metal facets2011

    • Author(s)
      K. Ikeda
    • Organizer
      ACS 242nd National Meeting
    • Place of Presentation
      Colorado Convention Center(USA)
    • Year and Date
      2011-08-30
    • Related Report
      2011 Final Research Report
  • [Presentation] Crystal face dependent SERS spectra at atomically defined metal facets2011

    • Author(s)
      Katsuyoshi Ikeda
    • Organizer
      ACS 242nd National Meeting
    • Place of Presentation
      Colorado Convention Center (USA)
    • Year and Date
      2011-08-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] 構造規制電極におけるプラズモニクス2011

    • Author(s)
      池田勝佳
    • Organizer
      第27回ライラックセミナー・第17回若手研究者交流会
    • Place of Presentation
      おたる自然の村(小樽市)
    • Year and Date
      2011-06-18
    • Related Report
      2011 Final Research Report
  • [Presentation] 構造規制電極におけるプラズモニクス2011

    • Author(s)
      池田勝佳
    • Organizer
      第27回ライラックセミナー・第17回若手研究者交流会
    • Place of Presentation
      おたる自然の村(小樽市)(招待講演)
    • Year and Date
      2011-06-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] 電極触媒および光機能性分子修飾電極におけるプラズモン共鳴の利用2011

    • Author(s)
      池田勝佳
    • Organizer
      統合物質創製化学推進事業第二回若手研究会
    • Place of Presentation
      休暇村支笏湖(苫小牧市)
    • Year and Date
      2011-05-28
    • Related Report
      2011 Final Research Report
  • [Presentation] 電極触媒および光機能性分子修飾電極におけるプラズモン共鳴の利用2011

    • Author(s)
      池田勝佳
    • Organizer
      統合物質創製化学推進事業第二回若手研究会
    • Place of Presentation
      休暇村支笏湖(苫小牧市)(招待講演)
    • Year and Date
      2011-05-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] Plasmonic enhancement of photo-energy conversion in organic monolayer system2011

    • Author(s)
      K. Ikeda
    • Organizer
      219th ECS Meeting
    • Place of Presentation
      Montreal Convention Center(Canada)
    • Year and Date
      2011-05-02
    • Related Report
      2011 Final Research Report
  • [Presentation] Plasmonic enhancement of photo-energy conversion in organic monolayer system2011

    • Author(s)
      Katsuyoshi Ikeda
    • Organizer
      219th ECS Meeting
    • Place of Presentation
      Montreal Convention Center (Canada)(招待講演)
    • Year and Date
      2011-05-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] 白金族原子層で被覆した単結晶金電極表面のギャップモード増強ラマン観察2011

    • Author(s)
      池田勝佳
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国立大(横浜市)
    • Year and Date
      2011-03-29
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] ギャップモードプラズモン共鳴を利用した光誘起電子移動の高効率化2011

    • Author(s)
      池田勝佳
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大(横浜市)
    • Year and Date
      2011-03-28
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Gap-mode plasmon enhanced Raman scattering spectroscopy for in-situ observation of atomically smooth single crystalline metal electrode surfaces2010

    • Author(s)
      K. Ikeda
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      シェラトンワイキキ(アメリカ)
    • Year and Date
      2010-12-16
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 構造規制表面におけるギャップモードプラズモン励起と高感度分光および高効率光電変換への応用2010

    • Author(s)
      池田勝佳
    • Organizer
      日本分光学会高感度表面・界面部会第3回シンポジウム
    • Place of Presentation
      産総研つくばセンター(つくば市)
    • Year and Date
      2010-12-03
    • Related Report
      2011 Final Research Report
  • [Presentation] 構造規制表面におけるギャップモードプラズモン励起と高感度分光および高効率光電変換への応用2010

    • Author(s)
      池田勝佳
    • Organizer
      日本分光学会高感度表面・界面部会第3回シンポジウム
    • Place of Presentation
      産総研つくばセンター(つくば市)(招待講演)
    • Year and Date
      2010-12-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] ギャップモードプラズモン励起による金および白金単結晶電極表面でのラマン分光2010

    • Author(s)
      池田勝佳
    • Organizer
      第30回表面科学学術講演会
    • Place of Presentation
      大阪大(吹田市)
    • Year and Date
      2010-11-05
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Gap-mode plasmon enhanced Raman scattering at atomically smooth surfaces of gold and platinum single crystals2010

