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Creation of Chromic[3] catenane controlled by its unique motion

Research Project

Project/Area Number 22750035
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionNiigata University

Principal Investigator

IWAMOTO Hajime  新潟大学, 自然科学系, 准教授 (80304393)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsカテナン / 機械的結合 / クロミック分子
Research Abstract

[3] Catenanes, which change their color according to external stimuli such as temperature and metal ions, were investigated.[3] Catenanes having chromophores were synthesized. On addition of diamine to their solution, UV spectra changes of their solution were observed with a couple of isosbestic points. Variable-temperature fluorescence spectra showed red shift of emission maximum with increasing temperature.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (27 results)

All 2011 2010

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (13 results) Book (1 results)

  • [Journal Article] Highly shape-selective guest encapsulation in the precisely defined cavity of a calix 4 arene-capped metalloporphyrin2011

    • Author(s)
      Hajime Iwamoto, Saori Nishi and Takeharu Haino
    • Journal Title

      Chemical Communications

      Volume: 47 Pages: 12670-12672

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric alpha-2-tosylvinylation of in situ-generated N-2-tosylvinyl proline-derived ammonium ylides2011

    • Author(s)
      Tomohito Igarashi, Eiji Tayama, Hajime Iwamoto and Eietsu Hasegawa
    • Journal Title

      Tetrahedron Lett.

      Volume: 52 Pages: 1819-1821

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly shape-selective guest encapsulation in the precisely defined cavity of a calix[4]arene-capped metalloporphyrin2011

    • Author(s)
      Iwamoto, Hajime; Nishi, Saori; Haino, Takeharu
    • Journal Title

      Chemical Communications

      Volume: 47 Issue: 47 Pages: 12670-12672

    • DOI

      10.1039/c1cc14739k

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric alpha-2-tosylvinylation of in situ-generated N-2-tosylvinyl proline-derived ammonium ylides2011

    • Author(s)
      Tomohito Igarashi
    • Journal Title

      Tetrahedron Letters

      Volume: 52 Issue: 15 Pages: 1819-1821

    • DOI

      10.1016/j.tetlet.2011.02.040

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper(II) Triflate Catalyzed Intermolecular Aromatic Substitution of N, N-Disubstituted Anilines with Diazo Esters2010

    • Author(s)
      Eiji Tayama, Tomoyo Yanaki, Hajime Iwamoto and Eietsu Hasegawa
    • Journal Title

      European Journal of Organic Chemistry

      Pages: 6719-6721

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Remarkable enhancement effect of potassium tert-butoxide/THF solution in base-induced Sommelet-Hauser rearrangements2010

    • Author(s)
      Eiji Tayama, Keisuke Takedachi, Hajime Iwamoto and Eietsu Hasegawa
    • Journal Title

      Tetrahedron

      Volume: 66 Pages: 9389-9395

    • NAID

      120006746915

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly efficient synthesis of[3] rotaxane assisted by preorganization of pseudorotaxane using bis(crown ether)2010

    • Author(s)
      Hajime Iwamoto, Yukimi Yawata, Yoshimasa Fukazawa and Takeharu Haino
    • Journal Title

      Supramol. Chem.

      Volume: 22 Pages: 815-826

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tether-assisted synthesis of[3] rotaxane by olefin metathesis2010

    • Author(s)
      Hajime Iwamoto, Yukimi Yawata, Yoshimasa Fukazawa and Takeharu Haino
    • Journal Title

      Chemistry Letters

      Volume: 39 Pages: 24-25

    • NAID

      10027176294

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Application of biphasic reaction procedure using ferric chloride dissolved in an imidazolium salt and benzotrifluoride(FeIm-BTF procedure) to aza-Prins cyclization reaction2010

    • Author(s)
      Eietsu Hasegawa, Nohara Hiroi, Chika Osawa, Eiji Tayama and Hajime Iwamoto
    • Journal Title

      Tetrahedron Lett.

      Volume: 51 Pages: 6535-6538

    • NAID

      120006749081

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tether-assisted synthesis of [3]rotaxane by olefin metathesis2010

    • Author(s)
      Hajime Iwamoto
    • Journal Title

      Chemistry Letters

      Volume: 39 Pages: 24-25

    • NAID

      10027176294

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly efficient synthesis of 3 rotaxane assisted by preorganization of pseudorotaxane using bis(crown ether)s2010

    • Author(s)
      Hajime Iwamoto
    • Journal Title

      Supramolecular Chemistry

      Volume: 22 Pages: 815-826

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Application of biphasic reaction procedure using ferric chloride dissolved in an imidazolium salt and benzotrifluoride (FeIm-BTF procedure) to aza-Prins cyclization reaction2010

    • Author(s)
      Eietsu Hasegawa
    • Journal Title

      Tetrahedron Letters

      Volume: 51 Pages: 6535-6538

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper(II) Triflate Catalyzed Intermolecular Aromatic Substitution of N, N-Disubstituted Anilines with Diazo Esters2010

