Construction and properties of supramolecular system based on paramagnetic endofullerenes
Project/Area Number |
22750030
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Single-year Grants |
Research Field |
Organic chemistry
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Research Institution | University of Tsukuba |
Principal Investigator |
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Project Period (FY) |
2010 – 2011
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Project Status |
Completed (Fiscal Year 2011)
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Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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Keywords | 内包フラーレン / 自己組織化 / 合成化学 / スピンエレクトロニクス / 金属内包フラーレン / 金属ポルフィリン / 磁性 / 錯形成 |
Research Abstract |
Paramagnetic endohedral metallofullerene ligand, which has a pyridine moiety as a ligation moiety for metal complexes, was synthesized selectively by the [2 + 3] cycloaddition reaction of La@C82 with azomethine ylide. Supramolecular complexes of the metallofullerene ligands with metalloporphyrin and fused metalloporphyrin dimer were constructed.
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Report
(3 results)
Research Products
(67 results)
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[Journal Article] X-Ray Structures of Sc2C2@C2n (n=40, 41, 42): In-Depth Understanding of the Core-Shell Interplay in Carbide Cluster Metallofullerenes2012
Author(s)
H. Kurihara, X. Lu, Y. Iiduka, H. Nikawa, M. Hachiya, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nlaga.sg, T. kasaka
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Journal Title
Inorg. Chem
Volume: 51
Issue: 1
Pages: 746-750
DOI
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Peer Reviewed
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[Journal Article] Enantioselective Synthesis of Endohedral Metallofullerenes2011
Author(s)
K.Sawai, Y.Takano, M.Izquierdo, S.Filippone, N.Martin, Z.Slanina, N.Mizorogi, M.Waelchli, T.Tsuchiya, T.Akasaka, S.Nagase
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Journal Title
J.Am.Chem.Soc.
Volume: 133
Issue: 44
Pages: 17746-17752
DOI
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Peer Reviewed
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[Journal Article] Semi-Metallic Single-Component Crystal of Soluble La@C_<82> Derivative with High Electron Mobility2011
Author(s)
S.Sato, S.Seki, Y.Honsho, L.Wang, H.Nikawa, G.Luo, J.Lu, M.Haranaka, T.Tsuchiya, S.Nagase, T.Akasaka
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Journal Title
J.Am.Chem.Soc.
Volume: 133
Issue: 8
Pages: 2766-2771
DOI
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Peer Reviewed
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[Journal Article] Organosulfur-based Fullerene Materials2011
Author(s)
T.Nakahodo, M.O.Ishitsuka, Y.Takano, T.Tsuchiya, T.Akasaka, A.Herranz, N.Martin, D.M.Guldi, S.Nagase
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Journal Title
Phosphorus, Sulfur, Silicon Relat.Elem.
Volume: 186
Issue: 5
Pages: 1308-1311
DOI
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Peer Reviewed
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[Journal Article] Photochemical Addition of C_<60> with Siliranes: Synthesis and Characterization of Carbosilylated and Hydrosilylated C_<60> Derivatives2010
Author(s)
J. Nagatsuka, S. Sugitani, M. Kako, T. Nakahodo, N. Mizorogi, M.0. Ishitsuka, Y. Maeda, T. Tsuchiva, T. Akasaka, X. Gao, S. Nagase
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Journal Title
J. Am. Chem. Soc
Volume: 132
Issue: 34
Pages: 12106-12120
DOI
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Peer Reviewed
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[Journal Article] A Molecular Ce_2@I_h-C_<80> Switch - Unprecedented Oxidative Pathway in Photoinduced Charge Transfer Reactivity2010
Author(s)
D. M. Guldi, L. Feng, S. G. Radhakrishnan, H. Nikawa, M. Yamada, N. Mizorogi, T. Tsuchiya, T. Akasaka, S. Nagase, M. A. Herranz, N. Martin
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Journal Title
J. Am. Chem. Soc
Volume: 132
Issue: 26
Pages: 9078-9086
DOI
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Peer Reviewed
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[Journal Article] The Effect of Atomic Nitrogen on the C_<60> Cage2010
Author(s)
H. Nikawa, Y. Araki, Z. Slanina, T. Tsuchiya, T. Akasaka, T. Wada, 0. Ito, K.-P. Dinse, M. Ata, T. Kato, S. Nagase
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Journal Title
Chem. Commun
Volume: 46
Issue: 4
Pages: 631-633
DOI
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Peer Reviewed
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[Book] Wiley-Blackwell, Chichester2010
Author(s)
T. Tsuchiya, T. Akasaka, S. Nagase inChemistry of Nanocarbons, T. Akasaka,F. Wudl, amd S. Nagase Eds
Total Pages
498
Publisher
Recent Progress in Chemistry ofEndohedral Metallofullerenes
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