Transformation of functional π-conjugated molecules into open-shell state
| Project/Area Number |
22750036
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
HIROTO Satoru 名古屋大学, 工学研究科, 助教 (30547427)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | ラジカル / ポルフィリン / 多環芳香族炭化水素 / シクロファン / アントラセン / 有機合成 / 高歪み化合物 / ヘリセン / インドール / 近赤外色素 / ピラジン / 酸化 / ビラジカル / 遷移金属触媒反応 / ヘキサベンゾコロネン |
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| Research Abstract |
We developed efficient method for introduction of various functionalities toward hexa-peri-hexabenzocoronenes. Second, we discovered that oxidation of amino-substituted porphyrins provided pyrazine-fused dimers in excellent yield with high regioselectivity. The pyrazine-fused dimers were also obtained by oxidation of amino-substituted anthracenes. In this case, pyrrole-fused dimer with helical conformation was obtained. Furthermore, oxidation of dihydroxyanthracenes afforded highly distorted [2.2]metacyclophanes.
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Report
(4 results)
Research Products
(66 results)
