Vaporization mechanism of room temperature ionic liquids
Project/Area Number |
22750010
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Single-year Grants |
Research Field |
Physical chemistry
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Research Institution | Tokyo Institute of Technology |
Principal Investigator |
AKAI Nobuyuki 東京工業大学, 大学院・理工学研究科, 助教 (50452008)
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Project Period (FY) |
2010 – 2011
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Project Status |
Completed (Fiscal Year 2011)
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Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
|
Keywords | 分子構造 / イオン液体 / 赤外スペクトル / 量子化学計算 / マトリックス単離法 / カチオン効果 / 蒸発機構 / 赤外分光法 / イオン対構造 |
Research Abstract |
Thermally vaporized room temperature ionic liquids were isolated in cryogenic neon matrices, and then their IR spectra were measured. Analyzing the observed IR spectra with aids of high-level quantum chemical calculations resulted in determination of anion-cation ion-pair structures of room temperature ionic liquid in the gas phase. It is found that a kind of ionic liquid has different ion-pair structures between the gas and liquid phases.
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Report
(3 results)
Research Products
(65 results)
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[Presentation] 一重項酸素の吸収・発光分光2010
Author(s)
秀森丈寛, 森琢麻, 井田明, 古井栄治, 赤井伸行, 河合明雄, 渋谷一彦
Organizer
第16回大気化学討論会
Place of Presentation
首都大学東京
Year and Date
2010-11-18
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