• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

New Reactions, Compounds and Materials Based on Boron Ate Complexes

Research Project

Project/Area Number 22750038
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionKyoto University

Principal Investigator

ISHIDA Naoki  京都大学, 大学院・工学研究科, 助教 (70512755)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsホウ素 / アート錯体 / パラジウム / ボラート / インデン / アリル化 / XANTPHOS / アルケニルボラン / アルケニルボロン酸
Research Abstract

Organoboron compounds serve as useful reagents to synthesize pharmaceuticals and optoelectronic materials. We developed herein a new synthetic method for them. The present method enabled to synthesize complex molecules which are difficult to prepare by conventional methods. The pyridine. borane complexes obtained by this method exhibited intense fluorescence and high electron affinity. The new materials were successfully applied to hybrid organic-inorganic LED, a promising flexible lightning system.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (10 results)

All 2011 2010

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (4 results)

  • [Journal Article] Synthesis of Pyridine-N-oxide. Borane Intramolecular Complexes by Palladium-Catalyzed Reaction of 2-Bromopyridine-N-oxides with Alkynyltriarylborates2011

    • Author(s)
      Naoki Ishida, Wataru Ikemoto, Mizuna Narumi, Masahiro Murakami
    • Journal Title

      Org. Lett

      Volume: 13 Pages: 3008-3011

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Pyridine-N-oxide-Borane Intramolecular Complexes by Palladium-Catalyzed Reaction of 2-Bromopyridine-N-oxides with Alkynyltriarylborates2011

    • Author(s)
      Naoki Ishida, Wataru Ikemoto, Mizuna Narumi, Masahiro Murakami
    • Journal Title

      Organic Letters

      Volume: 13 Issue: 12 Pages: 3008-3011

    • DOI

      10.1021/ol2008439

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iterative Approach to Oligo(arylenevinylene) s Containing Tetrasubstituted Vinylene Unit2010

    • Author(s)
      Naoki Ishida, Yasuhiro Shimamoto, Masahiro Murakam
    • Journal Title

      Org. Lett

      Volume: 12 Pages: 3179-3181

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Allylation Reaction of Alkynylborates2010

    • Author(s)
      Naoki Ishida, Tatsuo Shinmoto, Shota Sawano, Tomoya Miura, Masahiro Murakami
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 83 Pages: 1380-1385

    • NAID

      10027652835

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Allylation Reaction of Alkynylborates2010

    • Author(s)
      Naoki Ishida, Tatsuo Shinmoto, Shota Sawano, Tomoya Miura, Masahiro Murakami
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 83 Pages: 1380-1385

    • NAID

      10027652835

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iterative Approach to Oligo(arylenevinylene)s Containing Tetrasubstituted Vinylene Units2010

    • Author(s)
      Naoki Ishida, Yasuhiro Shimamoto, Masahiro Murakami
    • Journal Title

      Organic Letters

      Volume: 12 Pages: 3179-3181

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] パラジウム触媒を用いたアルキニルボラートと2-ブロモピリジン-N-オキシドの反応によるピリジン-N-オキシド-ボラン錯体の合成2011

    • Author(s)
      石田直樹、池元亘、鳴海瑞菜、村上正浩
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Year and Date
      2011-09-09
    • Related Report
      2011 Final Research Report
  • [Presentation] パラジウム触媒を用いたアルキニルボラートと2-ブロモピリジン-N-オキシドの反応によるピリジン-N-オキシド-ボラン錯体の合成2011

    • Author(s)
      石田直樹、池元旦、鳴海瑞菜、村上正浩
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋市名古屋大学
    • Year and Date
      2011-09-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] Palladium-catalyzed reaction of Alkynyl(aryl) borates with aryl halides2010

    • Author(s)
      Naoki Ishida
    • Organizer
      Pacifichem 2010(2010環太平洋国際化学会議)
    • Place of Presentation
      ハワイ(ホノルル)
    • Year and Date
      2010-12-19
    • Related Report
      2011 Final Research Report
  • [Presentation] Palladium-catalyzed reaction of Alkynyl(aryl)borates with aryl halides.2010

    • Author(s)
      Naoki Ishida
    • Organizer
      Pacifichem 2010(2010環太平洋国際化学会議)
    • Place of Presentation
      Honolulu, Hawaiiu USA
    • Year and Date
      2010-12-19
    • Related Report
      2010 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi