| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Research Abstract |
Rhenium(I) biscarbonyl complexes linked with a viologen moiety as an electron pool as well as the complexes having a ruthenium(II) complex were successfully synthesized. These complexes were found to exhibit accumulation of multi-electrons in one molecule and photocatalytic abilities for reduction of carbon dioxide. Moreover, it was found that the rhenium(I) biscarbonyl complex was converted into a rhenium(I) tricarbonyl complex bearing a sacrificial electron donor, which led to inhibition of the photocatalytic reaction.
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