    • Author(s)
      Tayama Eiji
    • Journal Title

      European Journal of Organic Chemistry

      Pages: 6719-6721

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] エグリントンカップリングを用いたカテナン合成における分子内・分子間環化反応の選択性2011

    • Author(s)
      滝沢渉,岩本啓
    • Organizer
      第62回有機合成化学協会関東支部シンポジウム
    • Place of Presentation
      新潟市
    • Related Report
      2011 Final Research Report
  • [Presentation] クラウンエーテルと環状アンモニウム塩分子からなるカテナンの合成と回転運動性2011

    • Author(s)
      萩原達也,岩本啓
    • Organizer
      第62回有機合成化学協会関東支部シンポジウム(新潟シンポジウム)
    • Place of Presentation
      新潟市
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] カリックス[4]アレーンでキャプしたポルフィリンホスト分子のゲスト認識能とその熱力学的挙動2011

    • Author(s)
      岩本啓,西沙織,灰野岳晴
    • Organizer
      第7回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      東広島
    • Related Report
      2011 Final Research Report
  • [Presentation] カリックス[4]アレーンでキャプしたポルフィリンホスト分子のゲスト認識能とその熱力学的挙動2011

    • Author(s)
      岩本啓
    • Organizer
      第7回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      東広島市
    • Related Report
      2011 Annual Research Report
  • [Presentation] エグリントンカップリングを用いたカテナン合成における分子内・分子間環化反応の選択性2011

    • Author(s)
      滝沢渉
    • Organizer
      第62回有機合成化学協会関東支部シンポジウム(新潟シンポジウム)
    • Place of Presentation
      新潟市
    • Related Report
      2011 Annual Research Report
  • [Presentation] Shape-selective molecular recognition in confined space provided by calixarene-capped porphyrin and its thermodynamic behavior2010

    • Author(s)
      Hajime Iwamoto, Saori Nishi and Takeharu Haino
    • Organizer
      2010 International chemical congress of Pacific Basin Societies(Pacifichem 2010)
    • Place of Presentation
      Hawaii
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of[5] catenane via olefin metathesis reaction of pseudorotaxane composed of[2] catenane and secondary-ammonium salt2010

    • Author(s)
      Hajime Iwamoto, Shinzi Tafuku and Takeharu Haino
    • Organizer
      2010 International chemical congress of Pacific Basin Societies(Pacifichem 2010)
    • Place of Presentation
      Hawaii
    • Related Report
      2011 Final Research Report
  • [Presentation] 相補的水素結合形成を利用した新規[3]ロタキサン合成法の開発2010

    • Author(s)
      高橋直大,岩本啓
    • Organizer
      第60回有機合成化学協会関東支部シンポジウム(新潟シンポジウム)
    • Place of Presentation
      新津市
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Shape-Selective Molecular Recognition in Confined Space Provided by Calixarene-Capped Porphyrin2010

    • Author(s)
      Hajime Iwamoto, Saori Nishi and Takeharu Haino
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2010(ICSM 2010)
    • Place of Presentation
      Kyoto
    • Related Report
      2011 Final Research Report
  • [Presentation] カテナンとアンモニウム塩からなる擬ロタキサンの閉環メタセシス反応による[5]カテナンの合成2010

    • Author(s)
      田福伸次,岩本啓,灰野岳晴
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      東大阪市
    • Related Report
      2011 Final Research Report
  • [Presentation] Shape-Selective Molecular Recognition in Confined Space Provided by Calixarene-Capped Porphyrin2010

    • Author(s)
      Hajime Iwamoto
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2010 (ICSM 2010)
    • Place of Presentation
      Kyoto
    • Related Report
      2010 Annual Research Report
  • [Presentation] Shape-selective molecular recognition in confined space provided by calixarene-capped porphyrin and its thermodynamic behavior2010

    • Author(s)
      Hajime Iwamoto
    • Organizer
      2010 International chemical congress of Pacific Basin Societies (Pacifichem 2010)
    • Place of Presentation
      Hawaii
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of [5]catenane via olefin metathesis reaction of pseudorotaxane composed of [2]catenane and secondary-ammonium salt2010

    • Author(s)
      Hajime Iwamoto
    • Organizer
      2010 International chemical congress of Pacific Basin Societies (Pacifichem 2010)
    • Place of Presentation
      Hawaii
    • Related Report
      2010 Annual Research Report
  • [Book] 45. 27 Product Class Calixarenes, in Volume 45, Compounds with All-Carbon Functions : Arenes, Quasiarenes, Annulenes, and Polyenes. Synthesis of Science, Houben-Weyl Methods of Molecular Transformations, Eds. Siegel, J. S., Tobe, Y.2010

    • Author(s)
      Takeharu Haino, Hajime Iwamoto
    • Publisher
      Georg Thieme Verlag : Stuttgart
    • Related Report
      2011 Final Research Report

URL: 

Published: 2010-08-23   Modified: 2016-04-21  

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