    • Author(s)
      K. Ikeda
    • Organizer
      Symposium on Advanced Spectroscopy : The Spectroscopical Society of Japan
    • Place of Presentation
      北海道大(札幌市)
    • Year and Date
      2010-10-08
    • Related Report
      2011 Final Research Report
  • [Presentation] Gap-mode plasmon enhanced Raman scattering at atomically smooth surfaces of gold and platinum single crystals2010

    • Author(s)
      Katsuyoshi Ikeda
    • Organizer
      Symposium on Advanced Spectroscopy : The Spectroscopical Society of Japan
    • Place of Presentation
      北海道大(札幌市)(招待講演)
    • Year and Date
      2010-10-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] 光機能性有機超薄膜におけるプラズモニック光ナノアンテナの利用2010

    • Author(s)
      池田勝佳
    • Organizer
      第4回分子科学討論会
    • Place of Presentation
      大阪大(豊中市)
    • Year and Date
      2010-09-15
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] プラズモニック光ナノアンテナを利用した単分子修飾電極における高効率光電変換2010

    • Author(s)
      池田勝佳
    • Organizer
      2010年光化学討論会
    • Place of Presentation
      千葉大(西千葉)
    • Year and Date
      2010-09-08
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Gap-mode plasmon enhanced photo-energy conversion at well-defined metal-molecular interfaces2010

    • Author(s)
      K. Ikeda
    • Organizer
      International Conference on Electrified Interfaces(ICEI2010)
    • Place of Presentation
      Geneva(USA)
    • Year and Date
      2010-06-25
    • Related Report
      2011 Final Research Report
  • [Presentation] Gap-mode plasmon enhanced photo-energy conversion at well-defined metal-molecular interfaces2010

    • Author(s)
      Katsuyoshi Ikeda
    • Organizer
      International Conference on Electrified Interfaces (ICEI2010)
    • Place of Presentation
      Geneva (USA)(招待講演)
    • Year and Date
      2010-06-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] プラズモン増強光電場の分子科学研究への展開2010

    • Author(s)
      池田勝佳
    • Organizer
      構造規制界面におけるプラズモニック光化学の展開,分子研研究会
    • Place of Presentation
      分子科学研究所(岡崎市)
    • Year and Date
      2010-06-18
    • Related Report
      2011 Final Research Report
  • [Presentation] 構造規制界面におけるプラズモニック光化学の展開2010

    • Author(s)
      池田勝佳
    • Organizer
      分子研研究会「プラズモン増強光電場の分子科学研究への展開」
    • Place of Presentation
      分子科学研究所(岡崎市)(招待講演)
    • Year and Date
      2010-06-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] 構造規制界面におけるラマン散乱および光電変換のプラズモン増強,「光-分子強結合反応場の創成」領域および「半導体における動的相関電子系の光科学」2010

    • Author(s)
      池田勝佳
    • Organizer
      領域合同シンポジウム
    • Place of Presentation
      日本科学未来館(東京都)
    • Year and Date
      2010-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] 構造規制界面におけるラマン散乱および光電変換のプラズモン増強2010

    • Author(s)
      池田勝佳
    • Organizer
      「光-分子強結合反応場の創成」領域および「半導体における動的相関電子系の光科学」領域合同シンポジウム
    • Place of Presentation
      日本科学未来館(東京都)
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Plasmon-assisted photoenergy conversion in organic monolayer system2010

    • Author(s)
      K. Ikeda
    • Organizer
      217th Electro chemical Society Meeting
    • Place of Presentation
      バンクーバー(カナダ)
    • Year and Date
      2010-04-27
    • Related Report
      2011 Final Research Report
  • [Presentation] Plasmon-assisted photo-energy conversion in organic monolayer system2010

    • Author(s)
      Katsuyoshi Ikeda
    • Organizer
      217th Electrochemical Society Meeting
    • Place of Presentation
      ザ フェアモントホテルバンクーバー(カナダ)(招待講演)
    • Year and Date
      2010-04-27
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://pcl.sci.hokudai.ac.jp/groups/kikeda/

    • Related Report
      2011 Final Research Report

URL: 

Published: 2010-08-23   Modified: 2016-04-21  

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