Chemistry on highly unsaturated iron carbene complexes
| Project/Area Number |
22750051
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 鉄錯体 / ホスファアルケン / ジアゾメタン / スピン状態 / 鉄 / カルベン / 低配位リン / ルテニウム |
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| Research Abstract |
Novel low-coordinate iron(I) complex[FeMes(BPEP)](3) was prepared by the reaction of[FeBr(BPEP)](1) with MesMgBr. Complex 1 underwent N-N bond cleavage of RCHN2(R=Ph, Me3Si) at room temperature to form a mixture of[FeBr(RCN)(BPEP)] and[FeBr(RCHNH)(BPEP)]. On the other hand, the reaction of 2 with Me3SiCHN2 resulted in the formation of Me3SiCH=CHSiMe3.
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Report
(3 results)
Research Products
(32 results)
